Alkali Metal Ozonides

  • Il’ya Ivanovich Vol’nov
  • A. W. Petrocelli

Abstract

In the course of studies on the reaction of ozone with anhydrous metal hydroxides, I. A. Kazarnovskii [1, 2] confirmed the formation of red-colored products which had been first reported at the turn of the century by a number of investigators [3, 4, 5]. These products represent a new class of compounds characterized by the presence of the O3 ion and classified as ozonides. The O3 ion has an odd number of electrons and, as a result, the ozonides are paramagnetic. They can be considered to be free radicals with high chemical reactivity and an unusally long lifetime. The existence of the O3 ion in these compounds has been established by x-ray studies [6], magnetic studies [1], electron paramagnetic resonance studies [7–10], and by spectroscopic studies [7].

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Copyright information

© Plenum Press 1966

Authors and Affiliations

  • Il’ya Ivanovich Vol’nov
    • 1
  • A. W. Petrocelli
    • 2
  1. 1.Laboratory of Peroxide Chemistry, N. S. Kurnakov Institute of General and Inorganic ChemistryAcademy of Sciences of the USSRMoscowUSSR
  2. 2.General Dynamics/Electric Boat DivisionChemistry and Chemical Engineering SectionGrotonUSA

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