Abstract
A study has been made of the concentration dependence of the specific electrical resistivity, Hall coefficient, absolute thermo-emf, magnetic susceptibility, microhardness, and crystal lattice constant at room temperature, and also of the temperature dependence of the specific electrical resistivity and the coefficient of the thermo-emf in the range 77–300°K, of alloys in the system TaC-WC in the solid-solution region. The regular features observed in the changes in physical properties and the qualitative explanation of them are in accordance with current ideas regarding the electron structure of transition-metal carbides. The authors have put forward a suggestion concerning the strengthening of the covalent bond in the Me-Me band of the solid solutions.
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Literature Cited
A.I. Ansel’m, Introduction to the Theory of Semiconductors [Russian translation], Fizmatgiz, Moscow and Leningrad (1962).
Ya. G. Dorfman, Magnetic Properties and the Structure of Matter [in Russian], Gostekhizdat, Moscow (1955).
Ya. G. Dorfman, Diamagnetic and Chemical Bonding [in Russian], Fizmatgiz, Moscow (1961).
L. B. Dubrovskaya and I.I. Matvienko, Fiz. Metal, i Metalloved., 19:199 (1965).
S.N. L’vov and V. F.Nemchenko, Infor mpis’mo IMSS Akad. Nauk UkrSSR, No. 272 (1960).
S.N. L’vov, V. F. Nemchenko, and V. I. Marchenko, Pribory i Tekh. Eksperim., No. 2, 159 (1961).
S.N. L’vov, V. F. Nemchenko, and G. V. Samsonov, Poroshkovaya Met., No. 4, 3 (1962).
G. V. Samsonov, Poroshkovaya Met., No. 12, 49 (1966).
V. I. Trefilov, in: The Physical Nature of the Brittle State [in Russian], Naukova Dumka, Kiev (1965), p. 76.
A. S. Umanskii and V. I. Fadeeva, Fiz. Metal, i Metalloved., 20:719 (1965).
V. F. Funke and V. S. Popov, Izv. Akad. Nauk SSSR, Metally, No. 6 (1966).
H. Biltz, Z. Physik, 153:338 (1958).
R. Conte, Rapp. CEAR, No. 2854 (1965).
D. Z. Deddneore, J. Am. Ceram. Soc, Ceram. Abs., 48:354 (1965).
I. Fumitake, T. Takashi, and T. Hideo, J. Phys. Soc. Japan, 19:136 (1964).
H. Goretzki, Doctoral Dissertation, Vienna (1963).
H. Kojima, R. S. Tebble, and D. E. Williams, Proc. Roy. Soc, A260:237 (1961).
C. T. Kriessman, Rev. Mod. Phys., 25:122 (1953).
B. T. Matthias, V. D. Compton, and Corenzwit, J. Phys. Chem. Solids, 1:188 (1956).
E. Rudy and F. Benesovsky, Planseeber. Pulvermet., 8:12 (1960).
E. Rudy, El. Rudy, and F. Benesovsky, Monatsh. Chem., 93:1176 (1962).
H. E. Smidt, Z. Metallk., 49:113 (1958).
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© 1974 Consultants Bureau, New York
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Denbnovetskaya, E.N., L’vov, S.N. (1974). A Study of Some Physical Properties of Alloys of the System TaC-WC. In: Samsonov, G.V. (eds) Refractory Carbides. Studies in Soviet Science. Springer, New York, NY. https://doi.org/10.1007/978-1-4684-8598-1_31
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DOI: https://doi.org/10.1007/978-1-4684-8598-1_31
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