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Time-Resolved Kinetics of Organometallic Reactions in the Gas Phase by Transient Infrared Absorption Spectrometry

  • Bruce H. Weiller
  • Edward R. Grant
Part of the Modern Inorganic Chemistry book series (MICE)

Abstract

Chemical change is a science of intermediates. Reactive molecules and fragments guide the chemistry of multicomponent systems and determine the stereospecific outcomes of individual reactions. Organometallic chemistry is among the richest of all for its transient species. Metal-centered intermediates variously appear and disappear via oxidative addition, insertion, metallocyclization, and their reverse reactions.(1) Progress in stoichiometric synthesis as well as catalysis depends on the accurate knowledge of the intermediate forms at work in these and other organometallic transformations.

Keywords

Metal Carbonyl Matrix Isolation Bimolecular Rate Constant InSb Detector Incoherent Source 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1989

Authors and Affiliations

  • Bruce H. Weiller
    • 1
  • Edward R. Grant
    • 1
  1. 1.Department of ChemistryPurdue UniversityWest LafayetteUSA

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