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ESR Study of Copper(II) and Silver(II) Tetraphenylporphyrin

  • P. T. Manoharan
  • Max T. Rogers

Abstract

Copper(II) tetraphenylporphyrin and silver(II) tetraphenylporphyrin have been studied by ESR spectroscopy using the pure solid materials, solutions, magnetically-diluted single crystals, and polycrystalline powders. It has been possible to obtain rather complete ESR data, including the hyperfine interaction tensors, for 14N, 6365Cu, and 107109Ag. The results have been used to estimate molecular orbital coefficients in these compounds and to discuss details of the chemical bonding.

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References

  1. 1.
    A. B. P. Lever, in: Advances in Inorganic Chemistry and Radiochemistry, Vol. 7, H. J. Emeleus and A. G. Sharpe, eds. (Academic Press, New York, 1965 ), p. 28.Google Scholar
  2. 2.
    J. E. Falk, Porphyrins and Metalloporphyrins ( Elsevier Publishing Co., New York, 1964 ).Google Scholar
  3. 3.
    D. J. E. Ingram, J. E. Bennett, P. George, and J. M. Goldstein, J. Am. Chem. Soc. 78, 3545 (1956).CrossRefGoogle Scholar
  4. 4.
    E. B. Fleischer, J. Am. Chem. Soc. 85, 1353 (1963); 85, 146 (1963).Google Scholar
  5. 5.
    J. L. Hoard, M. J; Hamor, and T. A. Hamor, J. Am. Chem. Soc. 85, 2334 (1963);CrossRefGoogle Scholar
  6. J. L. Hoard, M. J; Hamor, and T. A. Hamor, J. Am. Chem. Soc. 86, 1938 (1964).CrossRefGoogle Scholar
  7. 6.
    S. J. Silvers and A. Tulinsky, J. Am. Chem. Soc. 86, 927 (1964); 89, 3331 (1967).CrossRefGoogle Scholar
  8. 7.
    E. B. Fleischer, C. K. Miller, and L. E. Webb, J. Am. Chem. Soc. 86, 2342 (1964).CrossRefGoogle Scholar
  9. 8.
    G. Donnay and C. B. Storm, Molecular Crystals 2, 287 (1967).CrossRefGoogle Scholar
  10. 9.
    J. S. Griffith, Discussions Faraday Soc. 26, 81 (1958).CrossRefGoogle Scholar
  11. 10.
    E. M. Roberts and W. S. Koski, J. Am. Chem. Soc. 82, 3006 (1959).CrossRefGoogle Scholar
  12. 11.
    F. K. Kneübuhl, W. S. Koski, and W. S. Caughey, J. Am. Chem. Soc. 83, 1607 (1961).CrossRefGoogle Scholar
  13. 12.
    E. M. Roberts, W. S. Koski, and W. S. Caughey, J. Chem. Phys. 34, 591 (1961).CrossRefGoogle Scholar
  14. 13.
    D. Kivelson and S.-K. Lee, J. Chem. Phys. 41, 1896 (1964).CrossRefGoogle Scholar
  15. 14.
    A. MacGraph, C. B. Storm, and W. S. Koski, J. Am. Chem. Soc. 87, 1470 (1965).CrossRefGoogle Scholar
  16. 15.
    J. M. Assour, J. Chem. Phys. 43, 2477 (1965).CrossRefGoogle Scholar
  17. 16.
    E. M. Roberts and W. S. Koski, J. Am. Chem. Soc. 83, 1865 (1961).CrossRefGoogle Scholar
  18. 17.
    J. M. Assour and S. E. Harrison, Phys. Rev. 136, A1368 (1964).CrossRefGoogle Scholar
  19. 18.
    R. Neiman and D. Kivelson, J. Chem. Phys. 35, 156, 162 (1961).CrossRefGoogle Scholar
  20. 19.
    D. J. E. Ingram and J. E. Bennett, Nature 175, 130 (1955);Google Scholar
  21. D. J. E. Ingram and J. E. Bennet Discussions Faraday Soc. 26, 72 (1958).CrossRefGoogle Scholar
  22. 20.
    J. F. Gibson, D. J. E. Ingram, and D. Schonland, Discussions Faraday Soc. 26, 72 (1958).CrossRefGoogle Scholar
  23. 21.
    R. M. Deal, D. J. E. Ingram, and R. Srinivasan, in: Electronic Magnetic Resonance and Solid Dielectrics, R. Servant and A. Charru, eds. ( North-Holland Publishing Co., Amsterdam, 1964 ), p. 239.Google Scholar
  24. 22.
    J. M. Assour and W. K. Kahn, J. Am. Chem. Soc. 87, 207 (1965).CrossRefGoogle Scholar
  25. 23.
    M. Abkowitz, I. Chen, and J. H. Sharp, J. Chem. Phys. 48, 4561 (1968).CrossRefGoogle Scholar
  26. 24.
    G. D. Dorough, J. R. Miller, and F. M. Huennekens, J. Am. Chem. Soc. 73, 4315 (1951).CrossRefGoogle Scholar
  27. 25.
    C. Rimington, S. F. Mason, and O. Kennard, Spectrochim. Acta 12, 65 (1958).CrossRefGoogle Scholar
  28. 26.
    J. M. Goldstein, Ph.D. Dissertation, University of Pennsylvania, 1959.Google Scholar
  29. 27.
    A. Tulinsky, private communication.Google Scholar
  30. 28.
    R. N. Rogers and G. E. Pake, J. Chem. Phys. 33, 1107 (1960).CrossRefGoogle Scholar
  31. 29.
    B. Bleaney, Phil Mag. 42, 441 (1951).CrossRefGoogle Scholar
  32. 30.
    L. D. Kispert, Thesis, Michigan State University, 1966.Google Scholar
  33. 31.
    M. Zerner and M. Gouterman, Theoret. Chim. Acta 4, 44 (1966).CrossRefGoogle Scholar
  34. 32.
    A. Abragam and M. H. L. Pryce, Proc. Roy. Soc. (London) A206, 164 (1951);CrossRefGoogle Scholar
  35. A. Abragam and M. H. L. Pryce, Proc. Roy. Soc. (London) A205, 135 (1951).CrossRefGoogle Scholar
  36. 33.
    D. Kivelson and R. Neiman, J. Chem. Phys. 35, 149 (1961).CrossRefGoogle Scholar
  37. 34.
    H. R. Gersman and J. D. Swalen, J. Chem. Phys. 36, 3221 (1962).CrossRefGoogle Scholar
  38. 35.
    A. H. Maki and B. R. McGarvey. J. Chem. Phys. 29, 31, 35 (1958).CrossRefGoogle Scholar
  39. 36.
    R. D. Watson, private communication.Google Scholar
  40. 37.
    E. Clementi, IBM Research Reports, R256 (1963).Google Scholar
  41. 38.
    T. M. Dunn, Trans. Faraday Soc. 57, 1441 (1961).CrossRefGoogle Scholar
  42. 39.
    D. W. Thomas and A. E. Martell, Arch. Biochem. Biophys. 76, 286 (1958).CrossRefPubMedGoogle Scholar
  43. 40.
    M. Gouterman, J. Chem. Phys. 30, 1139 (1959).CrossRefGoogle Scholar
  44. 41.
    B. R. McGarvey, J. Phys. Chem. 71, 51 (1967).CrossRefGoogle Scholar
  45. 42.
    R. Pettersson and T. Vänngârd, Arkiv Kemi 17, 249 (1960).Google Scholar
  46. 43.
    J. M. Assour, J. Goldmacher and S. E. Harrison, J. Chem. Phys. 43, 159 (1965).CrossRefGoogle Scholar
  47. 44.
    C. M. Hurd and P. G. Coodin, J. Phys. Chem. Solids 28, 523 (1966).CrossRefGoogle Scholar

Copyright information

© Plenum Press, New York 1969

Authors and Affiliations

  • P. T. Manoharan
    • 1
  • Max T. Rogers
    • 1
  1. 1.Department of Chemistry, Michigan State UniversityEast LansingUSA

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