Skip to main content

Use of Neutron Beams in Studying Vibrational Modes of Molecules Adsorbed on Catalysts

  • Chapter
Fundamental Aspects of Heterogeneous Catalysis Studied by Particle Beams

Part of the book series: NATO ASI Series ((NSSB,volume 265))

Abstract

When one looks over the different types of instruments available around a high flux reactor (e.g. ref. 1), it immediately appears that neutron based techniques cover a wide range of applications. There are two main classes of instruments : elastic scattering instruments which are used for determining the structure of materials, and inelastic scattering spectrometers which, by measuring energy transfers, give information on atomic and molecular motions. Therefore, leaving aside fundamental and nuclear physics, the applications of neutron scattering to condensed matter include crystal and magnetic structures, molecular dynamics, disordered materials, colloids, polymers, structural excitations, biology, etc.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

eBook
USD 16.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Neutron Research Facilities at the ILL High Flux Reactor (Internal Scientific Report, Institut Laue Langevin, 1986).

    Google Scholar 

  2. J.W. White, in “Dynamics of Solids and Liquids by Neutron Scattering, ” (S.W. Lovesey and T. Springer Eds.) p. 197, Springer-Verlag, New York (1977).

    Google Scholar 

  3. R.K. Thomas, Prog. Solid St. Chem. 14, 1 (1982).

    Article  CAS  Google Scholar 

  4. C.J. Wright and C.M. Sayers, Rep. Prog. Phys. 46, 773 (1983).

    Article  Google Scholar 

  5. R.R. Cavanagh, J.J. Rush and R.D. Kelley, in “Vibrational Spectroscopy of Molecules on surfaces”, (J.T. Yates Jr. and T.E. Madey, Eds.) p. 183, Plenum, New York (1987).

    Google Scholar 

  6. H. Jobic, in “Physical Techniques in the Study of Catalysts”, (B. Imelik and J.C. Védrine, Eds.), Plenum, in press.

    Google Scholar 

  7. I.I. Gurevich and L.V. Tarasov, Low-Energy Neutron Physics, North-Holland, Amsterdam (1968).

    Google Scholar 

  8. H. Boutin and S. Yip, Molecular Spectroscopy with Neutrons, M.I.T. Press, Cambridge (1968).

    Google Scholar 

  9. W. Marshall and S. Lovesey, Theory of Thermal Neutron Scattering, Oxford University Press (1971).

    Google Scholar 

  10. G.L. Squires, Introduction to the Theory of Thermal Neutron Scattering, Cambridge University Press (1978).

    Google Scholar 

  11. A.C. Levi and H. Suhl, Surface Sci. 88, 221 (1979).

    Article  CAS  Google Scholar 

  12. A.C. Zemach and R.J. Glauber, Phys. Rev. 101, 118 (1956).

    Article  CAS  Google Scholar 

  13. J. Tomkinson, M. Warner and A.D. Taylor, Molec. Phys. 51, 381 (1984).

    Article  CAS  Google Scholar 

  14. J. Howard, J.M. Nicol, B.C. Boland, J. Tomkinson, J. Eckert, JA Goldstone and A.D. Taylor, Molec. Phys. 53, 323 (1984).

    Article  CAS  Google Scholar 

  15. H. Jobic, J. Chem. Phys. 76, 2693 (1982).

    Article  CAS  Google Scholar 

  16. A. Griffin and H. Jobic, J. Chem. Phys. 75, 5940 (1981).

    Article  CAS  Google Scholar 

  17. M. Warner, S.W. Lovesey and J. Smith, Z. Physik В 51, 109 (1983).

    CAS  Google Scholar 

  18. HJ. Lauter and H. Jobic, Chem. Phys. Lett. 108, 393 (1984).

    Article  CAS  Google Scholar 

  19. J. Penfold and J. Tomkinson, Rutherford Appleton Lab. Rep. RAL-86–019 (1986).

    Google Scholar 

  20. W.B. Neiligan, D.J. Lepoire, C.K. Loong, T.O. Brun and S.H. Chen, Nucl. Instrum. Meth. Phys. Res. A 254, 563 (1987).

    Article  Google Scholar 

  21. H. Jobic and H.J. Lauter, J. Chem. Phys. 88, 5450 (1988).

    Article  CAS  Google Scholar 

  22. J. Tomkinson and G.J. Kearley, J. Chem. Phys. 91, 5164 (1989).

    Article  CAS  Google Scholar 

  23. R.G. Sachs and E. Teller, Phys. Rev. 60, 18 (1941).

    Article  CAS  Google Scholar 

  24. T.J. Krieger and M.S. Nelkin, Phys. Rev. 106, 290 (1957).

    Article  CAS  Google Scholar 

  25. A. Sjölander, Ark. Fys. 14, 315 (1958).

    Google Scholar 

  26. W. Langel, D.L Price, R.O. Simmons and P.E. Sokol, Phys. Rev. В 38, 11275 (1988).

    Article  CAS  Google Scholar 

  27. J. Tomkinson, Chem. Phys. 127, 445 (1988).

    Article  CAS  Google Scholar 

  28. R.S. Holt, LM. Needham and M.P. Paoli, Phys. Letters, 126 A, 373 (1988).

    Google Scholar 

  29. R. Rauh and N. Watanabe, Phys. Letters 100 A, 244 (1984).

    CAS  Google Scholar 

  30. H. Jobic, Chem. Phys. Lett. 170, 217 (1990).

    Article  CAS  Google Scholar 

  31. E.B. Wilson, J.C. Decius and P.C. Cross, Molecular Vibrations, Mc Graw-Hill, New York (1955).

    Google Scholar 

  32. N. Bjerrum, Verhandl-deut. physik. Ges. 16, 737 (1914) ;

    Google Scholar 

  33. R.G. Snyder, J.H. Schachtschneider, Spectrochim. Acta 21, 169 (1965).

    Article  CAS  Google Scholar 

  34. H.C. Urey and C.A. Bradley, Phys. Rev. 38, 1969 (1931).

    Article  CAS  Google Scholar 

  35. S. Lifson and A. Warshel, J. Chem. Phys. 49, 5116 (1968).

    Article  CAS  Google Scholar 

  36. ISIS Annual Report, Rutherford Appleton Lab. (1989).

    Google Scholar 

  37. A.D. Taylor, E.J. Wood, J.A. Goldstone and J. Eckert, Nucl. Instrum. Meth. Phys. Res. 221, 408 (1984).

    Article  CAS  Google Scholar 

  38. P.S. Goyal, J. Penfold and J. Tomkinson, Rutherford Appleton Lab. Rep. RAL-86–070(1986).

    Google Scholar 

  39. R. Stockmeyer, H. Stortnik, I. Natkaniec and J. Mayer, Ber. Bunsenges. Phys. Chem. 84, 79 (1980).

    CAS  Google Scholar 

  40. H. Jobic, G. Clugnet and A. Renouprez, J. Elec. Spect. Relat. Phenom. 45, 281 (1987).

    Article  CAS  Google Scholar 

  41. R. Stockmeyer, H. Conrad, A. Renouprez and P. Fouilloux, Surf. Sci. 49, 549 (1975).

    Article  CAS  Google Scholar 

  42. A.J. Renouprez, P. Fouilloux, G. Coudurier, D. Tocchetti and R. Stockmeyer, J. Chem. Soc, Faraday Trans. 1, 73, 1 (1977).

    Google Scholar 

  43. R.R. Cavanagh, R.D. Kelley and J.J. Rush, J. Chem. Phys. 77, 1540 (1982).

    Article  CAS  Google Scholar 

  44. H. Jobic and A. Renouprez, J. Chem. Soc, Faraday Trans. 1, 80, 1991 (1984).

    Google Scholar 

  45. J. Howard, T.C. Waddington and C.J. Wright, Chem. Phys. Lett. 56, 258 (1978).

    Article  CAS  Google Scholar 

  46. I.J. Braid, J. Howard and J. Tomkinson, J. Chem. Soc, Faraday Trans. 2, 79, 253(1983).

    Google Scholar 

  47. H. Jobic, J.P. Candy, V. Perrichon and A. Renouprez, J. Chem. Soc, Faraday Trans. 1, 81, 1955(1985).

    Google Scholar 

  48. H. Jobic and A.J. Renouprez, J. Less-Common Met. 129, 311 (1987).

    Article  CAS  Google Scholar 

  49. J.M. Nicol, J.J. Rush and R.D. Kelley, Surf. Sci. 197, 67 (1988).

    Article  CAS  Google Scholar 

  50. J. Howard, T.C. Waddington and C.J. Wright, in “Neutron Inelastic Scattering”, Vol. II (IAEA, Vienna), p. 499 (1978).

    Google Scholar 

  51. J.J. Rush, R.R. Cavanagh, R.D. Kelley and J.M. Rowe, J. Chem. Phys. 83, 5339 (1985).

    Article  CAS  Google Scholar 

  52. A.J. Renouprez and H. Jobic, J. Catal. 113, 509 (1988).

    Article  CAS  Google Scholar 

  53. C.J. Wright, C. Sampson, D. Fraser, R.B. Moyes, P.B. Wells and C. Riekel, J. Chem. Soc, Faraday Trans. 1, 76, 1585 (1980).

    Google Scholar 

  54. CF. Sampson, J.M. Thomas, S. Vasudevan and C.J. Wright, Bull. Soc. Chim. Beiges, 90, 1215(1981).

    Article  CAS  Google Scholar 

  55. P.N. Jones, E. Knözinger, W. Langel, R.B. Moyes and J. Tomkinson, Surf. Sci. 207, 159(1988).

    Article  CAS  Google Scholar 

  56. C.J. Wright, D. Fraser, R.B. Moyes and P.B. Wells, Appl. Catal. 1, 49 (1981).

    Article  CAS  Google Scholar 

  57. C.J. Wright, C Riekel, R. Schöllhorn and B.C. Tofield, J. Solid State Chem. 24, 219(1978).

    Article  CAS  Google Scholar 

  58. C Riekel, H.G. Reznik, R. Schöllhorn and C.J. Wright, J. Chem. Phys. 70, 5203 (1979).

    Article  CAS  Google Scholar 

  59. W.H. Heise, K.Lu, Y.J. Kuo, T.J. Udovic, J.J. Rush and B.J. Tatarchuk, J. Phys. Chem. 92, 5184 (1988).

    Article  CAS  Google Scholar 

  60. C.J. Wright, J. Solid State Chem. 20, 89 (1977).

    Article  CAS  Google Scholar 

  61. P.G. Dickens, J.J. Birtill and C.J. Wright, J. Solid State Chem. 28, 185 (1979).

    Article  CAS  Google Scholar 

  62. J. Howard, I.J. Braid and J. Tomkinson, J. Chem. Soc, Faraday Trans. 1, 80, 225(1984).

    Google Scholar 

  63. C.J. Wright, J. Chem. Soc, Faraday Trans. 2, 73, 1497 (1977).

    Google Scholar 

  64. D. Graham, J. Howard and T.C. Waddington, J. Chem. Soc, Faraday Trans. 1, 79, 1281 (1983).

    Google Scholar 

  65. CM. Sayers, J. Phys. C, Solid State Phys. 16, 2381 (1983).

    Article  CAS  Google Scholar 

  66. CM. Sayers, Surf. Sci., 143, 411 (1984).

    Article  CAS  Google Scholar 

  67. CM. Sayers and C.J. Wright, J. Chem. Soc, Faraday Trans. 1, 80, 1217 (1984).

    Google Scholar 

  68. B. Voigtlander, S. Lehwald and H. Ibach, Surf. Sci. 208, 113 (1989).

    Article  Google Scholar 

  69. P.A. Karlsson, A.S. Martensson, S. Anderson and P. Nordlander, Surf. Sci. 175, L 759 (1986).

    Article  CAS  Google Scholar 

  70. J.T. Richardson and T.S. Cale, J. Catal. 102, 419 (1986).

    Article  CAS  Google Scholar 

  71. H. Jobic et al. (unpublished results).

    Google Scholar 

  72. A.S. Martensson, C. Nyberg and S. Anderson, Surf. Sci. 205, 12 (1988).

    Article  Google Scholar 

  73. J.W. White and C.J. Wright, J. Chem. Soc. A, 2843 (1971).

    Google Scholar 

  74. J.W. White and C.J. Wright, J. Chem. Soc, Faraday Trans. 2, 68, 1423 (1972).

    Google Scholar 

  75. D. Graham, J. Howard and T.C. Waddington, J. Chem. Soc, Faraday Trans. 1, 79, 1281 (1983).

    Google Scholar 

  76. D. Graham, J. Howard, T.C Waddington and J. Tomkinson, J. Chem. Soc, Faraday Trans. 2, 79, 1713 (1983).

    Google Scholar 

  77. H. Jobic, J. Tomkinson and A. Renouprez, Mol. Phys. 39, 989 (1980).

    Article  CAS  Google Scholar 

  78. J. Howard, K. Robson and T.C. Waddington, J. Chem. Soc, Dalton Trans. 967 (1982).

    Google Scholar 

  79. J. Howard, T.C. Waddington and C.J. Wright, J. Chem. Soc, Faraday Trans. 2, 73, 1768(1977).

    Google Scholar 

  80. H. Jobic, J. Mol. Struct. 131, 167 (1985).

    Article  CAS  Google Scholar 

  81. G.J. Kearley, J. Chem. Soc, Faraday Trans. 2, 82, 41 (1986).

    Google Scholar 

  82. M.J.S. Dewar, Bull. Soc Chim. Fr. 18, C71 (1951);

    Google Scholar 

  83. M.J.S. Dewar and G.F. Ford, J. Am. Chem. Soc 101, 783 (1979).

    Article  CAS  Google Scholar 

  84. J. Chatt and LA. Duncanson, J. Chem. Soc. 2339 (1953).

    Google Scholar 

  85. J. Hiraishi, Spectrochim. Acta, Part A, 25, 749 (1969).

    Article  CAS  Google Scholar 

  86. E. Yagasaki and R.I. Masel, Surf. Sci. 222, 430 (1989).

    Article  CAS  Google Scholar 

  87. J. Howard, T.C. Waddington and C.J. Wright, J. Chem. Soc, Faraday Trans. 2, 73, 1768(1977).

    Google Scholar 

  88. H. Jobic, J. Tomkinson, J.P. Candy, P. Fouilloux and A. Renouprez, Surf. Sci. 95, 496(1980).

    Article  CAS  Google Scholar 

  89. H. Jobic and A. Renouprez, Surf. Sci. 111, 53 (1981).

    Article  CAS  Google Scholar 

  90. A. Renouprez, G. Clugnet and H. Jobic, J. Catal. 74, 296 (1982).

    Article  CAS  Google Scholar 

  91. J.C. Bertolini and J. Rousseau, Surf. Sci. 78, 577 (1978).

    Article  Google Scholar 

  92. D. Graham and J. Howard, J. Chem. Soc, Faraday Trans. 1, 80, 3365 (1984).

    Google Scholar 

  93. Z. Paal and D. Marton, Appl. Surf. Sci. 26, 161 (1986).

    Article  CAS  Google Scholar 

  94. H. Jobic and A. Renouprez, Proc. TCSS4 and ECOSS3, Suppl. “Le Vide, Les Couches Minces”, n° 201, Vol II, p. 746 (1980).

    Google Scholar 

  95. J.P. Candy, H. Jobic and A. Renouprez, J. Phys. Chem. 87, 1227 (1983).

    Article  CAS  Google Scholar 

  96. R.D. Kelley, R.R. Cavanagh, J.J. Rush and T.E. Madey, Surf. Sci. 155, 480 (1985).

    Article  CAS  Google Scholar 

  97. R.R. Cavanagh, J.J. Rush, R.D. Kelley and T.J. Udovic, J. Chem. Phys. 80, 3478(1984).

    Article  CAS  Google Scholar 

  98. H. Jobic et al. (unpublished results).

    Google Scholar 

  99. A.N. Fitch, H. Jobic and A. Renouprez, J. Chem. Soc., Chem. Commun. 284 (1985) ; J. Phys. Chem. 90, 1311 (1986).

    Article  CAS  Google Scholar 

  100. P.A. Wright, J.M. Thomas, A.K. Cheetham and A.K. Nowak, Nature 318, 611 (1985).

    Article  Google Scholar 

  101. J.M. Newsam, J. Phys. Chem. 93, 7689 (1989).

    Article  CAS  Google Scholar 

  102. M. Czjzek, T. Vogt and H. Fuess, Angew. Chem., 28, 770 (1989).

    Article  Google Scholar 

  103. A. Renouprez, H. Jobic and R.C. Oberthur, Zeolites 5, 222 (1985).

    Article  CAS  Google Scholar 

  104. CJ. Wright and C. Riekel, Mol. Phys. 36, 695 (1978).

    Article  CAS  Google Scholar 

  105. E. Cohen de Lara and R. Kahn, J. Physique 42, 1029 (1981).

    Article  Google Scholar 

  106. H. Jobic, M. Bée and A. Renouprez, Surf. Sci. 140, 307 (1984).

    Article  CAS  Google Scholar 

  107. H. Jobic, A. Renouprez, M. Bée and C. Poinsignon, J. Phys. Chem. 90, 1059 (1986).

    Article  CAS  Google Scholar 

  108. H. Jobic, M. Bée and G.J. Kearley, Zeolites, 9, 312 (1989).

    Article  CAS  Google Scholar 

  109. H. Jobic, M. Bée, J. Caro, M. Bülow and J. Kärger, J. Chem. Soc, Faraday Trans. 1, 85, 4201 (1989).

    Google Scholar 

  110. R. Kahn, E. Cohen de Lara and E. Viennet, J. Chem. Phys. 91, 5097 (1989).

    Article  CAS  Google Scholar 

  111. E. Cohen de Lara, R. Kahn and F. Mezei, J. Chem. Soc., Faraday Trans 1, 79, 1911 (1983).

    Google Scholar 

  112. H. Jobic, M. Bée, J. Kärger, H. Pfeifer and J. Caro, J. Chem. Soc., Chem. Commun., 341 (1990).

    Google Scholar 

  113. H. Jobic, Spectrochim. Acta (in press).

    Google Scholar 

  114. LM. Kustov, V.Yu. Borovkov and V.B. Kazansky, J. Catal. 72, 149 (1981).

    Article  CAS  Google Scholar 

  115. M.J. Wax, R.R. Cavanagh, J.J. Rush, G.D. Stucky, LAbrams and D.R. Corbin, J. Phys. Chem. 90, 532 (1986).

    Article  CAS  Google Scholar 

  116. J. Sauer, J. Molec. Catalysis 54, 312 (1989).

    Article  CAS  Google Scholar 

  117. H. Jobic, J. Catal. (submitted).

    Google Scholar 

  118. R.A. van Santen, B.W.H. van Beest and A.J.M. de Man, in “Physicochemical Properties of Zeolitic Systems and thein Low Dimensionality”, NATO workshop (in press).

    Google Scholar 

  119. S. Yashonath, J.M. Thomas, A.K. Nowak and A.K. Cheetham, Nature, 331, 601 (1988).

    Article  CAS  Google Scholar 

  120. P. Demontis, G.B. Suffritti, A. Alberti, S. Quartieri, E.S. Fois and A. Gamba, Gazz. Chim. Ital. 116, 459 (1986).

    CAS  Google Scholar 

  121. L Leherte, D.P. Vercauteren, E.G. Derouane, G.C. Lie, E. Clementi and J.M. André, in “Zeolites : Facts, Figures, Future”, (Ed. P.A. Jacobs and R.A. van Santen), Elsevier, Amsterdam p. 773 (1989).

    Chapter  Google Scholar 

  122. P. Demontis, S. Yashonath and M.L Klein, J. Phys. Chem. 93, 5016 (1989).

    Article  CAS  Google Scholar 

  123. B. Smit and C.J.J den Ouden, J. Phys. Chem. 92, 7169 (1988).

    Article  Google Scholar 

  124. H. Jobic, A.N. Fitch, H.J. Lauter and J. Tomkinson (in preparation).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1991 Plenum Press, New York

About this chapter

Cite this chapter

Jobic, H. (1991). Use of Neutron Beams in Studying Vibrational Modes of Molecules Adsorbed on Catalysts. In: Brongersma, H.H., van Santen, R.A. (eds) Fundamental Aspects of Heterogeneous Catalysis Studied by Particle Beams. NATO ASI Series, vol 265. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-5964-7_22

Download citation

  • DOI: https://doi.org/10.1007/978-1-4684-5964-7_22

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-5966-1

  • Online ISBN: 978-1-4684-5964-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics