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Reactions in Ionized Metal Carbonyls: Clustering and Oxidative Addition

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Gas Phase Inorganic Chemistry

Part of the book series: Modern Inorganic Chemistry ((MICE))

Abstract

Volatile metal carbonyls were among the first transition metal compounds studied by mass spectrometry.(1–4) On electron impact the metal carbonyl molecular ions lose carbonyl ligands successively. A series of ions with increasing degrees of coordinative unsaturation result. The bare metal atomic ion (or cluster ion in the case of polynuclear carbonyls) in fact frequently dominates the mass spectrum. These coordinatively unsaturated ions represented a unique opportunity as techniques for studying gas phase ion-molecule reactions developed. Mass spectrometric studies of the metal carbonyls provide the basis on which we can exploit this opportunity.

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Author information

Authors and Affiliations

  1. Department of Chemistry, University of Delaware, Newark, Delaware, 19716, USA

    Douglas P. Ridge

  2. Department of Chemistry, Ohio State University, Newark, Ohio, 43055, USA

    Wilma K. Meckstroth

Authors
  1. Douglas P. Ridge
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  2. Wilma K. Meckstroth
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Editor information

Editors and Affiliations

  1. Department of Chemistry, Texas A&M University, College Station, Texas, 77843, USA

    David H. Russell

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© 1989 Plenum Press, New York

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Ridge, D.P., Meckstroth, W.K. (1989). Reactions in Ionized Metal Carbonyls: Clustering and Oxidative Addition. In: Russell, D.H. (eds) Gas Phase Inorganic Chemistry. Modern Inorganic Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-5529-8_3

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  • DOI: https://doi.org/10.1007/978-1-4684-5529-8_3

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-5531-1

  • Online ISBN: 978-1-4684-5529-8

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