Rovibrational Spectroscopy of ArCo Van Der Waals Complex

  • Edward J. Campbell
  • Anne De Piante
  • Steven J. Buelow


The information that can be obtained from the high resolution rovibrational spectra of small molecular clusters is very useful for determining intermolecular potentials and the effects of intermolecular interactions on intramolecular bonds. Recently, such spectra have been obtained via absorption measurements using F-center[1,2], frequency difference [3,4] and diode laser[5] sources. Because F-center and frequency difference lasers operate best in the 2–4 μm region, studies using these laser sources have involved high frequency vibrational modes (H-X, X=C,F,Cl,Br) or overtones. Although diode lasers cover a much broader spectral range (3–20 μm), they are less convenient to use for doing survey spectroscopy. We have developed several new techniques which improve the sensitivity and convenience of absorption measurements using diode lasers for the study of molecular clusters in supersonic expansions. Here we describe these techniques and their application for the measurement of the rovibrational spectra of ArCO near 5 μm.


Diode Laser Broad Spectral Range Energy Level Spacing InSb Detector Boxcar Integrator 
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Copyright information

© Plenum Press, New York 1988

Authors and Affiliations

  • Edward J. Campbell
    • 1
  • Anne De Piante
    • 1
  • Steven J. Buelow
    • 1
  1. 1.Chemistry and Laser Sciences DivisionLos Alamos National LaboratoryLos AlamosUSA

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