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Interface Acid-Base/Charge-Transfer Properties

  • Chapter
Surface and Interfacial Aspects of Biomedical Polymers

Abstract

Recent advances in the understanding of intermolecular interactions have led to new ideas about the interactions at interfaces between unlike substances, and these ideas are now being extended to interactions with biomaterials. Interactions at interfaces involve several kinds of intermolecular forces: dispersion forces, acid-base interactions, and the electrostatic attractions of ionic groups or of injected charges. This chapter reviews advances in: (1) acid-base interactions (including all hydrogen bonds) which had previously been labeled “polar”; and (2) the injection of electric charges upon contacting one material with another (“contact electrification”) and how this effect influences interfaces.

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References

  1. J. van der Waals, Thesis, Leiden University (1972).

    Google Scholar 

  2. W. H. Keesom, Physik A 22, 129, 643 (1921).

    CAS  Google Scholar 

  3. P. Debye, Physik Z. 21, 178 (1920).

    CAS  Google Scholar 

  4. P. Debye, Physik Z. 22, 302 (1921).

    CAS  Google Scholar 

  5. F. London, Z. Phys. Chem. B11, 222 (1930).

    Google Scholar 

  6. A. C. Hamaker, Physica 4, 1058 (1937).

    Article  CAS  Google Scholar 

  7. J. H. Hildebrand and R. L. Scott, Solubility of Nonelectrolytes, 3rd Edition, Reinhold, New York (1950).

    Google Scholar 

  8. F. M. Fowkes, Ind. Eng. Chem. 56, 40 (1964).

    Article  CAS  Google Scholar 

  9. G. N. Lewis, Valence and the Structure of Atoms and Molecules, Chem. Cat. Co., New York (1923).

    Google Scholar 

  10. R. S. Mulliken and W. B. Person, Ann. Rev. Phys. Chem. 13, 107 (1962).

    Article  CAS  Google Scholar 

  11. J. N. Bronsted, J. Chem. Soc. 119, 574 (1921).

    Article  CAS  Google Scholar 

  12. T. M. Lowry, Chem. Ind. 42, 43 (1923).

    Article  CAS  Google Scholar 

  13. G. Schwarzenbach, Rec. trav. chim. 75, 562 (1956).

    Google Scholar 

  14. R. G. Pearson, Hard and Soft Acids and Bases, Dowden, Hutchinson, and Ross, Stroudsburg, Pennsylvania (1973).

    Google Scholar 

  15. R. S. Drago, G. C. Vogel, and T. E. Needham, J. Am. Soc. 93, 6014 (1971).

    Article  CAS  Google Scholar 

  16. R. S. Drago, L. B. Parr, and C. S. Chamberlain, J. Am. Chem. Soc. 99, 3203 (1977).

    Article  CAS  Google Scholar 

  17. J. O. Edwards, J. Am. Chem. Soc. 76, 1540 (1954).

    Article  CAS  Google Scholar 

  18. H. F. Shurvell and J. T. Bulmer, in: Vibrational Spectra and Structure (J. R. Durig, ed.), p. 91, Elsevier, New York (1977).

    Google Scholar 

  19. F. M. Fowkes and S. Maruchi, Org. Coatings Plastics Chem. 37, 605 (1977).

    Google Scholar 

  20. H. P. Schreiber, C. Richard, and M. R. Wertheimer, in: Physicochemical Aspects of Polymer Surfaces (K. Mittal, ed.), Plenum, New York (1983).

    Google Scholar 

  21. F. M. Fowkes, D. O. Tischler, J. A. Wolfe, and M. J. Halliwell, Org. Coatings Appl. Polym. Sci. Proc. 46, 1 (1982).

    Google Scholar 

  22. L. J. Bellamy and R. L. Williams, Trans. Faraday Soc. 55, 14 (1959).

    Article  CAS  Google Scholar 

  23. A. Massat and J. E. Dubois, J. Mol. Struct. 65, 87 (1980).

    Article  CAS  Google Scholar 

  24. F. M. Fowkes, D. C. McCarthy, and M. A. Mostafa, J. Colloid Interface Sci. 78, 200 (1980).

    Article  CAS  Google Scholar 

  25. H. A. Benesi, J. Phys. Chem. 61, 970 (1957).

    Article  CAS  Google Scholar 

  26. F. M. Fowkes, H. A. Benesi et al., J. Agr. Food Chem. 8, 203 (1960).

    Article  CAS  Google Scholar 

  27. F. M. Fowkes and K. Knitter, unpublished results (1978).

    Google Scholar 

  28. J. C. Bolger and A. S. Michaels, in: Interface Conversion Polymer Coatings (P. Weiss, ed.), Elsevier, New York (1968).

    Google Scholar 

  29. L. A. Casper, Thesis, Lehigh University (1983).

    Google Scholar 

  30. F. M. Fowkes, J. Phys. Chem. 64, 726 (1960).

    Article  CAS  Google Scholar 

  31. F. M. Fowkes and M. A. Mostafa, Ind. Eng. Chem., Prod. Res. Develop. 17, 3 (1978).

    Article  CAS  Google Scholar 

  32. B. J. Fontana and J. R. Thomas, J. Phys. Chem. 65, 480 (1961).

    Article  CAS  Google Scholar 

  33. F. J. Fowkes, C.-Y. Sun, and S. T. Joslin, in: Corrosion Control by Organic Coatings (H. Leidheiser, Jr., ed.), p. 1 NACE, Houston (1981).

    Google Scholar 

  34. F. M. Fowkes, Disc, Faraday Soc. 42, 246 (1966).

    Article  Google Scholar 

  35. K. Tamaribuchi and M. L. Smith, J. Colloid Interface Sci. 22, 404 (1966).

    Article  CAS  Google Scholar 

  36. F. M. Fowkes, H. Jinnai, M. A. Mostafa, F. W. Anderson, and R. J. Moore, in: Colloids and Surfaces in Reprographic Technology, ACS Symp. Ser. 200, 307 (1982).

    Book  Google Scholar 

  37. S. M. Skinner, R. L. Savage, and J. E. Rutzler, J. Appl. Phys. 24, 438 (1953).

    Article  CAS  Google Scholar 

  38. B. V. Deryagin and V. P. Smilga, Third Inter. Congr. Surface Activity 2, 349 (1960).

    Google Scholar 

  39. V. J. Webers, J. Appl Polym. Sci. 7, 1317 (1963).

    Article  CAS  Google Scholar 

  40. D. K. Davies, Brit. J. Appl. Phys. 2, 1533 (1969).

    Google Scholar 

  41. H. G. von Harrach and B. N. Chapman, Thin Solid Films 13, 157 (1972).

    Article  Google Scholar 

  42. C. Weaver, Faraday Special Discussions 2, 1 (1972).

    Article  Google Scholar 

  43. T. J. Fabish, H. M. Saltsburg, and M. L. Hair, J. Appl. Phys. 47, 930–940 (1976).

    Article  CAS  Google Scholar 

  44. C. B. Duke and T. J. Fabish, Phys. Rev. Lett. 37, 1075 (1976).

    Article  CAS  Google Scholar 

  45. T. J. Fabish and C. B. Duke, J. Appl. Phys. 48, 4256 (1977).

    Article  CAS  Google Scholar 

  46. G. B. Duke, T. J. Fabish, and A. Paton, Chem. Phys. Lett. 49, 133 (1977).

    Article  CAS  Google Scholar 

  47. C. B. Duke, J. Vac. Sci. Technol. 15, 157 (1978).

    Article  CAS  Google Scholar 

  48. C. B. Duke, Phys. Rev. B 18, 5717 (1978).

    Google Scholar 

  49. C. B. Duke and T. J. Fabish, J. Appl. Phys. 49, 315 (1978).

    Article  CAS  Google Scholar 

  50. G. A. Cottrell, J. Lowell, and A. C. Rose-Innes, J. Appl. Phys. 50, 374 (1979).

    Article  CAS  Google Scholar 

  51. T. J. Fabish, C. B. Duke, M. L. Hair, and H. M. Saltsburg, J. Appl. Phys. 51, 1247 (1980).

    Article  CAS  Google Scholar 

  52. G. A. Cottrell, J. Lowell, and A. C. Rose-Innes, J. Appl. Phys. 51, 1250 (1980).

    Article  CAS  Google Scholar 

  53. F. M. Fowkes, F. H. Hielscher, and D. J. Kelly, J. Colloid Interface, Sci. 32, 469 (1970).

    Google Scholar 

  54. A. Bui, H. Carchano, and D. Sanchez, J. Appl Phys. 43, 3794 (1972).

    Article  Google Scholar 

  55. A. Bui, H. Carchano, and D. Sanchez, Thin Solid Films 13, 207 (1972).

    Article  Google Scholar 

  56. F. M. Fowkes and F. H. Hielscher, Spontaneous Electrostatic Precipitation of Dust, U.S. Bur. Mines Contract No.GO110269 Final Report (May 15, 1973).

    Google Scholar 

  57. H. R. Anderson, F. M. Fowkes, and F. H. Hielscher, J. Polym. Sci., Phys. 14, 879 (1976).

    Article  CAS  Google Scholar 

  58. F. M. Fowkes and F. H. Hielscher, Org. Coatings Plastics Chem. 42, 169 (1980).

    CAS  Google Scholar 

  59. F. M. Fowkes, in: Industrial Applications of Surface Analysis, ACS Symp. Ser. 199, 69 (1982).

    Book  Google Scholar 

  60. F. M. Fowkes, F. H. Hielscher, and J. Emerson, to be published.

    Google Scholar 

  61. E. J. Verwey and J. Th. G. Overbeek, Stability of Lyophobic Colloids, p. 32, Elsevier, Amsterdam (1984).

    Google Scholar 

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Author information

Authors and Affiliations

  1. Department of Chemistry, Lehigh University, Building 6, Pennsylvania, 18015, USA

    Frederick M. Fowkes

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  1. Frederick M. Fowkes
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Editor information

Editors and Affiliations

  1. University of Utah, Salt Lake City, Utah, USA

    Joseph D. Andrade

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© 1985 Plenum Press, New York

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Fowkes, F.M. (1985). Interface Acid-Base/Charge-Transfer Properties. In: Andrade, J.D. (eds) Surface and Interfacial Aspects of Biomedical Polymers. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8610-0_9

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  • DOI: https://doi.org/10.1007/978-1-4684-8610-0_9

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-8612-4

  • Online ISBN: 978-1-4684-8610-0

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