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High Pressure Studies of Solvent Effects on a Halide Exchange Reaction

  • P. G. Glugla
  • J. H. Byon
  • C. A. Eckert

Abstract

Kinetic solvent effects on chemical reactions are most pro-nounced when one or more of the reacting species is ionized, and may amount to several orders of magnitude [1]. In spite of the importance of this phenomenon, and after considerable effort to understand it over many years [2–4], no real quantitative or even good qualitative picture has emerged. The advent of high-accuracy high-pressure kinetic measurements provides a new tool with which to attack this problem.

Keywords

Partial Molal Volume Aprotic Solvent Transition State Theory Methylisobutyl Ketone Dipolar Aprotic Solvent 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1979

Authors and Affiliations

  • P. G. Glugla
    • 1
  • J. H. Byon
    • 1
  • C. A. Eckert
    • 1
  1. 1.University of IllinoisUrbanaUSA

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