Skip to main content

Polymer Surface Dynamics

  • Chapter

Abstract

Classical surface chemistry assumes that solid surfaces are rigid, immobile, and at equilibrium. These assumptions allow one to probe adsorption and wetting or contact angle processes purely from the point of view of the liquid phase, because one assumes that the solid phase does not in any way respond, reorient, or otherwise change in the different liquid environments. Although such assumptions may be partially correct for truly rigid solids, they are generally inappropriate for polymers (see also Chapter 7).

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. P. Hedvig, Dielectric Spectroscopy of Polymers, Wiley, New York (1977).

    Google Scholar 

  2. D. J. Williams, Polymer Science and Engineering, Prentice-Hall, Inc., Englewood Cliffs, New Jersey (1971).

    Google Scholar 

  3. J. D. Andrade, D. E. Gregonis, and L. M. Smith, in: Physicochemical Aspects of Polymer Surfaces (K. L. Mittal, ed.), pp. 911–922, Plenum Press, New York (1983).

    Google Scholar 

  4. E. Nyilas and R. S. Ward, Jr., Development of blood compatible elastomers. V., J. Biomed. Materials Res. Symp. 8, 69–84 (1977); also Proc. 23rd Ann. Conf Eng. Med. Biol. 12, 147–148 (1970).

    Google Scholar 

  5. F. J. Holly and M. F. Refojo, Wettability of hydrogels, J. Biomed. Materials Res. 9, 315–326 (1975).

    Article  CAS  Google Scholar 

  6. E. W. Merrill, Behavior of blood at surfaces, Ann. N.Y. Acad. Sci. 283, 6–16 (1977).

    Article  CAS  Google Scholar 

  7. S. A. Barenberg, J. S. Schultz, J. M. Anderson, and P. H. Geil, Hemocompatibility: macromolecular motions and order of the polymer interface, Trans. Am. Soc. Artificial Internal Organs 25, 159–162 (1979).

    Article  CAS  Google Scholar 

  8. S. A. Barenberg, J. M. Anderson, and K. A. Mauritz, Thrombogenesis: an epitaxial phenomena, J. Biomed. Materials Res. 15, 231–245 (1981).

    Article  CAS  Google Scholar 

  9. W. M. Reichert, R. E. Filisko, and S. A. Barenberg, Polyphosphazenes: effect of molecular motions on thrombogenesis, J: Biomed. Materials Res. 16, 301–312 (1982).

    Article  CAS  Google Scholar 

  10. Y. Sakurai, T. Akaike, K. Kataoka, and T. Okano, in: Biomedical Polymers (E. P. Goldberg and A. Nakajima, eds.), pp. 335–379, Academic Press, New York (1980).

    Google Scholar 

  11. D. Brier-Russell, E. W. Salzman, J. Lindon, R. Handin, E. C. Merrill, A. K. Dincer, and J.-S. Wu, Interaction of blood with model surfaces J. Colloid Interface Sci. 81, 311–318 (1981).

    Article  CAS  Google Scholar 

  12. D. L. Coleman, In Vitro Blood-Materials Interactions: A Multi-Test Approach, PhD. Thesis, University of Utah, August, 1980.

    Google Scholar 

  13. A. M. North, in: Molecular Behaviour and the Development of Polymeric Materials (A. Ledwith and A. M. North, eds.), pp. 368–403, Chapman and Hall, London (1974).

    Google Scholar 

  14. C. D. Armeniades and E. Baer, in: Introduction to Polymer Science and Technology (H. S. Kaufman, ed.), pp. 239–299, John Wiley and Sons, New York (1977).

    Google Scholar 

  15. M. J. Richardson and N. G. Savill, What information will DSC give on glassy polymers?, Brit. Polym. J. 11, 123–129 (1979).

    Article  CAS  Google Scholar 

  16. R. A. Pethrick, Molecular motion in semi-flexible macromolecules, Sci. Prog. Oxf. 6, 571–592 (1980).

    Google Scholar 

  17. J. M. G. Cowie, Relaxation processes in the glassy state: molecular aspects, J. Macromol. Sci. Phys. B18, 569–623 (1980).

    Google Scholar 

  18. J. Brandrup and E. H. Immergut, eds. Polymer Handbook, 2nd Edition, John Wiley and Sons, New York (1975).

    Google Scholar 

  19. L. R. Brostrom, D. L. Coleman, D. E. Gregonis, and J. D. Andrade, Thermal analysis of polymethacrylates, Makromol. Chem., Rapid Comm. 1, 341–343 (1980).

    Article  CAS  Google Scholar 

  20. E. A. Turi, Thermal Characterization of Polymeric Materials, Omnitherm Corp., Arlington Heights, Illinois (1982).

    Google Scholar 

  21. J. K. Gillham, S. J. Standicki, and Y. Hazony, Low-frequency thermomechanical spectrometry of polymeric materials: tactic poly(methyl methacrylates), J. Appl. Polym. Sci. 21,401–424 (1977).

    Article  CAS  Google Scholar 

  22. N. G. McCrum, B. E. Read, and G. Williams, Anelastic and Dielectric Effects in Polymeric Solids, John Wiley and Sons, New York (1967).

    Google Scholar 

  23. A. E. Woodward and F. A. Bovey, eds., Polymer Characterization by ESR and NMR, Am. Chem. Soc. Symp. Series 142 (1980).

    Google Scholar 

  24. J.-M. Braun and J. E. Guillet, Study of polymers by inverse gas chromatography, Adv. Polym. Sci. 21, 107–145 (1976).

    Article  CAS  Google Scholar 

  25. J.-M. Braun and J. E. Guillet, Studies of polystyrene in the region of the glass transition temperature by inverse gas chromatography, Macromolecules 8, 882–888 (1975).

    Article  CAS  Google Scholar 

  26. Z. Kessaissia, E. Papirer, and J.-B. Donnet, Molecular transitions of alkyl chains grafted onto silicas observed by gas chromatography, J. Colloid Interface Sci. 79, 257–263 (1981).

    Article  CAS  Google Scholar 

  27. H. P. Schreiber and M. D. Croucher, Surface characteristics of solvent-cast polymers, J. Appl. Polym. Sci. 25, 1961–1968 (1980).

    Article  CAS  Google Scholar 

  28. Y. S. Lipatov and L. M. Sergeeva, Adsorption of Polymers, Chapter 4, John Wiley and Sons, New York (1974).

    Google Scholar 

  29. G. J. Howard and R. A. Shanks, Influence of filler particles on the mobility of polymer molecules, J. Macromol. Sci, Chem. A17, 287–295 (1982).

    CAS  Google Scholar 

  30. A. Yim, R. S. Chahal, and L. E. St. Pierre, Effect of polymer-filler interaction energy on the Tg of filled polymers, J. Colloid Interface Sci. 43, 583–590 (1973).

    Article  CAS  Google Scholar 

  31. P. Peyser and W. D. Bascom, Effect of filler and cooling rate on the glass transition of polymers, J. Macromol. Sci-Phys. B13, 597–610 (1977).

    Article  CAS  Google Scholar 

  32. J. F. M. Pennings and B. Bosman, Relaxation of the surface energy of solid polymers, Colloid Polym. Sci. 257, 720–724 (1979).

    Article  CAS  Google Scholar 

  33. A. Carre and H. P. Schreiber, Solvent history effects and multi-valued surface properties of PMMA coatings, Proc. FATIPEC Congress, Belgium, May, 1982.

    Google Scholar 

  34. H. Yasuda, A. K. Sharma, and T. Yasuda, Effect of orientation and mobility of polymer molecules at surfaces on contact angle and its hysteresis, J. Polym. Sci., Polym. Physics 19, 1285–1291 (1981).

    Article  CAS  Google Scholar 

  35. N. Beredijick, in: Newer Methods of Polymer Characterization (B. Ke, ed.), Interscience, New York (1964).

    Google Scholar 

  36. H. W. Fox, P. W. Taylor, W. A. Zisman, Polyorganosiloxanes: surface active properties, Ind. Eng. Chem. 39, 1401–1409 (1947).

    Article  CAS  Google Scholar 

  37. M. J. Owen, The surface activity of silicones, Ind. Eng. Chem., Prod. Res. Develop. 19, 97–103 (1980).

    Article  CAS  Google Scholar 

  38. A. Okawa, B.Sc. Thesis, Department of Materials Science, University of Utah, June, 1983.

    Google Scholar 

  39. K. Ohara, Relationship between frictional electrification and molecular motion of polymers, J. Electrostatics 9, 107–115 (1980).

    Article  CAS  Google Scholar 

  40. J. Klein and P. Luckham, Forces between two adsorbed PEO layers immersed in a good aqueous solvent, Nature 300, 429–430 (1982).

    Article  CAS  Google Scholar 

  41. A. Baszkin, N. Nishino, and L. Ter-Minassian-Saraga, Solid-liquid adhesion of oxidized polyethylene films, J. Colloid Interface Sci. 54, 317–322 (1976).

    Article  CAS  Google Scholar 

  42. H. Morawetz, Fluorescence studies of conformational mobility, Pure Appl. Chem. 52, 277–284 (1980).

    Article  CAS  Google Scholar 

  43. K. C. Rusch, Time-temperature superposition and relaxation behavior in polymer glasses, J. Macromol. Sci. Phys. B12, 179–204 (1968).

    Google Scholar 

  44. L.-H. Lee, Surface wettability and glass temperatures, J. Appl. Polym. Sci. 12, 719–730 (1968).

    Article  CAS  Google Scholar 

  45. S. Nagaoka, Y. Mori, H. Takiuchi, K. Yokota, H. Tanzawa, and S. Nichiumi, Interaction between blood components and hydrogels with poly(oxyethylene) chain, Polymer Preprints 24, 67–68 (1983).

    CAS  Google Scholar 

  46. T. Matsuda and T. Akutsu, Blood/materials interactions of hydrophobic and hydrophilic segmented polyurethanes, Organic Coatings and Applied Polymer Science Preprints 48, 647–648 (1983).

    CAS  Google Scholar 

  47. T. J. McCarthy, Polymer surface modification by diffusion of functional groups, Organic Coatings and Applied Polymer Science Preprints 48, 520–522 (1983).

    CAS  Google Scholar 

  48. R. S. Ward, Jr., Development of thermoplastics, Organic Coatings and Plastics Preprints 42, 227–228 (1980).

    CAS  Google Scholar 

  49. D. S. Everhart and C. N. Reilley, Functional group mobility, Surface and Interface Analysis 3, 126–133 (1981).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1985 Plenum Press, New York

About this chapter

Cite this chapter

Andrade, J.D., Gregonis, D.E., Smith, L.M. (1985). Polymer Surface Dynamics. In: Andrade, J.D. (eds) Surface and Interfacial Aspects of Biomedical Polymers. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8610-0_2

Download citation

  • DOI: https://doi.org/10.1007/978-1-4684-8610-0_2

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-8612-4

  • Online ISBN: 978-1-4684-8610-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics