Electron Kinetics in Nonpolar Liquids — Energy and Pressure Effects
Just as electron mobilities differ for liquids that are otherwise similar in bulk properties, the rates of electron reactions often change by orders of magnitude from one nonpolar liquid to another. Both positive and negative activation energies are observed and, as shown recently, application of high pressure has large effects on electron kinetics (Munoz et al., 1987; Nishikawa et al., 1988). Clearly it is a challenge to fully understand this diversity of behavior, and a comprehensive theory to account for electron reactions is needed.
KeywordsNonpolar Solvent Electron Attachment Polarization Energy Ethyl Bromide Nonpolar Liquid
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