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Thiomolybdates and Thiotungstates: Their Properties and Role as Ligands in Coordination Chemistry

  • Chapter
Nitrogen Fixation

Abstract

Since the first systematic studies of thiomolybdates and thio-tungstates as ligands having interesting properties in coordination chemistry,1–3 they have gained interest because of their impact in bioinorganic chemistry, e.g., the generation of compounds with poly-metallic units which exist in biology. The MoS 2-4 ion, for example, has been used as a starting material for the synthesis of FeMoS clusters. The possible relevance of the thiomolybdato and thiotungstato complexes of iron to the nitrogenase problem was pointed out several years ago.1 In this relation, the properties of such ions, e.g., their electronic structure and reactivity, their formation, and their tendency to form complexes, are of great importance. This article surveys the results available in this area.

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  103. A. Müller, H. Dornfeld, G. Henkel, B. Krebs, and M. P. A. Viegers, [Au2(WS4)2]2-, ein Neuartiges Anorganisches Ringsystem, Angew. Chem. 90:57 (1978); A. Müller, H. Dornfeld, M. Dartmann, and H. Bögge, unpublished results.

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  104. D. Coucouvanis, E. D. Simhon, D. Swenson, and N. C. Baenziger, X-Ray Crystal Structure of Bis(tetraethylammonium)Di-μ-thio-[bis(phenylthio)-ferrate(III)]dithiomolybdate(V), [Et4N]2 [(PhS)2FeMoS4]: J. Chem. Soc, Chem. Commun. 361 (1979).

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  106. A. Müller, A. M. Dommröse, W. Jaegermann, E. Krickemeyer, and S. Sarkar, Determination of the Structure of New Tetrathio-molybdato Complexes of Fe(II), Cu(I) and Ag(I) by the Resonance Raman Effect: Textbrook Examples for its Application in Coordination Chemistry, Angew. Chem. 93:1119 (1981).

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  108. A. Müller, H. G. Tölle, and H. Bögge, Darstellung und Kristallstruktur von Verbindungen mit den Komplexen Anionen [Cl2FeS2MoS2]2- und [Cl2FeS2WS2]2-, Z. anorg. allg. Chem. 471:115 (1980).

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  110. A. Müller, H. Bögge, E. Königer-Ahlborn and W. Hellman, Preparation and X-ray Crystal and Molecular Structure of [Mo2S8Ag4](PPh3)4, a Compound with a Metal-Sulfur Cage, Inorg. Chem. 18:2301 (1979).

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  113. A. Müller, H. Bögge and E. Königer-Ahlborn, X-Ray Crystal and Molecular Structure of [W2S8Ag4(PPh3)4], A Compound Having a Novel Metal-Sulfur Cage Fused by Two Connected Six-Membered WS3Ag2 Rings, J. C. S. Chem. Comm . 739 (1978).

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  114. A. Müller, H. Bögge, and U. Schimanski, Molybdenum-Copper-Sulphur-Containing Cage System and its Bioinorganic Relevance. Preparation and X-Ray Crystal Structure of (CU3M0S3Cl)(PPh3)3S with an Interesting Stereochemistry of Non-Equivalent Cu Atoms, J. Chem. Soc., Chem. Commun. 91 (1980).

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  116. A. Müller, T. K. Hwang, and H. Bögge, [{CU3WS3Cl}(PPh3)3O], Gezielte Synthese einer Verbindung mit Verschiedenen Metallatomen in einem Cubanartigen Gerüst, Angew. Chem. 91:656 (1979).

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  118. A. Müller, H. Bögge, and U. Schimanski, Crystal and Molecular Structure of [(C6H5)3P]2CuS2MoS2CuP(C6H5)3•0.8 CH2Cl2, a Compound with a Doubly Bridging MoS4 2--Ligand Between Cu Centers, Inorg. Chim. Acta 45:L249 (1980).

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  119. A. Müller, H. Bögge, and E. Königer-Ahlborn, Darstellung und Kristallstruktur von (PPh3)3Ag2WS4, einem Neuartigen Dreikern-Komplex mit Tetraedrisch und Trigonal Planar Koordinierten Ag-Atomen, Z. Naturforsch. 34b:1698 (1979).

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  1. Faculty of Chemistry, University of Bielefeld, P.O. Box 8640, D-4800, Bielefeld 1, West Germany

    Achim Müller & Ekkehard Diemann

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  1. Achim Müller
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  1. University of Bielefeld, Bielefeld, Federal Republic of Germany

    Achim Müller

  2. Charles F. Kettering Research Laboratory, Yellow Springs, Ohio, USA

    William E. Newton

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© 1983 Plenum Press, New York

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Müller, A., Diemann, E. (1983). Thiomolybdates and Thiotungstates: Their Properties and Role as Ligands in Coordination Chemistry. In: Müller, A., Newton, W.E. (eds) Nitrogen Fixation. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8523-3_8

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  • DOI: https://doi.org/10.1007/978-1-4684-8523-3_8

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