Advertisement

Determination of The Formation Enthalpies of Sodium Alloys of Lithium with In, Tl, Sn, Pb and Bi

  • Ferdinand Sommer
  • Bernd Fischer
  • Bruno Predel

Abstract

The formation enthalpies in systems with lithium as the one alloy component are, at present, only known in a few cases, and in these cases they are affected with very large uncertainties (1). Doubtlessly this is due to experimental difficulties. However, the exact knowledge of the thermodynamic properties of such phases is important for the investigation of the formation conditions and the stability of these alloys. Therefore, a solution calorimeter has been constructed which is peculiarly suitable for the investi-gation of highly reactive alloys.

Keywords

Liquid Alloy Formation Enthalpy Excess Entropy Lithium Alloy Solution Enthalpy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    R. Hultgren, R. D. Desai, D. P. Hawkins, M. Gleiser and K. K. Kelley: Selected Values of the Thermodynamic Properties of the Binary Systems, ASM, eds., Metal Park, Ohio, 1973.Google Scholar
  2. 2.
    R. Hultgren, R. D. Desai, D. P. Hawkins, M. Gleiser, K. K. Kelley and D. D. Wagman: Selected Values of the Thermodynamic Properties of the Elements, ASM, eds., Metals Park, Ohio, 1973.Google Scholar
  3. 3.
    F. Sommer: In these proceedings.Google Scholar
  4. 4.
    O. Kubaschewski and W. Seith: Z. Electrochem., 1937, Vol. 43, pp. 743–749, 1941, Vol. 47, pp. 623–666; Z. Metallkde., 1938, Vol. 30, pp. 7–9.Google Scholar
  5. 5.
    O. Kubaschewski and W. Seith: Z. Electrochem., 1937, Vol. 43, pp. 743–749, 1941, Vol. 47, pp. 623–666; Z. Metallkde., 1938, Vol. 30, pp. 7–9.Google Scholar
  6. 6.
    O. Kubaschewski and W. Seith: Z. Electrochem., 1937, Vol. 43, pp. 743–749, 1941, Vol. 47, pp. 623–666; Z. Metallkde., 1938, Vol. 30, pp. 7–9.Google Scholar
  7. 7.
    O. Alpaut and Th. Heumann: Acta Met., 1965, Vol. 13, pp. 543–548.CrossRefGoogle Scholar
  8. 8.
    A. R. Miedema and P. F. de Chatel: Theory of Alloy Formation, 1979, Proceeding of a Symposium of the AIME Annual Meeting, ed. L.H. Bennet, New York, 1980, pp. 344–387.Google Scholar
  9. 9.
    W. Vogelbein, M. Ellner and B. Predel: Thermochim. Acta, 1981 (in print).Google Scholar
  10. 10.
    B. Predel and G. Oehme: Z. Metallkde., 1979, Vol. 70, pp. 450–453; pp. 618–623.Google Scholar
  11. 11.
    P. Chieux and H. Ruppersberg: J. de Physique Colloque C-8, 1980, pp. 145–152.Google Scholar
  12. 12.
    C. van der Marel, B. P. Albas, J. Hennephof, G.J.B. Vinke and W. van der Lugt: In these proceedings.Google Scholar
  13. 13.
    S. P. Yatsenko and E. A. Saltykova: Zhur. Fiz. Khim., 1975, Vol. 49, pp. 507 – 508; Elektrokhim., 1975, Vol. 11, pp. 580 – 581.Google Scholar
  14. 14.
    S. P. Yatsenko and E. A. Saltykova: Zhur. Fiz. Khim., 1975, Vol. 49, pp. 507 – 508; Elektrokhim., 1975, Vol. 11, pp. 580 – 581.Google Scholar
  15. 15.
    M. L. Saboungi, J. Marr and M. Blander: J. Chem. Phys., 1978, Vol. 68, pp. 1375 - 1384.CrossRefGoogle Scholar

Copyright information

© Plenum Press, New York 1982

Authors and Affiliations

  • Ferdinand Sommer
    • 1
    • 2
  • Bernd Fischer
    • 1
    • 2
  • Bruno Predel
    • 1
    • 2
  1. 1.Max-Planck Institut für MetallforschungInstitut für WerkstoffwissenschaftenStuttgartFed. Rep. of Germany
  2. 2.Institut für Metallkunde der UniversitätStuttgartFed. Rep. of Germany

Personalised recommendations