Jahn-Teller Resonance States in the Vb Metal Hydrides

  • G. C. Abell
Part of the NATO Conference Series book series (NATOCS, volume 6)

Abstract

A hamiltonian with a localized Jahn-Teller electron-phonon interaction plus a band-coupling term belonging to a metal cluster state adjacent to interstitial hydrogen in the Vb metals is presented. It is shown that in a low-frequency approximation, this hamiltonian is analogous to the Anderson Hamiltonian for magnetic impurities in metals. The role of hydrogen in triggering the Jahn-Teller instability is explained in the context of the Hartree-Fock solutions of the low-frequency hamiltonian, using a ‘phase diagram’ in the Hartree-Fock parameter space. An elastic susceptibility expression is derived and compared with an observed elastic relaxation. The empirical connection of the Jahn-Teller distortion to the observed elastic dipole tensor is reconsidered.

Keywords

Magnetite Eter Hydride 

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Copyright information

© Plenum Press, New York 1983

Authors and Affiliations

  • G. C. Abell
    • 1
  1. 1.MRC-MoundMiamisburgUSA

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