Abstract
Solvent chemical-shift and temperature effects on acrylic-copolymers were studied. The solvents used in this investigation were o-dichlorobenzene, bromoform, 1,1,2,2-tetrachloroethylene, and 1,1,2,2-tetrabromoethane. Bromoform was found to give the best resolved spectra at a temperature of 102 C. Analytical data obtained by integration of the NMR resonance bands for the arcylic copolymers were within a few percent of the initial monomer content.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
K. J. Liu, J. Polymer Sci. Part A-2 5, 1199 (1967).
K. J. Liu, J. S. Szutz, and R. Ullman, Am. Chem. Soc, Div. Polymer Chem., Preprints 5 (2), 761 (1964).
A. Nishioka, H. Watanabe, I. Yamagushi, and H. Shimizu, J Polymer Sci. 45, 323 (1960).
T. Yoshino, Y. Kikuchi, and J. Komiyama, J. Phys. Chem. 70(4), 1059 (1966).
U. Johnsen, Kolloid Z. 178, 161 (1961).
L. J. Merrill, J. A. Sauer, and A. E. Woodward, J. Polymer Sci. Part A 3(12), 4243 (1965).
K. Matsuzaki, T. Uryn, A. Ishida, and T. Ohki, J. Polymer Sci. Part B 2(12), 1139 (1964).
J. G. Powles, J. H. Strange, and D. J. H. Sandiford, Polymer 4(3), 401 (1963).
N. M. Bazhenov, M. V. Vol’kenshtein, and A. S. Khachaturov, Vysokomolekul. Soedin. 5(7), 1025 (1963).
F. A. Bovey, J. Polymer Sci. 46(147), 59 (1960).
A. Nishioka, Y. Kato, T. Vetake, and H. Watanabe, J. Polymer Sci. 61, S32–S33 (1962).
H. Watanabe, Y. Kato, and A. Nishioka, Kogyo Kagaku Zasshi 65, 270 (1962).
M. L. Miller and C. E. Rauhut, J. Polymer Sci. 38(133), 63 (1959).
K. M. Sinnott, J. Polymer Sci. 42, 3 (1960).
N. Grassie, B. J. D. Torrance, J. D. Fortune, and J. D. Gemmell, Polymer 6, 653 (1965).
F. A. Bovey, J. Polymer Sci. 62, 197 (1962).
K. C. Ramey and J. Messiek, J. Polymer Sci. Part A-2 4, 155 (1961).
C. Haney, F. A. Johnson, and M. G. Baldwin, J. Polymer Sci. Part A 4(7), 1791 (1966).
H. A. Willis and M. E. A. Cudby, Appl. Spectry. Rev. 1 (2), 237 (1968).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1970 Chicago Section of the Society for Applied Spectroscopy
About this chapter
Cite this chapter
Netzel, D.A. (1970). An NMR Study of Acrylic Polymers. In: Grove, E.L., Perkins, A.J. (eds) Developments in Applied Spectroscopy. Developments in Applied Spectroscopy, vol 7b. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8589-9_13
Download citation
DOI: https://doi.org/10.1007/978-1-4684-8589-9_13
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-8591-2
Online ISBN: 978-1-4684-8589-9
eBook Packages: Springer Book Archive