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Intramolecular Reversible Addition Reactions to the Other Groups

  • Raimonds E. Valters
  • Wilhelm Flitsch

Abstract

Numerous synthetic methods for the preparation of heterocyclic imines and amines have been developed [1, 2] in which the last stage involves an intramolecular nucleophilic addition of a hydroxy, amino, or mercapto group to a C≡N bond. Intermediates in these syntheses, i.e., hydroxy, amino, or mercaptonitriles (1A, X = O, NR, S) usually were not isolated.

Keywords

Phosphorus Atom Cyclic Form Tautomeric Equilibrium Thermal Isomerization Cyclic Isomer 
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Copyright information

© Plenum Press, New York 1985

Authors and Affiliations

  • Raimonds E. Valters
    • 1
  • Wilhelm Flitsch
    • 2
  1. 1.Faculty of ChemistryA. Pelshe Riga Polytechnical InstituteRigaUSSR
  2. 2.Organisch-Chemisches InstitutWestfälischen Wilhelms-UniversitätMünsterFederal Republic of Germany

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