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Applications of 14N NMR Data in the Study of Inorganic Molecules

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Book cover Nitrogen NMR

Abstract

The foregoing chapters have indicated that in spite of inherent difficulties, 14N NMR spectroscopy has proved to be of considerable value in the study of nitrogen compounds. For example, the last few years have witnessed an extensive and rewarding application of the technique in organic chemistry (Chapter 4). Three recent general reviews [1–3] of nitrogen nuclear magnetic resonance including both 14N and 15N, show that less attention has been paid to the study of inorganic molecules and reasons for this neglect are readily apparent. A high proportion of inorganic compounds are solids of generally low solubility, yet the lower limit of concentration for observance of suitably intense 14N signals by direct continuous wave measurement is as high as ca. 1M. Even if a solvent can be found which shows little or no interaction with a nitrogen-containing inorganic solute, this level of solubility is frequently difficult or impossible to achieve. Valuable information can result from 14N NMR studies of solids (Section 6.4) but thus far, few studies of this type have been reported.

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  1. Department of Chemistry, University of Nottingham, Nottingham, England

    N. Logan

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  1. Institute of Organic Chemistry, Polish Academy of Science, Warsaw, Poland

    M. Witanowski

  2. Department of Chemical Physics, University of Surrey, Guidford, Surrey, England

    G. A. Webb

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Logan, N. (1973). Applications of 14N NMR Data in the Study of Inorganic Molecules. In: Witanowski, M., Webb, G.A. (eds) Nitrogen NMR. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8175-4_6

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