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New Monomers and Polymers pp 285–309Cite as

Synthesis and NMR Characterization of Copolymers of α-Fluorostyrene with Methyl Acrylate

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Part of the book series: Polymer Science and Technology ((POLS,volume 25))

Abstract

Polymers of α-halostyrenes are unstable because they contain labile halogen atoms which are readily lost as hydrogen halide1. Although a few studies on the synthesis and applications of homopolymers and copolymers of α-chlorostyrene2–10, α-bromostyrene11,12 and α-fluorostyrene 13–16 have been reported, no systematic studies on the copolymerization behavior of these monomers or on the microstructures of their polymers are known. Most of these studies have dealt with homopolymerization of α-halostyrenes in emulsion or in suspension or with copolymerizations (mostly graft) involving very small molar percentages of α-halostyrene.

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Authors and Affiliations

  1. Institute of Polymer Science, The University of Akron, Akron, Ohio, 44325, USA

    Ramendra N. Majumdar & H. James Harwood

Authors
  1. Ramendra N. Majumdar
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  2. H. James Harwood
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Editors and Affiliations

  1. Ashland Chemical Company, Columbus, Ohio, USA

    Bill M. Culbertson

  2. Mississippi State University, Mississippi, Mississippi State, USA

    Charles U. Pittman Jr.

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© 1984 Plenum Press, New York

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Majumdar, R.N., Harwood, H.J. (1984). Synthesis and NMR Characterization of Copolymers of α-Fluorostyrene with Methyl Acrylate. In: Culbertson, B.M., Pittman, C.U. (eds) New Monomers and Polymers. Polymer Science and Technology, vol 25. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-4619-7_17

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  • DOI: https://doi.org/10.1007/978-1-4684-4619-7_17

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-4621-0

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