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Iron-Molybdenum-Sulfur Clusters

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Book cover Nitrogen Fixation

Abstract

The recognition that molybdenum is present in the nitrogenase enzymes as an extraetable cofactor, containing iron, molybdenum, and sulfur in the approximate ratios 7:1:6,1-4 stimulated much interest in the synthesis and study of compounds containing these three elements. This article describes those compounds presently known to contain an Fe-Mo-S framework; their physical properties are then compared with those of the iron-molybdenum cofactor, with particular emphasis being given to systems containing Fe3MoS4 cubane-like clusters.

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Author information

Authors and Affiliations

  1. Department of Chemistry, Manchester University, Manchester, M13 9PL, UK

    C. David Garner, Stephen R. Acott, George Christou, David Collison, Frank E. Mabbs, Vasili Petrouleas & Christopher J. Pickett

  2. Physics Division, Nuclear Research Center Demokritos, Aghia Paraskevi, Attiki, Greece

    Vasili Petrouleas

  3. A.R.C. Unit of Nitrogen Fixation, University of Sussex, BN1 9RQ, Brighton, Sussex, UK

    Christopher J. Pickett

Authors
  1. C. David Garner
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  2. Stephen R. Acott
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  3. George Christou
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  4. David Collison
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  5. Frank E. Mabbs
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  6. Vasili Petrouleas
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  7. Christopher J. Pickett
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Editor information

Editors and Affiliations

  1. University of Bielefeld, Bielefeld, Federal Republic of Germany

    Achim Müller

  2. Charles F. Kettering Research Laboratory, Yellow Springs, Ohio, USA

    William E. Newton

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© 1983 Plenum Press, New York

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Garner, C.D. et al. (1983). Iron-Molybdenum-Sulfur Clusters. In: Müller, A., Newton, W.E. (eds) Nitrogen Fixation. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8523-3_10

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  • DOI: https://doi.org/10.1007/978-1-4684-8523-3_10

  • Publisher Name: Springer, Boston, MA

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