Electrical Aspects of Liquid/Vapor, Liquid/Liquid, and Liquid/Metal Interfaces

  • B. E. Conway
Part of the NATO ASI Series book series (NSSB, volume 193)


Manifestation of electrical behavior of interfaces depends in important ways on the type of liquid. Three principal types can be distinguished:
  1. a)

    metallic liquids, e. g., Hg, its amalgams, Ga;

  2. b)

    dipolar liquids, including H-bonded fluids; and

  3. c)

    non-polar liquids of spherical atoms or molecules, e.g., Ar, Ne, Ch4, etc.



Surface Potential Liquid Interface Metal Interface Hydration Energy Dipole Orientation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


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  1. Alfenaar, M., de Ligny, C., and Remijnse, 1967, Ree. Trav. Chim. F.B., 86:986.CrossRefGoogle Scholar
  2. Badiali, J.P., Rosinberg, H.L., and Goodisman, J., 1981, J. Electroanal. Chem., 130:31.CrossRefGoogle Scholar
  3. Bardeen, J., 1940, Phys. Rev., 58:727.ADSMATHCrossRefGoogle Scholar
  4. Bell, G.M., and Rangecroft, P.D., 1971, Trans. Faraday Soc., 67:649.CrossRefGoogle Scholar
  5. Bockris, J.O. M., Devanathan, M.A.V., and Muller, K., 1963, Proc. Roy. Soc., London, A274:55.ADSGoogle Scholar
  6. Conway, B.E., 1975, J. Electroanal. Chem., 65:691.CrossRefGoogle Scholar
  7. Conway, B.E., 1977, Adv. Coll. Interface. Sci., 8:91.CrossRefGoogle Scholar
  8. Conway, B.E., and Dhar, H.P., 1973, Croatica Chem. Croatica Chem. Acta, 45:173.Google Scholar
  9. Cox, B.G., Parker, A.J., and Waghorne, W.E., 1973, J. Amer. Chem. Soc., 95:1010.CrossRefGoogle Scholar
  10. Cutler, P.H., and Gibbons, J.J., 1958, Phys. Rev., 111:394.ADSCrossRefGoogle Scholar
  11. Cutler, P.H., and Davis, J.C., 1964, Surface Sci., 1:194.ADSCrossRefGoogle Scholar
  12. Equiluz, A.G., 1984, Phys. Rev., 30:4366.ADSCrossRefGoogle Scholar
  13. Fawcett, W.R., 1978, J. Chem. Phys., 82:1385.CrossRefGoogle Scholar
  14. Feldman, V.J., Partenskii, H.B., and Vorobev, M.M., 1986, Progress in Surface Science, 23:3ADSCrossRefGoogle Scholar
  15. Fermi, E., 1927, Rind. Acad. Lincei, 6:602.Google Scholar
  16. Frank, H.S., and Evans, M., 1945, J. Chem. Phys, 13:507.ADSCrossRefGoogle Scholar
  17. Frumkin, A.N., 1924, Zeit. Phys. Chem, 109:34.Google Scholar
  18. Frumkin, A.N., 1926, Koll. Zeit., 39:8.CrossRefGoogle Scholar
  19. Frumkin, A.N., and Williams, J.W., 1929, Proc. Natl. Acad. Sci, U.S.A., 15:400.ADSCrossRefGoogle Scholar
  20. Frumkin, A.N., and Damaskin, B.B., 1974, Electrochim. Acta, 19:173.CrossRefGoogle Scholar
  21. Gomer, R., and Swanson, L.W., 1963, J. Chem. Fhys., 38:1613.ADSCrossRefGoogle Scholar
  22. Gottesfeld, S., Conway, B.E., and Dhar, H.P., 1973, J. Coll. Interface, Sci., 43:303.CrossRefGoogle Scholar
  23. Grahame, D.C., 1947, Chem. Rev., 47:447.Google Scholar
  24. Guggenheim, E.A., 1940, Trans. Faraday Soc., 36:397.CrossRefGoogle Scholar
  25. Hamelin, A., 1986, Chapter I in Modern Aspects of Electrochemistry, Eds. B.E. Conway, J.O’M. Bockris, and R. White, Plenum Publ. Corp., N.Y.Google Scholar
  26. Jarvis, N.J., and Schieman, M.A., 1968, J. Chem. Phys., 72:74.CrossRefGoogle Scholar
  27. Jones, G., and Ray, W.A., 1937, J. Amer. Chem. Soc., 59:181.CrossRefGoogle Scholar
  28. Jones, G., and Ray, W.A., 1941, J. Amer. Chem. Soc., 63:288.CrossRefGoogle Scholar
  29. Juretschke, H., 1953, Phys. Rev., 92:1140.ADSMATHCrossRefGoogle Scholar
  30. Kaganovich, R.I., and Gerovich, V.M., 1966, Elektrokhimiya, 2:977.Google Scholar
  31. Kemball, C., 1947, Proc. Roy. Soc., London, A188:117.ADSGoogle Scholar
  32. Kenrick, F.B., 1896, Zeit. Phys. Chem., 19:625.Google Scholar
  33. Kornyshev, A.A., Rubinshtein, A.I., and Vorotyntsev, M.A., 1977, Phys. Stat. Solid, b84:125.ADSCrossRefGoogle Scholar
  34. Kornyshev, A.A., Partenskii, M.B., and Schmickler, W., 1984. Zeit. Naturfonch, 39a:1122.ADSGoogle Scholar
  35. Ku, N.Y., and Ullmann, F.G., 1964, J. Appl. Phys., 35:265.ADSCrossRefGoogle Scholar
  36. Lang, N.D., and Kohn, W., 1973, Phys. Rev., B7:3541.ADSGoogle Scholar
  37. Lang, N.D., and Williams, A.R., 1978, Phys. Rev., B18:616.ADSGoogle Scholar
  38. Lang, N.D., 1981, Phys. Rev., 46:842.ADSGoogle Scholar
  39. Lange, E., and Miscenko, S., 1930, Zeit, Phys. Chem., 149:1.Google Scholar
  40. Lange, E., 1951, Zeit. Elektrochem., 55:76.Google Scholar
  41. Levine, S., Bell, G.M., and Smith, A.L., 1969, J. Phys. Chem., 73:3534.CrossRefGoogle Scholar
  42. Marshall, S., and Conway, B.E., 1984. J. Chem. Phys., 81:923.ADSCrossRefGoogle Scholar
  43. Mclntyre, J.D., and Peck, M., 1973, Disc. Faraday Soc., 56:122.CrossRefGoogle Scholar
  44. Mignolet, J.C.P., 1950, Disc. Faraday Soc., 8:105; 1953, J. Chem. Phys., 21:1298.Google Scholar
  45. Morcos, I., 1971, J. Chem. Phys., 55:4125.ADSCrossRefGoogle Scholar
  46. Morcos, I., 1972, J. Chem. Phyl., 56:3996.ADSCrossRefGoogle Scholar
  47. Onsager, L. and Samaras, W.N.T., 1934, J. Chem. Phys., 2:528.ADSCrossRefGoogle Scholar
  48. Parsons, R., 1954, Chapter 3 in Modern Aspects of Electrochemistry, Ed. J.O.M. Bockris, Butterworths, London.Google Scholar
  49. Parsons, R., 1975, J. Electroanal. Chem., 59:229.CrossRefGoogle Scholar
  50. Partenskii, M.B., Porov, E.I., and Kuzema, V.E., 1976, Fiz, Metalov I Metalovedenie, 41:280.Google Scholar
  51. Randies, J.E.B., 1963, Adv. Electrochem. and Electrochem. Eng., Eds., P. Delahay, and C. Tobias, 3:1 John Wiley and Sons, N. Y.Google Scholar
  52. Randies, J.E.B. and Whiteley, K.W., 1956, Trans. Faraday Soc., 52:1509.CrossRefGoogle Scholar
  53. Rice, O.K., 1928, Phys. Rev., 31:1051.ADSCrossRefGoogle Scholar
  54. Sachs, R.G., and Dexter, D.C., 1950, J. Appl. Phys., 21:1304.MathSciNetADSMATHCrossRefGoogle Scholar
  55. Samec, Z, Marecek, V., Koryta, J., and Khali1, M.W., 1977, J. Electroanal. Chem., 83:393.CrossRefGoogle Scholar
  56. Samec, Z., 1979, J. Electroanal. Chem., 99:197.CrossRefGoogle Scholar
  57. Samec, Z., Marecek, V., and Weber, J., 1979a, J. Electroanal. Chem., 96:245.CrossRefGoogle Scholar
  58. Samec, Z., Marecek, V., and Weber, J., 1979b, J. Electrochem. Chem., 100:841.CrossRefGoogle Scholar
  59. Schmickler, W., 1979, J. Electroanal. Chem., 100:533.CrossRefGoogle Scholar
  60. Schmickler, W., 1983, J. Electroanal. Chim., 150:19.CrossRefGoogle Scholar
  61. Schmickler, W. and Henderson, D., 1984, J. Electroanal. Chem., 176:383.CrossRefGoogle Scholar
  62. Schultze, J.W., and Vetter, K., 1973, J. Electroanal. Cheiut 44:83.CrossRefGoogle Scholar
  63. Slater, J.C., 1939, Introduction to Chemical Physics, McGraw Hill, N. Y.Google Scholar
  64. Stillinger, R.H., and Ben-Naim, A., 1967, J. Chem. Phys., 47:4431.Google Scholar
  65. Thomas, L.H., 1926, Proc. Cambridge Phil. Soc., 23:542.ADSCrossRefGoogle Scholar
  66. Tsong, T.T., and Muller, E.W., 1969, Phys. Rev, 181:530.ADSCrossRefGoogle Scholar
  67. Wagner, C., 1924, Phys. Zeit., 25:474.Google Scholar
  68. Watts-Tobin, R.J., and Mott, N.F., 1961, Electrochem. Acta., 4:79; Phil. Mag., 6:133.ADSCrossRefGoogle Scholar
  69. Young, T., 1805, Phil. Trans. Roy. Soc., London, p.84.Google Scholar

Copyright information

© Plenum Press, New York 1988

Authors and Affiliations

  • B. E. Conway
    • 1
  1. 1.Chemistry DepartmentUniversity of OttawaOttawaCanada

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