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Quaternization of Condensation Polymers

  • William H. Daly
  • Shih-Jen Wu
Part of the Polymer Science and Technology book series (POLS, volume 25)

Abstract

Although the preparation of quaternary ammonium containing resins from appropriately substituted vinyl monomers has been studied extensively1 elaboration of condensation polymers has not received comparable attention. Condensation polymers cannot be prepared with sufficiently high molecular weights or satisfactory chemical stability for most applications involving flocculation or viscosity enhancement. However, the excellent mechanical properties exhibited by many aromatic condensation polymers suggest that speciality applications, in particular, permselective membranes, could be served by suitably modified resins. We have observed that polymers containing oxy-phenylene repeat units are subject to facile electrophilic substitution including chloromethylation; the reactive derivatives can be cast into tough flexible films.2

Keywords

Alkyl Halide Glyceryl Ether Pyridinium Bromide Chloromethyl Group Condensation Polymer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1984

Authors and Affiliations

  • William H. Daly
    • 1
  • Shih-Jen Wu
    • 1
  1. 1.Department of ChemistryLouisiana State UniversityBaton RougeUSA

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