Recent Progresses in the Understanding of Chemical Properties of Zeolites

  • Jacques C. Védrine
Part of the NATO ASI Series book series (NSSB, volume 221)


Catalytic properties of zeolites and molecular sieves materials are very much depending on both their chemical and physical features. The former aspect correspond to acidic, metallic, basic or redox-type reactions since it involves active sites whose nature, chemical strength, density and distribution in strength have to be determined. The physical aspect is known to greatly influence shape selectivity (1), confinement (2) and diffusion (1) properties.


Acid Site Probe Molecule Lewis Acid Site Isomorphous Substitution Zeolite Sample 
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  1. 1.
    P. B. Weisz, Pure Appi. Chem 52: 2091 (1980), J. M. Csicsery, in “Zeolite Chemistry and Catalysis”, J. M. Rabo, ed., Monograph ACS 171: 680 (1976).Google Scholar
  2. 2.
    E. G. Derouane, J. M. André and A. A. Lucas, J. Catal., 110: 58 (1988).CrossRefGoogle Scholar
  3. 3.
    R. M. Barrer, in “Hydrothermal Chemistry of Zeolite”, Academic Press, London, UK, 1982 p 419.Google Scholar
  4. 4.
    M. Taramasso, G. Perego and B. Notari, in “Proceed, of 5th Intern. Zeol. Confer., Napoli”, L. V. C. Rees, ed., Heyden-, London 1980 p 40.Google Scholar
  5. 5.
    C. T. W. Chu and C. D. Chang, J. Phys. Chem., 89: 1569 (1985).CrossRefGoogle Scholar
  6. 6.
    G. Coudurier and J. C. Vedrine, Pure Appi. Chem. 58: 1389 (1986).CrossRefGoogle Scholar
  7. 7.
    M. Taramasso, G. Perego and B. Notari, US Patent 4, 410, 501, (1983) assigned to ENI.Google Scholar
  8. 8.
    E. M. Flanigen, B. M. Lok, R. L. Patton and S. T. Wilson, Pure Appi. Chem. 58: 1351 (1986).CrossRefGoogle Scholar
  9. 9.
    D. E. W. Vaughan, M. M. J. Treacy, J. M. Newsam, this book, Page 99.Google Scholar
  10. 10.
    E. G. Derouane, L. Baltusis, R. M. Dessau and K. D. Schmitt in “Catalysis by acids and bases”, Stud, in Surf. Sci, and Catal. Elsevier, Amsterdam 10: 135 (1985).Google Scholar
  11. 11.
    H. K. Beyer and I. Belenkaja in “Catalysis by Zeolites”, Stud, in Surf. Sci, and Catal., Elsevier, Amsterdam, 5: 203 (1980).Google Scholar
  12. 12.
    B. Kraushaar-Czarnetzki, Thesis, Eindhoven, NL, april 1989Google Scholar
  13. 13.
    J. C. Vedrine, A. Auroux and G. Coudurier, in “Catalytic Materials, Relationship between structure and reactivity”, T. E. Whyte etal, ed., ACS Sympos. Ser., Washington, 248: 253 (1984).Google Scholar
  14. 14.
    D. Barthomeuf, Mater. Chem. and Phys. 17: 49 (1987).CrossRefGoogle Scholar
  15. 15.
    J. Kijenski and A. Baiker, Catal. today 5: 1 (1989).CrossRefGoogle Scholar
  16. 16.
    D. Barthomeuf, G. Coudurier and J. C. Vedrine, Mater. Chem. and Phys. 18: 553 (1988).CrossRefGoogle Scholar
  17. 17.
    G. Bergeret, P. Gallezot, P. Gelin, Y. Ben Taarit, F. Lefebvre and R. D. Shannon, Zeolites 6: 392 (1986).CrossRefGoogle Scholar
  18. 18.
    L. L. Sheu, H Knözinger and W. N Sachtler, Catal. Letters 2: 129 (1989).CrossRefGoogle Scholar
  19. 19.
    V. B. Kazansky, V. YU Borovkof and L. M. Kustov in “Proceed, of the 8th Intern. Conf. on Catalysis”, Berlin Dechema, Verlag Chemie, Basel 3: 3 (1984).Google Scholar
  20. 20.
    L. M. Kustov, V. B. Kazansky and P. Ratnasamy, Zeolites 7: 79 (1987).CrossRefGoogle Scholar
  21. 21.
    S. G. Hegde, P. Ratnasamy, L. M. Kustov and V. B. Kazansky, Zeolites 8: 137 (1988).CrossRefGoogle Scholar
  22. 22.
    A. Macedo, PhD thesis, Paris VI, IFP 36875, 1988.Google Scholar
  23. 23.
    H. Pfeifer, D. Freude and M. Hunger, Zeolites 5: 274 (1985)CrossRefGoogle Scholar
  24. 24.
    W. L. Earl, P. O. Fritz, A. V. Gibson and J. M. Lunsford, J. Phys. Chem. 91: 2091 (1987)CrossRefGoogle Scholar
  25. 25.
    B. Hunger and J. Hoffmann, React. Kinet. Catal. Letters 27: 305 (1985).CrossRefGoogle Scholar
  26. 26.
    A. Auroux in “Les techniques physiques d’Etudes des Catalyseurs” B. Imelik and J. C. Vedrine (ed.), Technip, Paris, chap. 24 p 823 (1988).Google Scholar
  27. 27.
    M. Soulard, S. Bilger, H. Kessler and J. L. Guth, Zeolites, 7: 463 (1987).CrossRefGoogle Scholar
  28. 28.
    J. Patarin, Thesis, Mulhouse, France (1988).Google Scholar
  29. 33.
    Y. S. Jin, A. Auroux and J. C. Vedrine, Appl. Catal. 37: 1 (1988).CrossRefGoogle Scholar
  30. 34.
    A. Auroux, Y. S. Jin, J. C. Vedrine, and L. Benoist, Appl. Catal. 36: 323 (1988).CrossRefGoogle Scholar
  31. 35.
    G. A. Olah and C. U. Pittman Jr, in “Carboniumions”, G. A. Olah and P. Von Schleyer (ed), Interscience publish., New York, I: 153 (1968).Google Scholar
  32. 37.
    J. B-Nagy, Z. Gabelica and t. Gl. Derouane, Chem. Letters 1105 (1982).Google Scholar
  33. 38.
    G. Boxhoorn, A. G. T. G. Kortbeek, G. R. Hays and N. C. M. Alma, Zeolites 4: 15 (1984).CrossRefGoogle Scholar
  34. 39.
    S. G. Fegan and B. M. Lowe, J. Chem. Soc., Chem. Commun. 437 (1984).Google Scholar
  35. 40.
    C. C. Price and J. R. Sowa, J. Amer. Chem. Soc. 32: 4126 (1967).Google Scholar
  36. 41.
    M. Hunger, J. Kärger, H. Pfeifer, J. Caro, B. Zibrowius, M. Bülow and R. Mostowicz, J. Chem. Soc., Faraday Trans. I, 83: 3459 (1987).Google Scholar
  37. 42.
    E. Lippmaa, A. Saloson, V. V. Brei and Y. I. Gorlov, Fiz. Chem. 259: 403 (1981).Google Scholar
  38. 43.
    H. Pfeifer, D. Freude and M. Hunger, Zeolites 5: 274 (1984).CrossRefGoogle Scholar
  39. 44.
    J. Caro, M. Bülow, J. Richter-Mendau, J. Kärger, M. Hunger, D. Freude and L. V. C. Rees, J. Chem. Soc., Faraday Trans. I 83: 1843 (1987)Google Scholar
  40. 45.
    D. Freude, M. Hunger and H. Pfeifer, Z. Phys. Chem. NF 152: 171 (1987).CrossRefGoogle Scholar
  41. 46.
    T. R. Hughes, R. L. Jacobson and P. W. Tamm, in “Catalysis”, Stud in Surf. Sci. and Catal., J. W. Ward, ed., Elsevier, Amsterdam 38: 317 (1988).Google Scholar
  42. 47.
    J. R. Bernard in “Proceed, of the 5 th Int. Conf. on Zeol”. Napoli, L. V. C. Rees, ed., Heyden, London 681 (1980), C. Bezuhanova, J. Guidot, D. Barthomeuf, M. Breysse and J. R. Bernard, J. Chem. Soc., Faraday Trans. I, 77: 1595 (1981).Google Scholar
  43. 48.
    P. A. Jacobs, F. H. van Cauwlaert, E. F. Vansant and J. B. Uytterhoeven, J. Chem. Soc. 69: 1056 (1973).Google Scholar
  44. 49.
    Y. Delaval, R. Seloudoux and E. Cohen de Lara, J. Chem. Soc., Faraday Trans I, 82: 365 (1986).Google Scholar
  45. 50.
    D. Barthomeuf, J. Phys. Chem. 88: 44 (1984).CrossRefGoogle Scholar
  46. 51.
    R. T. Sanderson, Chemical bonds and bond energy, Academic Press, New York, (1976).Google Scholar
  47. 52.
    A. Bielanski and J. Datka, J. Catal. 42: 183 (1974).CrossRefGoogle Scholar
  48. 53.
    A. de Mallmann and D. Barthomeuf, Zeolites 8: 292 (1988).CrossRefGoogle Scholar
  49. 55.
    E. D. Garbowski and H. Praliaud, J. Chim. Phys. 76: 687 (1979).Google Scholar
  50. 56.
    P. Wierzchowski, E. D. Garbowski and J. C. Vedrine J. Chim. Phys. 78: 41 (1981).Google Scholar
  51. 57.
    A. A. Slinkin, A. V. Kucherov, D. A. Kondratyev, T. N. Bondarenko, A. M. Rubinstein and Kh. M. Minachev, J. Molec. Catal. 35: 97 (1986).CrossRefGoogle Scholar
  52. 58.
    A. V. Kucherov, A. A. Slinkin, D. A. Kondratyev, T. N. Bondarenko, A. M. Rubinstein and Kh. M. Minachev, J. Molec. Catal. 37: 107 (1986).CrossRefGoogle Scholar
  53. 59.
    Y. Kodratoff, C. Naccache and B. Imelik, J. Chim. Phys. 65: 562 (1968).Google Scholar
  54. 60.
    B. D. Flockhart in “Surface and defects properties of solids”, The Chemical Society, London, 2: 69 (1973).Google Scholar
  55. 61.
    M. Tielen, M. Geelen and P. A. Jacobs, Acta Phys. Chem. 31: 1 (1985).Google Scholar
  56. 62.
    E. M. Flanigen, H. Khatami and M. A. Szymanski in “Molecular Sieve Zeolites”, Adv. Chem. Ser. 101: 201 (1971). M. Fichtner-Schmittler, V. Lohse, G. Engelhardt and U. Patzelova, Cryst. Res Techn. 9: 11 (1984).Google Scholar
  57. 63.
    N. A. Kutz in “Proceed, of the 2nd Symp. of Industry-University cooperative programme”, Texas A. et M. University Press, College Station 121 (1984).Google Scholar
  58. 64.
    M. Taramasso, G. Perego and B. Notari, U. S. Patent, 4, 410, 501 (1983).Google Scholar
  59. 65.
    R. B. Borade, Zeolites, 7: 398 (1987).CrossRefGoogle Scholar
  60. 67.
    B. F. Mentzen C. R. Acad. Sci. Paris, Ser. II, 303: 1289 (1986) Mater. Res. Bull. 22: 309 (1987).Google Scholar
  61. 68.
    D. B. Wiles and R. A. Young, J. Appi. Cryst. 14: 149 (1981).CrossRefGoogle Scholar
  62. 69.
    B. F. Mentzen and J. C. Vedrine, C. R. Acad. Sci. Paris, Ser. II, 301: 1017 (1985). J. C. Vedrine, G. Coudurier and B. F. Mentzen, in “Prospective in Molecular Sieve Science”, W. H. Flank and T. E. Whyte (ed), ACS Symp. Ser., Washington, 368: 66 (1988).Google Scholar
  63. 70.
    B. F. Mentzen, J. C. Vedrine and R. Khouzami, C. R. Acad. Sci. Paris, Ser. II, 304: 11 (1987).Google Scholar
  64. 71.
    C. Baerlocher in “Proceed, of the 6th Intern. Zeol. Conf.” D. M. Olson and A. Bisio (ed), Butterworths, London, p 823 (1984).Google Scholar
  65. 72.
    K. F. M. G. J. Scholle, A. P. M. Kentgens, W. S. Veeman, P. Frenken and G. P. M. Van der Velden, J. Phys. Chem. 88: 5 (1984).CrossRefGoogle Scholar
  66. 73.
    G. Coudurier, A. Auroux, J. C. Vedrine, R. D. Shannon, L. Abrams and R. D. Farlee, J. Catal. 108: 1 (1987).CrossRefGoogle Scholar
  67. 74.
    L. E. Iton, R. B. Beai and D. T. Hodul, J. Molec. Catal. 21: 151 (1983).CrossRefGoogle Scholar
  68. 75.
    P. Ratnasamy, R. B. Borade, I. Sivasanker, V. P. Shiralkar and S. G. Hedge, Acta Phys. Chem. 31: 137 (1985).Google Scholar
  69. 76.
    R. Szostak and T. L. Thomas, J. Catal. 100: 555 (1986), R. Szostak, V. Nair and T. L. Thomas, J. Chem. Soc., Faraday Trans. I, 83: 487 (1987).Google Scholar
  70. 77.
    G. C. Alis, P. Frenken, E. de Boer, A. Swolfs and M. A. Hefni, Zeolites 7: 319 (1987).CrossRefGoogle Scholar
  71. 79.
    G. Doppler, R. Lehnert, L. Marosi and A. X. Trautwein, Ibid p 215.Google Scholar
  72. 80.
    E. G. Derouane, M. Mestdagh and L. Vielvoye, J. Catal. 33: 90 (1974).CrossRefGoogle Scholar
  73. 81.
    Nat. Bur. Stand. (USA) Monogr. 25 Sec 15 (1978).Google Scholar
  74. 82.
    G. Perego, G. Belussi, C. Corno, M. Taramasso, F. Buonomo and A. Esposito, in “Proceed, of the 7 th Intern. Zeol. Conf.,” Tokyo 1986, Y. Murakami etal, ed, Elsevier, Amsterdam 129 (1986).Google Scholar
  75. 84.
    M. R. Boccuti, K. M. Rao, A. Zecchina, L. Leofanti and G. Petrini, in “Proceed, of the Sympos. on Reactivity of Solids”, Trieste, 1988, in press 1989.Google Scholar
  76. 85.
    P. Pichat, R. Beaumont and D. Barthomeuf, J. Chem. Soc., Faraday Trans I, 70: 1402 (1974).CrossRefGoogle Scholar
  77. 86.
    M. B. Sayed, A. Auroux and J. C. Vedrine J. Catal. 101: 43 (1986). M. B. Sayed, A. Auroux and J. C. Vedrine J. Catal. 116: 1 (1989).Google Scholar
  78. 87.
    J. C. Vedrine, A. Auroux, P. Dejaifve, H. Hoser and S. B. Zhou, J. Catal. 73: 147 (1982).CrossRefGoogle Scholar
  79. 88.
    W. W. Kaeding, C. Chu, L. B. Young, B. Weinstein and S. A. Butter, J. Catal. 67: 159 (1981).CrossRefGoogle Scholar
  80. 89.
    J. A. Lercher and G. Rumplmayr, Appi. Catal. 25: 215 (1986).CrossRefGoogle Scholar
  81. 90.
    A. Auroux, H. Dexpert, C. Leclercq and J. C. Vedrine, Appi. Catal. 6: 95 (1983).CrossRefGoogle Scholar
  82. 91.
    P. Gallezot, Y. Ben Taarit and B. Imelik, C. R. Acad. Sci. Paris, Ser C, 272: 261 (1971), J. Catal. 26: 295 (1972).CrossRefGoogle Scholar
  83. 92.
    C. Naccache and Y. Ben Taarit, Chem. Phys. Letters 11: 11 (1971).CrossRefGoogle Scholar
  84. 93.
    M. Primet, J. C. Vedrine and C. Naccache J. Molec. Catal. 4: 411 (1978).Google Scholar
  85. 94.
    J. C. Vedrine, E. G. Derouane and Y. Ben Taarit J. Phys. Chem. 78: 531 (1974).Google Scholar
  86. 95.
    J. Howard and J. M. Nicol Zeolites 8: 142 (1988).Google Scholar
  87. 96.
    M. Suzuki, K. Tsutsumi, H. Takamasmi and Y. Saito, Zeolites 8: 381 (1981).CrossRefGoogle Scholar
  88. 97.
    M. Suzuki, K. Tsutsumi, H. Takamasmi and Y. Saito Zeolites 8: 387 (1988).CrossRefGoogle Scholar
  89. 98.
    B. R. Gane and A. H. P. Hall, Europ. Patent Appi. 147, 111 (1984), S. A. I. Barri and T. K. Mc Niff, Europ. Patent appi. 171, 981 (1985), I. C. Bennett and A. H. P. Hall, Europ. Patent Appi. 202, 000 (1986) assigned to B. P. Corp.Google Scholar
  90. 99.
    A. Abou-KaYs, C. Mirodatos, J. Massardier, D. Barthomeuf and J. C. Vedrine, J. Phys. Chem. 81: 397 (1977).CrossRefGoogle Scholar
  91. 100.
    M. Itoh, A. Miyamato and Y. Murakami, J. Catal. 64: 284 (1980).CrossRefGoogle Scholar

Copyright information

© Plenum Press, New York 1990

Authors and Affiliations

  • Jacques C. Védrine
    • 1
  1. 1.Institut de Recherches sur la CatalyseCNRSVilleurbanneFrance

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