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Peroxides of the Group Two Elements of the Periodic Table

  • Chapter
Peroxides, Superoxides, and Ozonides of Alkali and Alkaline Earth Metals

Abstract

All elements of the second group, with the exception of beryllium [1], form peroxide compounds. Peroxides of calcium, strontium, and barium belong to the M2+O2 2- type; while peroxides of magnesium, zinc, and cadmium, of general formula MO2 • xH2O, probably belong to the HO—M—OOH type where the covalent bond between the hydroperoxyl group and the metal atom is the same as that in the hydrogen peroxide molecule [2–4]. Radium peroxide, RaO2, the heat of formation of which is estimated as 150 kcal/mole [5], has not yet been produced.

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Authors and Affiliations

  1. Laboratory of Peroxide Chemistry, N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow, USSR

    Il’ya Ivanovich Vol’nov (Head)

  2. General Dynamics/Electric Boat Division, Chemistry and Chemical Engineering Section, Groton, Connecticut, USA

    A. W. Petrocelli (Chief)

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  1. Il’ya Ivanovich Vol’nov
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  1. General Dynamics/Electric Boat Division, Chemistry and Chemical Engineering Section, Groton, Connecticut, USA

    A. W. Petrocelli (Chief) (Chief)

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Vol’nov, I.I., Petrocelli, A.W. (1966). Peroxides of the Group Two Elements of the Periodic Table. In: Petrocelli, A.W. (eds) Peroxides, Superoxides, and Ozonides of Alkali and Alkaline Earth Metals. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8252-2_4

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