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Chemically Reacting SiO2, H2O, and SiO2 + H2O Systems under High Pressure and Temperature

  • F. H. Ree

Abstract

When we simulate dynamic physical processes with a computer, we must know the equation of state (EOS) for the materials in question. The more accurate the equation of state, the closer the program can simulate the physical reality. This study was undertaken to obtain equation of state expressions for silicon dioxide (SiO2), water (H2O), and SiO2 + H2O mixture. Such expressions are of primary interest to the designers of underground nuclear tests because cavity size, pressure, and other seismic disturbances of the explosion depend on the state properties of rock media. To date, a rather crude EOS expression (such as an ideal-gas law) has been used to satisfy an actual need.

Keywords

Gaseous Species Lawrence Livermore Laboratory Condensed Species Seismic Disturbance Underground Nuclear Test 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    F. H. Ree, “Equation of State of the Silcon Dioxide System,” Lawrence Livermore Laboratory Rept. UCRL-52153 (1976), unpublished work.Google Scholar
  2. 2.
    F. H. Ree, “Equation of State of Water,” Lawrence Livermore Laboratory Rept. UCRL-52190 (1976), unpublished work.Google Scholar
  3. 3.
    R. D. Cowan and W. Fickett, J. Chem. Phys. 24, 932 (1956).CrossRefGoogle Scholar
  4. 4.
    G. A. Gurtman, J. W. Kirsch, and C. R. Hastings, J. Appl. Phys. 42, 851 (1971).CrossRefGoogle Scholar
  5. 5.
    D. R. Stull and H. Prophets, eds., “JANAF Thermochemical Data,” 2nd ed. NSRD-NBS 37 (1971).Google Scholar
  6. 6.
    M. Cowperthwaite and W. H. Zwisler, “TIGER Program Documentation,” Stanford Research Institute, Publication No. Z106, Vol. I ( 1973 ), Vols. II-IV (1974).Google Scholar
  7. 7.
    F. P. Bundy, J. Chem. Phys. 41, 3809 (1964).CrossRefGoogle Scholar
  8. 8.
    R. G. McQueen, J. N. Fritz, and S. P. Marsh, J. Geophys. Res. 69, 2947 (1964).CrossRefGoogle Scholar
  9. 9.
    F. Birch, J. Geophys. Res. 69, 4377 (1964).CrossRefGoogle Scholar
  10. 10.
    B. J. Alder, J. Geophys. Res. 71, 4973 (1966).CrossRefGoogle Scholar
  11. 11.
    J. Shaner and W. Gust, private communication.Google Scholar
  12. 12.
    E. Schmidt, Properties of Water in SI-Units Springer-Verlag, Inc., New York (1969).Google Scholar
  13. 13.
    C. W. Burnham, J. R. Holloway, and N. F. Davis, “Thermodynamic Properties of H2O to 1000C and 1 kbar,” The Geological Society of America Special Paper No. 132 (1969).Google Scholar

Copyright information

© Springer Science+Business Media New York 1979

Authors and Affiliations

  • F. H. Ree
    • 1
  1. 1.Lawrence Livermore LaboratoryUniversity of CaliforniaLivermoreUSA

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