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Conclusion

  • B. L. Erusalimskii
Part of the Macromolecular Compounds book series (MMCO)

Abstract

The format used here, which differs from that usually found in books on ionic polymerization, is the result of our intention of selecting problems of a general nature and preferring to examine the reactivity and the stereospecificity of active sites separately rather than jointly. It was also decided that a general summary should be given rather than detailed conclusions for each chapter. In such an undertaking we considered it necessary, together with the points already mentioned, to consider certain facts which have, for one reason or another, been omitted from the basic material.

Keywords

Cationic Polymerization Growth Reaction Ionic Polymerization Active Reagent Polar Monomer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    F. R. Mayo and M. Morton, “Ionic polymerization,” Khim. Tekhnol. Polym., No. 7, 12–15 (1965).Google Scholar
  2. 2.
    B. L. Erusalimskii, The Polarization of Polar Monomers [in Russian], Nauka, Leningrad (1970), pp. 280–286.Google Scholar
  3. 3.
    Japan—U.S. Seminar on Unsolved Problems in Ionic Polymerization, J. Macromol. Sci., Chem., A9, Nos. 5, 6 (1975), pp. 641–1083.Google Scholar
  4. 4.
    D. Lehmann, “Radiochemische Untersuchungen zum Mechanismus der Anionschen Polymerisation im System Acrylnitril-N, N-Dimethylformamid-Lithium-tert-Butanolat,” Dissertation, Dresden (1982).Google Scholar
  5. 5.
    S. Riedel, G. Wunderlich, D.Lehmann, R. Dreyer, W. Berger, and H.-J. Adler, “Radiochemische Untersuchungens über den Initiatoreinbau bei der Anionischen Polymerisation von Acrylnitril in DMF, V. Int. Mikrosymp. Fortschr. in Ionenpolymerisation, Prague (1982), prepr. 45.Google Scholar
  6. 6.
    W. Berger, S. Riedel, H.-J. Adler, D. Lehmann, G. Wunderlich, and O. Vogel, “Radiochemical investigations on the mechanism of the initiation of the acrylonitrile polymerization by lithium alkoxides in dimethylformamide,” J. Macromol. Sci., Chem., A20, 299–307 (1983).CrossRefGoogle Scholar
  7. 7.
    A. F. Podol’skii (Podolsky), A. G. Boldyrev, I. Yu. Sapurina, V. V. Shamanin, I. L. Ushakova, and N. G. Orlova, “The anomalous behavior of a paramagnetic sodium adduct of stilbene in disproportionation and initiation of polymerization in THF,” Acta Polym., 33, 181–184 (1982).CrossRefGoogle Scholar
  8. 8.
    A. F. Halasa, D. N. Schulz, D. P. Tate, and V. W. Mochel, “Organolithium catalysts and diene polymerization,” Adv. Organo-met. Chem., 18, 55–95 (1980).CrossRefGoogle Scholar
  9. 9.
    A. Wolf and H. H. Schmidtke, “All-electron SCF LCAO MO calculations on various conformations of cis-and trans-stilbene,” Theor. Chim. Acta (Berl.), 48, 37–45 (1978).CrossRefGoogle Scholar
  10. 10.
    B. L. Erusalimskii (Erussalimsky). Erusalimskii (Erussalimsky), “Structure and reactivity of anionic active centers, ” J. Polym. Sci., Polym. Symp., 62, 29–50 (1978).Google Scholar
  11. 11.
    C. D. Johnson, “The reactivity-selectivity principle: Fact or fiction?,” Tetrahedron, 36, 3461–3480 (1980).CrossRefGoogle Scholar
  12. 12.
    J. P. Kennedy and E. Marechal, Carbocationic Polymerization, Wiley, New York (1982).Google Scholar
  13. 13.
    M. Szwarc, “Living polymers and mechanisms of anionic polymerization,” Adv. Polym. Sci., 49, Springer Verlag, Berlin-Heidelberg (1983).CrossRefGoogle Scholar
  14. 14.
    B. A. Dolgoplosk and E. I. Tinyakova, Organometallic Catalysis in Polymerization [in Russian], Nauka, Moscow (1982).Google Scholar
  15. 15.
    G. Del Re, “Binding: A unifying notion or a pseudoconcept?,” Int. J. Quantum Chem., 19, 979–984 (1981).CrossRefGoogle Scholar

Copyright information

© Consultants Bureau, New York 1986

Authors and Affiliations

  • B. L. Erusalimskii
    • 1
  1. 1.Institute of Macromolecular CompoundsAcademy of Sciences of the USSRLeningradUSSR

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