Abstract
General features of the hyperspherical adiabatic representation of atomic structure and spectra are illustrated by means of a pair of simple thought experiments. The thought experiments describe how correlated atomic wavefunctions evolve under independent variations of the nuclear charge and of the number density of electrons. Consequences of the theory include systematic patterns of configuration mixing in both ground state channels and multiply-excited states.
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© 1988 Plenum Press, New York
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Cavagnero, M. (1988). A Hyperspherical Description of N-Electron Atoms. In: Briggs, J.S., Kleinpoppen, H., Lutz, H.O. (eds) Fundamental Processes of Atomic Dynamics. NATO ASI Series, vol 181. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-5544-1_17
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DOI: https://doi.org/10.1007/978-1-4684-5544-1_17
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