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Oxidation — Reduction Reactions of Ions with Molecules

  • E. T. Denisov

Abstract

Polar organic compounds (alcohols, ketones, hydroxy acids, acids) are oxidized by variable-valence ions (Co3+, Ce4+, Mn3+, VO 2 + ) through a one-electron mechanism with the formation of free radicals. In water, water-alcohol, and acetic acid solutions, the oxidation normally includes two stages. First, the organic compound enters into the internal coordination sphere of the ion-oxidant by way of an equilibrium reaction. Then, in this complex, the oxidation-reduction reaction takes place. The scheme of such a reaction is represented in simplified form as follows:
$$RH + M{e^{n + 1}}\overset K \leftrightarrows HR...M{e^{n + 1}}\xrightarrow{{{k_1}}}R \cdot + M{e^{n + }} + {H^ +}$$

Keywords

Binuclear Complex Copper Phthalocyanine Compound Condition Polar Organic Compound Trivalent Manganese 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© IFI/Plenum Data Company 1974

Authors and Affiliations

  • E. T. Denisov
    • 1
  1. 1.Institute of Chemical PhysicsMoscowUSSR

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