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Tandem Mass Spectrometry and High-Energy Collisional Activation for Studies of Metal Ion-Molecule Reactions

  • Denise K. MacMillan
  • Michael L. Gross
Part of the Modern Inorganic Chemistry book series (MICE)

Abstract

The study of gas phase ion-molecule reactions has been greatly facilitated in recent years by the rapid development of tandem mass spectrometry (MS/MS). Originally promoted as a method for analysis of complex mixtures, MS/MS is now also used to determine ion structure, as well as reaction cross sections, thermodynamics, and kinetics.(1) MS/MS enables an ion to be selected quickly and accurately, with greater sensitivity and specificity than is possible in traditional mass spectrometry, and then allows the reactions in which the ion participates to be followed. The availability of new instrumentation(2) and the development of new methods(3) for MS/MS have made tandem mass spectrometry especially useful for the study of gas phase ion chemistry.

Keywords

Collisional Activation Collisionally Activate Dissociation Electric Sector Fourier Transform Mass Spectrometry Kinetic Energy Release 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1989

Authors and Affiliations

  • Denise K. MacMillan
    • 1
  • Michael L. Gross
    • 1
  1. 1.Department of ChemistryUniversity of NebraskaLincolnUSA

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