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Chemical Reactions in Liquid Sodium and Liquid Lithium

  • Richard J. Pulham

Abstract

Lithium shows some significant differences from Na in its solvent properties and also in the chemical reactions which occur between dissolved solutes in the liquid metal. The elements N, H, C, Si and Ge are more soluble in lithium (N and H form eutectics) and the compounds which crystallize are more stable than their Na counterparts. Thus for compounds M = Li, Na, −ΔG298 values (kJ mol −1) are M2O 561.4 (1), 378.7 (1) or 375.6 (2); M3.N 128.6 (3), (87) (4); MH 70.1 (5), 38 (6); and M2C2 (56) (7), −21.0 (8). Values in parenthese are estimates and the present work gives ΔG873 Li2C2 = −89 kJ mol−1. The corresponding solubilities (appm non-metal) at 500 °C are M2O 800 (9), 1696 (10), M3N 34200 (11), <10−4 (12); MH 34400 (11)2, 8273 (13); and M2C2 210 (14), 1 (15). Consequently Li forms a more stable nitride which is soluble and reactive towards both non-metals and transition metals Li5TiN3 (16), Li2ZrN2 (17), Li7MN4, (M = V, Nb, Ta) (18), Li9MN5 (M = Cr, Mo, W) (19) and Li3FeN2 (20) are known and Li converts LiOH entirely to Li2O and LiH thereby virtually removing the equilibrium between OH, O2− and H- which exists in Na (21). The present work describes some reactions of C in Na and Li.

Keywords

Liquid Metal Liquid Sodium Liquid Lithium JANAF Thermochemical Table United Kingdom Introduction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1982

Authors and Affiliations

  • Richard J. Pulham
    • 1
  1. 1.University of NottinghamUK

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