Advertisement

Applications of Multinuclear NMR in the Solid State to Structural and Dynamical Problems in Macromolecular Chemistry

  • Robert G. Bryant
  • S. D. Kennedy
  • C. L. Jackson
  • Thomas M. Eads
  • William R. Croasmun
  • Allen E. Blaurock
Part of the Basic Life Sciences book series (BLSC, volume 56)

Abstract

Nuclear magnetic resonance is a long established molecular spectroscopy that provides both dynamical and structural information about the molecules bearing the nuclear spin observed. Currently, data acquisition is accomplished in the time domain by the application of radio frequency excitation followed by acquisition of the transient nuclear induction signal using rapid analog to digital conversion for storage of the data set in a fast and usually dedicated digital computer. A Fourier transform of the time domain signal provides the usual frequency domain spectrum that is most often interpreted to yield structural information about the molecules observed.

Keywords

Chemical Shift Anisotropy Radio Frequency Field Chemical Shift Tensor Beta Form Alpha Form 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Abragam, A., 1961, Principles of Nuclear Magnetism, Clarendon Press, Oxford, Ch. 7.Google Scholar
  2. Azuory, R., Aronhime, J. S., Sarig, S., Abrashkin, S., Mayer, I., and Garti, N., 1988, J. Am. Oil Chem. Soc., a6:964.CrossRefGoogle Scholar
  3. Bociek, S. M., Ablatt, S., and Norton, I. T., 1985, J. Am. Oil Chem. Soc., 62:1261.CrossRefGoogle Scholar
  4. Burnett, L. J., and Muller, B. H., 1971, J. Chem. Phys., 55:5829.CrossRefGoogle Scholar
  5. Davis, J. H., 1983, Biochem. Biophys. Acta., 737:117.PubMedGoogle Scholar
  6. Derbyshire, V., Gorvin, T. C., and Warner, D., 1969, Mol. Phys., 17:401.CrossRefGoogle Scholar
  7. Dudley, R. L., and Fyfe, C. A., 1982, Fuel, 61:651.CrossRefGoogle Scholar
  8. Ernst, R. R., Bodenhausen, G., and Wokaun, A., 1987, “Principles of Nuclear Magnetic Resonance In One and Two Dimensions,” Clarendon Press, Oxford.Google Scholar
  9. Fyfe, C. A., 1983, Solid State NMR for Chemists, C.F.C. Press, (P.O. Box 1720, Guelph, Ontario, Canada).Google Scholar
  10. Gerstein, B. C., and Dybowski, C. R., 1985, Transient Techniques in NMR of Solids, Academic Press, New York.Google Scholar
  11. Gibon, V., Durant, F., and Deroanne, C., 1986, J. Am. Oil Chem. Soc., 63:1047.CrossRefGoogle Scholar
  12. Gorenstein, D. G., ed., 1984, Phosphorus-31 NMR, Academic Press, New York.Google Scholar
  13. Griffin, R. G., 1981, Methods in Enzymology, 72:108.PubMedCrossRefGoogle Scholar
  14. Jackson, C. L., and Bryant, R. G., 1989, Biochemistry, 28:5024.PubMedCrossRefGoogle Scholar
  15. Jacob, G. S., Schaefer, J., and Wilson, Jr., G. E., 1985, J. Biol. Chem., 260:2777.PubMedGoogle Scholar
  16. Jelinski, L. W., 1986, “High Resolution NMR Spectroscopy of Synthetic Polymers in Bulk,” R. A. Komoroski, ed., VCH Publishers, Deerfield Beach, Florida, p. 335.Google Scholar
  17. Kennedy, S. D., and Bryant, R. G., 1990, Biopolymers, in press.Google Scholar
  18. Komoroski, R. A., and Mandelkern, L., 1986, High Resolution NMR Spectroscopy of Synthetic Polymers in Bulk, R.A. Komoroski, ed., VCH Publishers, Deerfield Beach, Florida, pp. 1–17.Google Scholar
  19. Kunts, I. D., and Kauzman, W., 1974, Adv. Protein Chem., 28:239.CrossRefGoogle Scholar
  20. Larsson, K., 1964, Ark. Kemi., 23:1.Google Scholar
  21. Mehring, M., 1976, High Resolution NMR Spectroscopy in Solids, Springer-Verlag Series: NMR Basic Principles and Progress, Volume 11.Google Scholar
  22. Norton, I. T., Lee-Tuffnell, C. D., Ablett, S., and Bociek, S. M., 1985, J. Am. Oil Chem. Soc., 62:1237.CrossRefGoogle Scholar
  23. Small, D. M., 1986, “The Physical Chemistry of Lipids, from Alkanes to Phospholipids,” V. 4 in Handbook of Lipid Research, Plenum Press, New York, pps. 26–7 for hydrocarbon chain packing volumes.Google Scholar
  24. Smith, R. L., and Oldfield, E., 1984, Science, 225:280.PubMedCrossRefGoogle Scholar
  25. Spiess, H. W., 1985, Adv. Polymer Sci., 66:24.Google Scholar
  26. Torchia, D. A., and Szabo, A., 1982, J. Magn. Reson., 107.Google Scholar
  27. Wuthrich, K., et al., 1989, J. Am. Chem. Soc., 111:1871.CrossRefGoogle Scholar

Copyright information

© Plenum Press, New York 1990

Authors and Affiliations

  • Robert G. Bryant
    • 1
    • 2
    • 4
  • S. D. Kennedy
    • 1
    • 4
  • C. L. Jackson
    • 1
    • 2
  • Thomas M. Eads
    • 1
    • 3
  • William R. Croasmun
    • 1
    • 3
  • Allen E. Blaurock
    • 1
    • 3
  1. 1.Biophysics DepartmentUniversity of Rochester Medical CenterRochesterUSA
  2. 2.Chemistry DepartmentUniversity of RochesterRochesterUSA
  3. 3.Kraft, Inc. -Technology CenterGlenviewUSA
  4. 4.Biophysics DepartmentUniversity of RochesterRochesterUSA

Personalised recommendations