Skip to main content

Conductive Polymers: An Opportunity for New Monomers and Polymers

  • Chapter
New Monomers and Polymers

Part of the book series: Polymer Science and Technology ((POLS,volume 25))

Abstract

Electrically conductive polymers have been the subject of sporadic interest to chemists and physicists over the past twenty-five years.1,2 This interest arises from the intriguing prospect of being able to combine in a single material the electrical properties of a metal (high conductivity, greater than 1 s/cm) or semiconductor (moderate conductivity, 10−7 to 1 s/cm) with those of a polymer (mechanical strength, flexibility, lighter weight, low preparation and fabrication costs, etc.). Part of the reason for the sporadic nature of the interest and progress in this field until recently was the fact that the interdisciplinary component necessary in such endeavours was not in place. A second cause was the physical nature of the polymers.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. H.W. Gibson, Polymer, in press (1983).

    Google Scholar 

  2. C.B. Duke and H.W. Gibson, Encyc. Chem. Tech., Wiley and Sons, New York, Vol. 18, pp. 755–794, 1982.

    Google Scholar 

  3. G. Natta, G. Mazzanti, P. Corrandini, Atti Acad. Naz. Lincei, Rend. Cl. Sci. Fis., Mat. Nat. 25 (8), 3, (1958).

    Google Scholar 

  4. D.J. Berets and D.S. Smith, Trans. Faraday Soc., 64, 823 (1968).

    Article  Google Scholar 

  5. T. Ito, H. Shirakawa, S. Ikeda, J. Polym. Sci., Polym. Chem. Ed., 12, 11(1974).

    Google Scholar 

  6. A.G. MacDiarmid, A.J. Heeger, Synth. Met. 1, 101 (1979/1980)

    Article  Google Scholar 

  7. C.K. Chiang, A.J. Heeger, A.G. MacDiarmid, Ber. Bunsenges. Phys. Chem., 83, 407(1979) and references therein.

    Google Scholar 

  8. V. Enkelmann, W. Muller and G. Wegner, Synthetic Metals, 1, 185 (1980);

    Article  Google Scholar 

  9. W.H. Watson, W.C. McMordie and L.G. Lands, J. Polym. Sci., 55, 137 (1961);

    Article  ADS  Google Scholar 

  10. P.S. Woon and M.F. Farona, J. Polym. Chem. Ed., 12, 1749 (1974).

    Article  Google Scholar 

  11. G.B. Butler, G.C. Corfíeld and C. Aso, Prog. Polym. Sci., 4, 71 (1975)

    Article  Google Scholar 

  12. G.B. Butler and R.J. Angelo, J. Amer. Chem. Soc., 79 3128 (1958);

    Article  Google Scholar 

  13. G.B. Butler, A. Crawshaw and W.L. Miller, J. Amer. Chem. Soc., 80, 3615 (1958).

    Article  Google Scholar 

  14. J.K. Stille and D.A. Frey, J. Amer. Chem. Soc., 83, 1697 (1961).

    Article  Google Scholar 

  15. H.W. Gibson, F.C. Bailey, A.J. Epstein, H. Rommelmann and J.M. Pochan, J. Chem. Soc., Chem. Comm., 426 (1980);

    Google Scholar 

  16. H.W. Gibson, F.C. Bailey, A.J. Epstein, H. Rommelmann, S. Kaplan, J. Harbour X.-Q. Yang, D.B. Tanner and J.M. Pochan, J. Amer. Chem. Soc., in press (1983).

    Google Scholar 

  17. A.J. Epstein, H. Rommelmann, R. Fernquist, H.W. Gibson, M.A. Druy and T. Woerner, Polymer, 23, 1211 (1982).

    Article  Google Scholar 

  18. T. Akaishi, K. Miyasaka, K. Ishikawa, H. Shirakawa and S. Ikeda, J. Polym. Sci., Polym. Phys. Ed., 18, 745(1980);

    Article  Google Scholar 

  19. H. Haberkorn, H. Naarmann, K. Penzien, J. Schlag and P. Simak, Synth. Metals, 5, 51 (1982);

    Article  Google Scholar 

  20. P. Robin, J.P. Pouget, R. Comes, H.W. Gibson and A.J. Epstein, Phys. Rev. B, in press (1983).

    Google Scholar 

  21. J.M. Pochan, H.W. Gibson and J. Harbour, Polymer, 23, 439(1982); unpublished data.

    Article  Google Scholar 

  22. J.M. Pochan, D.F. Pochan and H.W. Gibson, Polymer, 22, 1367 (1981);

    Google Scholar 

  23. J.M. Pochan, H.W. Gibson and J. Harbour, Polymer, 23, 435 (1982).

    Google Scholar 

  24. H.W. Gibson and J.M. Pochan, Macromolecules, 15, 242 (1982).

    Google Scholar 

  25. R.I. Yakhimovich, E.A. Shilov and G.F. Dvorko, Dokl. Akad. Nauk SSSR, 166, 98 (1966) ( Eng. Tr.).

    Google Scholar 

  26. L.A. Akopyan, G.V. Ambartsumyan, E.V. Ovakimyan and S.G. Matsoyan, Vysokomol. Soed., A19, 271 (1977).

    Google Scholar 

  27. I thank Dr. John Spiewak of these laboratories for pointing this possibility out.

    Google Scholar 

  28. L.W. Shacklette, R.L. Elsenbaumer, R.R. Chance, H. Eckhardt, J.E. Frommer and R.H. Baughman, J. Chem. Phys., 75, 1919 (1981) and references therein.

    Article  ADS  Google Scholar 

  29. G.E. Wnek, J.C.W. Chien, F.E. Karasz and C.P Lillya, Polymer, 20, 1441 (1979);

    Article  Google Scholar 

  30. J.C.W. Chien, R.D. Gooding, F.E. Karasz, C.P. Lillya, G.E. Wnek and K. Yao, Org. Coat. Plast. Chem., 43, 886 (1980);

    Google Scholar 

  31. J.R. Reynolds, J.C.W. Chien, F.E. Karasz, R.D. Gourley, and C.P. Lillya, Conf. Phys. Chem. Cond. Polym., Les Arcs, France, Dec. 11–15, 1982, to appear in J. Physique.

    Google Scholar 

  32. T. Yamamoto, K. Sanechika, and A. Yamamoto, J. Polym. Sci. Polym. Lett. Ed.,18, 9(1980);

    Article  ADS  Google Scholar 

  33. J.W. P. Lin and L. Dudek, J. Polym. Sci., Polym. Chem. Ed., 18, 2869(1980).

    Google Scholar 

  34. S.T. Wellinghoff, T. Kedrowski and H. Ishida, Conf. Phys. Chem. Cond. Polym. Les Arcs, France, Dec. 11–15, 1982, to appear in J. Physique.

    Google Scholar 

  35. G. Wolmershauser, R. Jotter and T. Wilhelm, Conf. Phys. Chem. Cond. Polym., Les Arcs, France, Dec. 11–15, 1982, to appear in J. Physique.

    Google Scholar 

  36. A. Diaz, Chemica Scripta, 17, 145 (1981).

    Google Scholar 

  37. G. Kossmehl and G. Chatzitheodorou, Proc. IUPAC 28th Macromol. Symp., Amherst, Mass., July 12–16, 1982, p. 419.

    Google Scholar 

  38. J.C.W. Chien, G.E. Wnek, F.E. Karasz and J.A. Hirsch, Macromolecules, 14, 479 (1981).

    Google Scholar 

  39. W. Diets, P. Cukor, M. Rubner and H. Jopson, Ind. Eng. Chem. Prod. R and D, 20, 696 (1981).

    Article  Google Scholar 

  40. M. Rubner and W. Deits, J. Polym. Sci., Polym. Chem. Ed., 20, 2043(1982).

    Article  ADS  Google Scholar 

  41. T. Higashimura and T. Masuda, Proc. IUPAC 28th Macromol. Symp. Amherst, Mass., July 12–16, 1982, p. 113;

    Google Scholar 

  42. T. Higashimura, Y.X. Deng and T. Matsuda, Macromolecules, 15, 234 (1982).

    Google Scholar 

  43. M.J. Kletter, A.G. MacDiarmid, A.J. Heeger, E. Faulques, S. Lefrant and P. Bernier, J. Polym. Sci., Polym. Lett. Ed., 20, 211 (1982).

    Article  ADS  Google Scholar 

  44. J.H. Edwards and W.J. Feast, Polymer, 21, 595 (1980);

    Google Scholar 

  45. H. Edwards and W.J. Feast, Conf. Phys. Chem. Cond. Polym., Les Arcs, France, Dec. 11–14, 1982, to appear in J. Physique.

    Google Scholar 

  46. J.H. Edwards, W.J. Feast and D.C. Bott, private communication.

    Google Scholar 

  47. G. Leising, F. Stelzer, and H. Kahlert, Conf. Phys. Chem. Cond. Polym., Les Arcs, France, Dec. 11–14, 1982, to appear in J. Physique.

    Google Scholar 

  48. A.J. Heeger and A.G. MacDiarmid, Chemica Scripta, 17, 115(1981) and references therein.

    Google Scholar 

  49. G. Wegner, Angew. Chem. Int. Ed. Eng., 20, 361(1981);

    Article  Google Scholar 

  50. G. Wegner, Proc. IUPAC 28th Macromol. Symp., Amherst, Mass., July 12–16, 1982, p. 410;

    Google Scholar 

  51. G. Wegner, V. Enkelmann, M. Monkenbusch, G. Wieners and G. Lieser, Conf. Phys. Chem. Cond. Polym., Les Arcs, France, Dec. 11–14, 1982, to appear in J. Physique.

    Google Scholar 

  52. C. Krohnke, V. Enkelmann and G. Wegner, Ang. Chem. Int. Ed. Eng., 19, 912 (1980).

    Article  Google Scholar 

  53. V. Hadek, P. Zach, K. Ulbert, and J. Honzl, Collect. Czech. Chem. Comm., 34, 3139 (1969);

    Google Scholar 

  54. J. Honzl, K. Ulbert, V. Hadek, and M. Tlustakova, J. Polym. Sci. Part C, 16, 4465 (1969);

    Google Scholar 

  55. V. Hadek, J. Chem. Phys., 49, 5202 (1968);

    Google Scholar 

  56. K. Ulbert, J. Polym. Sci. Part C, 22, 881 (1969).

    Google Scholar 

  57. H. Block, M.A. Cowd and S.M. Walker, Polymer,18781 (1977);

    Google Scholar 

  58. H. Block, Adv. Polym. Sci. 33, 93 (1979).

    Google Scholar 

  59. S. Lefrant, Conf. Phys. Chem. Conf. Polym., Dec. 11–14, 1982, Les Arcs, France, to appear in J. Physique;

    Google Scholar 

  60. H. Kuzmany, ibid;

    Google Scholar 

  61. G.P. Brivio and E. Mulazzi, ibid.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1984 Plenum Press, New York

About this chapter

Cite this chapter

Gibson, H.W. (1984). Conductive Polymers: An Opportunity for New Monomers and Polymers. In: Culbertson, B.M., Pittman, C.U. (eds) New Monomers and Polymers. Polymer Science and Technology, vol 25. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-4619-7_21

Download citation

  • DOI: https://doi.org/10.1007/978-1-4684-4619-7_21

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-4621-0

  • Online ISBN: 978-1-4684-4619-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics