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Reactions in Ionized Metal Carbonyls: Clustering and Oxidative Addition

  • Douglas P. Ridge
  • Wilma K. Meckstroth
Part of the Modern Inorganic Chemistry book series (MICE)

Abstract

Volatile metal carbonyls were among the first transition metal compounds studied by mass spectrometry.(1–4) On electron impact the metal carbonyl molecular ions lose carbonyl ligands successively. A series of ions with increasing degrees of coordinative unsaturation result. The bare metal atomic ion (or cluster ion in the case of polynuclear carbonyls) in fact frequently dominates the mass spectrum. These coordinatively unsaturated ions represented a unique opportunity as techniques for studying gas phase ion-molecule reactions developed. Mass spectrometric studies of the metal carbonyls provide the basis on which we can exploit this opportunity.

Keywords

Oxidative Addition Metal Carbonyl Ligand Substitution Carbonyl Ligand Electron Deficiency 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1989

Authors and Affiliations

  • Douglas P. Ridge
    • 1
  • Wilma K. Meckstroth
    • 2
  1. 1.Department of ChemistryUniversity of DelawareNewarkUSA
  2. 2.Department of ChemistryOhio State UniversityNewarkUSA

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