Pressure Effects in Inorganic Solution Chemistry

  • T. W. Swaddle

Abstract

A metal cation M in Solution can be pictured as being surrounded by a geometrically well-defined first coordination sphere (c.s.) consisting of ligands L and X (which could be solvent molecules, Sol) and a second c.s. of centripetally-oriented Sol and possibly other species Y; beyond the second c.s. lies bulk solvent which may contain free Y. In this paper, we consider the contribution of the study of pressure effects to the understanding of the mechanism of exchange of X, Y, L, and Sol between these three regions.

Keywords

Enthalpy DMSO Cobalt Hunt Compressibility 

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References

  1. 1.
    D. R. Stranks, Pure Appl. Chem. 38, 303 (1974).CrossRefGoogle Scholar
  2. 2.
    C. H. Langford and H. B. Gray, Ligand Substitution Processes, W. A. Benjamin, New York (1966).Google Scholar
  3. 3.
    T. W. Swaddle, Coord. Chem. Rev. 14, 217 (1974).CrossRefGoogle Scholar
  4. 4.
    S. T. D. Lo, E. M. Oudeman, J. C. Hansen, and T. W. Swaddle, Can. J. Chem. 54, 3685 (1976).CrossRefGoogle Scholar
  5. 5.
    T. W. Swaddle, Can. J. Chem. 55, 3166 (1977).CrossRefGoogle Scholar
  6. 6.
    H. R. Hunt and H. Taube, J. Am. Chem. Soc. 80, 2642 (1958).CrossRefGoogle Scholar
  7. 7.
    D. R. Stranks and T. W. Swaddle, J. Am. Chem. Soc. 93, 2783 (1971).CrossRefGoogle Scholar
  8. 8.
    D. A. Palmer and H. Keim, Inorg. Chim. Acta. 19, 117 (1976).CrossRefGoogle Scholar
  9. 9.
    D. R. Stranks and N. Vanderhoek, Inorg. Chem. 15, 2639 (1976).CrossRefGoogle Scholar
  10. 10.
    W. E. Jones, L. R. Carey, and T. W. Swaddle, Can. J. Chem. 50, 2739 (1972).CrossRefGoogle Scholar
  11. 11.
    M. C. Weekes and T. W. Swaddle, Can. J. Chem. 53, 3697 (1975).CrossRefGoogle Scholar
  12. 12.
    A. Jost, Ber. Bunsenges. phys. Chem. 80, 316 (1976).CrossRefGoogle Scholar
  13. 13.
    B. B. Hasinoff, Can. J. Chem. 54, 1820 (1976).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1979

Authors and Affiliations

  • T. W. Swaddle
    • 1
  1. 1.The University of CalgaryCalgaryCanada

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