High Pressure Studies of Solvent Effects on a Halide Exchange Reaction

  • P. G. Glugla
  • J. H. Byon
  • C. A. Eckert


Kinetic solvent effects on chemical reactions are most pro-nounced when one or more of the reacting species is ionized, and may amount to several orders of magnitude [1]. In spite of the importance of this phenomenon, and after considerable effort to understand it over many years [2–4], no real quantitative or even good qualitative picture has emerged. The advent of high-accuracy high-pressure kinetic measurements provides a new tool with which to attack this problem.


Partial Molal Volume Aprotic Solvent Transition State Theory Methylisobutyl Ketone Dipolar Aprotic Solvent 
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Copyright information

© Springer Science+Business Media New York 1979

Authors and Affiliations

  • P. G. Glugla
    • 1
  • J. H. Byon
    • 1
  • C. A. Eckert
    • 1
  1. 1.University of IllinoisUrbanaUSA

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