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Structure and Reaction Mechanisms in Sulphur-Radical Chemistry Revealed by E.S.R. Spectroscopy

  • Bruce C. Gilbert
Part of the NATO ASI Series book series (NSSA, volume 197)

Abstract

Free radicals derived from sulphur-containing compounds are believed to participate in a wide variety of reaction types, including those of synthetic or industrial importance, and they are increasingly implicated in a number of important biological processes. Although their mediation in chemical reactions has long been invoked, direct proof of their involvement — and their full characterization — has largely been the result of the relatively recent application of a number of spectroscopic techniques to the study of a variety of reaction systems.

Keywords

Unpaired Electron Hyperfine Splitting Thiyl Radical Restricted Rotation Dimethyl Sulphide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1990

Authors and Affiliations

  • Bruce C. Gilbert
    • 1
  1. 1.Department of ChemistryUniversity of YorkHeslington, YorkUK

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