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Linear Chain 1,2-Dithiolene Complexes

  • L. Alcácer
  • H. Novais

Abstract

This chapter focuses on linear chain materials formed by the association of 1,2-dithiolene metal complex molecules with organic or inorganic donors and cations.

Keywords

High Occupied Molecular Orbital Lower Unoccupied Molecular Orbital Lower Unoccupied Molecular Orbital Molecular Arrangement Metal Oxidation State 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.(a)
    Bähr, G., and Schleitzer, H., Chem. Ber. 88, 1771 (1955).Google Scholar
  2. (b).
    Bähr, G., and Schleitzer, H., Chem. Ber. 90, 438 (1957).Google Scholar
  3. 2.
    Gray, H. B., Williams, R., Bemal, I., and Billig, E., J. Am. Chem. Soc. 84, 3596 (1962).Google Scholar
  4. 3.
    Davison, A., Edelstein, N., Holm, R. H., and Maki, A. H., J. Am. Chem. Soc. 85, 2029 (1963).Google Scholar
  5. 4.(a)
    McCleverty, J. A., in Progress in Inorganic Chemistry, Vol. 10, F. A. Cotton, Ed., Interscience, New York (1968), pp. 49–221.Google Scholar
  6. (b).
    McCleverty, J. A., in MTP International Review of Science, Inorganic Chemistry, Series One, Vol. 2, C. C. Addison and D. B. Sowerby, Eds., Butterworths, London (1972), pp. 301–327.Google Scholar
  7. 5.(a)
    Schrauzer, G. N., in Transition Metal Chemistry, Vol. 4, R. C. Carlin, Ed., Marcel Dekker, New York (1968), pp. 299–335.Google Scholar
  8. (b).
    Schrauzer, G. N., Acc. Chem. Res. 2, 72 (1969).Google Scholar
  9. 6.
    Hoyer, E., Dietzsch, W., and Schroth, W., Z. Chem. 11, 41 (1971).Google Scholar
  10. 7.
    Eisenberg, R., in Progress in Inorganic Chemistry, Vol. 12, S. J. Lippard, Ed., Interscience, New York (1970), pp. 295–369.Google Scholar
  11. 8.
    Miller, J. S., and Epstein, A. J., in Progress in Inorganic Chemistry, Vol. 20, S. J. Lippard, Ed., Interscience, New York (1976), pp. 1–151.Google Scholar
  12. 9.
    Schroth, W., and Peschel, J., Chimia 18, 171 (1964).Google Scholar
  13. 10.
    King, R. B., and Eggers, C. A., Inorg. Chem. 7, 340 (1968).Google Scholar
  14. 11.
    Schrauzer, G. N., and Mayweg, V. P., J. Am. Chem. Soc. 87, 3585 (1965).Google Scholar
  15. 12.
    Hoyer, E., and Schroth, W., Chem. Indus., 652 (1965).Google Scholar
  16. 13.
    Hoyer, E., Dietzsch, W., Hennig, H., and Schroth, W., Chem. Ber. 102, 603 (1969).Google Scholar
  17. 14.
    Browall, K. W., and Interrante, L. V., J. Coord. Chem. 3, 27 (1973).Google Scholar
  18. 15.
    Miles, M. G., and Wilson, J. D., Inorg. Chem. 14, 2357 (1975).Google Scholar
  19. 16.
    Interrante, L. V., Browall, K. W., Hart, Jr., H. R., Jacobs, I. S., Watkins, G. D., and Wee, S. H., J. Am. Chem. Soc. 97, 889 (1975).Google Scholar
  20. 17.
    Interrante, L. V., Bray, J. W., Hart, Jr., H. R., Kasper, J. S., Piacente, P. A., and Watkins, G. D., J. Am. Chem. Soc. 99, 3523 (1977).Google Scholar
  21. 18.
    Kasper, J. S., Interrante, L. V., and Secaur, C. A., J. Am. Chem. Soc. 97, 890 (1975).Google Scholar
  22. 19.
    Bray, J. W., Hart, Jr., H. R., Interrante, L. V., Jacobs, I. S., Kasper, J. S., Piacente, P. A., and Watkins, G. D., Phys. Rev. B 16, 1359 (1977).Google Scholar
  23. 20.
    Getten, C., These, Université des Sciences et Techniques du Languedoc, Académie de Montpellier, 1979.Google Scholar
  24. 21.(a)
    Krespan, C. G., McKusick, B. C., and Cairns, T. L., J. Am. Chem. Soc. 82, 1515 (1960).Google Scholar
  25. (b).
    Krespan, C. G., J. Am. Chem. Soc. 83, 3434 (1961).Google Scholar
  26. 22.
    King, R. B., Inorg. Chem. 2, 641 (1963).Google Scholar
  27. 23.
    Davison, A., Edelstein, N., Holm, R. H., and Maki, A. H., Inorg. Chem. 2, 1227 (1963).Google Scholar
  28. 24.
    Davison, A., and Holm, R. H., Inorg. Synth. 10, 19 (1967).Google Scholar
  29. 25.
    Davison, A., Edelstein, N., Holm, R. H., and Maki, A. H., Inorg. Chem. 3, 814 (1964).Google Scholar
  30. 26.
    Davison, A., Howe, D. V., and Shawl, E. T., Inorg. Chem. 6, 458 (1967).Google Scholar
  31. 27.
    Balch, A. L., Dance, I. G., and Holm, R. H., J. Am. Chem. Soc. 90, 1139 (1968).Google Scholar
  32. 28.
    Davison, A., and Shawl, E. T., Inorg. Chem. 9, 1820 (1970).Google Scholar
  33. 29.
    Schmitt, R. D., Wing, R. M., and Maki, A. H., J. Am. Chem. Soc. 91, 4394 (1969).Google Scholar
  34. 30.
    Wheland, R. C., and Gillson, J. L., J. Am. Chem. Soc. 98, 3916 (1976).Google Scholar
  35. 31.
    Wing, R. M., and Schlupp, R. L., Inorg. Chem. 9, 471 (1970).Google Scholar
  36. 32.
    Dance, I. G., and Solstad, P. J., J. Am. Chem. Soc. 95, 7256 (1973).Google Scholar
  37. 33.
    Geiger, Jr., W. E., and Maki, A. H., J. Phys. Chem. 75, 2387 (1971).Google Scholar
  38. 34.
    Singhabhandhu, A., Robinson, P. D., Fang, J. H., and Geiger, Jr., W. E., Inorg. Chem. 14, 318 (1975).Google Scholar
  39. 35.
    Bray, J. W., Hart, Jr., H. R., Interrante, L. V., Jacobs, I. S., Kasper, J. S., Watkins, G. D., Lee, S. H., and Bonner, J. C., Phys. Rev. Lett. 35, 744 (1975).Google Scholar
  40. 36.
    Jacobs, I. S., Bray, J. W., Hart, Jr., H. R., Interrante, L. V., Kasper, J. S., Watkins, G. D., Prober, D. E., and Bonner, J. C., Phys. Rev. B 14, 3036 (1976).Google Scholar
  41. 37.
    Kasper, J. S., and Interrante, L. V., Acta Crystallogr. B 32, 2914 (1976).Google Scholar
  42. 38.
    Geiger, Jr., W. E., J. Phys. Chem. 77, 1862 (1973).Google Scholar
  43. 39.
    Wudl, F., in The Physics and Chemistry of Low Dimensional Solids, L. J. Alcácer, Ed., Reidel, Dordrecht (1980), pp. 265–279.Google Scholar
  44. 40.
    Interrante, L. V., Bray, J. W., Hart, Jr., H. R., Jacobs, I. S., Kasper, J. S., and Piacente, P. A., in Lecture Notes in Physics: Quasi-One-Dimensional Conductors II, S. Barisic, A. Bjelis, J. R. Cooper, and B. Leontic, Eds., Springer-Verlag, Berlin (1979), pp. 55–68.Google Scholar
  45. 41.
    Locke, J., and McKleverty, J. A., Inorg. Chem. 5, 1157 (1966).Google Scholar
  46. 42.
    Stiefel, E. I., Bennett, L. E., Dori, Z., Crawford, T. H., Simo, C., and Gray, H. B., Inorg. Chem. 9, 281 (1970).Google Scholar
  47. 43.
    Bray, J., Locke, J., McCleverty, J. A., and Coucouvanis, D., Inorg. Synth. 13, 187 (1971).Google Scholar
  48. 44.
    Ciganek, E., and Krespan, C. G., J. Org. Chem. 33, 541 (1968).Google Scholar
  49. 45.
    Billig, E., Williams, R., Bernai, L., Waters, J. H., and Bray, H. B., Inorg. Chem. 3, 663 (1964).Google Scholar
  50. 46.
    Weiher, J. F., Melby, L. R., and Benson, R. E., J. Am. Chem. Soc. 86, 4329 (1964).Google Scholar
  51. 47.
    Novais, H. M., unpublished.Google Scholar
  52. 48.
    Waters, J. H., and Gray, H. B., J. Am. Chem. Soc. 87, 3534 (1965).Google Scholar
  53. 49.
    Waters, J. H., Bergendahl, T. J., and Lewis, S. R., Chem. Commun., 834 (1971).Google Scholar
  54. 50.
    Dance, I. G., and Miller, T. R., Inorg. Chem. 13, 525 (1974).Google Scholar
  55. 51.
    Bechgaard, K., private communication.Google Scholar
  56. 52.
    Hove, M. J., Hoffman, B. M., and Ibers, J. A., J. Chem. Phys. 56, 3490 (1972).Google Scholar
  57. 53.
    Inoue, M., Kuramoto, H., and Nakamura, D., J. Magn. Reson. 33, 409 (1979).Google Scholar
  58. 54.
    Dance, I. G., Solstad, P. J., and Calabrese, J. C., Inorg. Chem. 12, 2161 (1973).Google Scholar
  59. 55.
    Wudl, F., Ho, C. H., and Nagel, A., Chem. Commun., 923 (1973).Google Scholar
  60. 56.
    Wudl, F., J. Am. Chem. Soc. 97, 1962 (1975).Google Scholar
  61. 57.
    Miles, M. G., Wilson, J. D., Dahm, D. J., and Wagenknecht, J. H., Chem. Commun., 751 (1974).Google Scholar
  62. 58.
    Miller, J. S., and Epstein, A. J., J. Coord. Chem. 8, 191 (1979).MATHGoogle Scholar
  63. 59.
    Endres, H., Keller, H. J., Moroni, W., and Nöthe, D., Acta Crystallogr. B 35, 353 (1979).Google Scholar
  64. 60.
    Rosseinsky, D. R., Kite, K., Malpas, R. E., and Hann, R. A., J. Electroanal. Chem. 68, 120 (1976).Google Scholar
  65. 61.
    Rosseinsky, D. R., and Malpas, R. E., J. Electroanal. Chem. 89, 433 (1978).Google Scholar
  66. 62.
    Rosseinsky, D. R., and Malpas, R. E., J. Chem. Soc. Dalton, 749 (1979).Google Scholar
  67. 63.(a)
    Alcácer, L. J., and Maki, A. H., J. Phys. Chem. 78, 215 (1974).Google Scholar
  68. (b).
    Alcácer, L. J., and Maki, A. H., J. Phys. Chem. 80, 1912 (1976).Google Scholar
  69. 64.
    Alcácer, L. J., Novais, H. M., and Pedroso, F. P., in Molecular Metals, W. E. Hatfield, Ed., Plenum Press, New York (1979), pp. 415–418.Google Scholar
  70. 65.
    Perez-Albuerne, E. A., Isett, L. C., and Haller, R. K., Chem. Commun., 417 (1977).Google Scholar
  71. 66.
    Caffery, M. L., and Coucouvanis, D., J. Inorg. Nucl. Chem. 37, 2081 (1975).Google Scholar
  72. 67.
    Coucouvanis, D., Baenziger, N. C., and Johnson, S. M., Inorg. Chem. 13, 1191 (1974).Google Scholar
  73. 68.
    Bergendahl, T. J., and Waters, J. H., Inorg. Chem. 14, 2556 (1975).Google Scholar
  74. 69.
    Manecke, G., and Wöhrle, D., Makrom. Chem. 116, 36 (1968).Google Scholar
  75. 70.
    Schrauzer, G. N., and Mayweg, V. P., J. Am. Chem. Soc. 84, 3221 (1962).Google Scholar
  76. 71.
    Schrauzer, G. N., and Mayweg, V. P., Z. Naturforsch. B 19, 192 (1964).Google Scholar
  77. 72.
    Schrauzer, G. N., and Mayweg, V. P., J. Am. Chem. Soc. 87, 1483 (1965).Google Scholar
  78. 73.
    Schrauzer, G. N., Mayweg, V. P., and Heinrich, W., Inorg. Chem. 4, 1615 (1965).Google Scholar
  79. 74.(a)
    Schrauzer, G. N., Mayweg, V. P., Finck, H. W., Müller-Westerhoff, U., and Heinrich, W., Angew. Chem. (Int. Ed.) 3, 381 (1964).Google Scholar
  80. (b).
    Schrauzer, G. N., and Mayweg, V. P. Angew. Chem. (Int. Ed.) 3, 639 (1964).Google Scholar
  81. 75.
    Schrauzer, G. N., Mayweg, V. P., Finck, H. W., and Heinrich, W., J. Am. Chem. Soc. 88, 4604 (1966).Google Scholar
  82. 76.
    McCleverty, J. A., Atherton, N. M., Locke, J., Wharton, E. J., and Winscom, C. J., J. Am. Chem. Soc. 89, 6082 (1966).Google Scholar
  83. 77.
    Olson, D. C., Mayweg, V. P., and Schrauzer, G. N., J. Am. Chem. Soc. 88, 4876 (1966).Google Scholar
  84. 78.
    Engler, E. M., Patel, V. V., and Schumaker, R. R., IBM Tech. Discl Bull. 20, 2858 (1977).Google Scholar
  85. 79.
    Hurtley, W. R. H., and Smiles, S., J. Chem. Soc. 128, 1821 (1962).Google Scholar
  86. 80.
    Ferretti, A., Org. Synth. Coll. 5, 419 (1973).Google Scholar
  87. 81.
    Baker-Hawkes, M. J., Billig, E., and Gray, H. B., J. Am. Chem. Soc. 88, 4870 (1966).Google Scholar
  88. 82.
    Hünig, S., and Fleckenstein, E., Liebigs Ann. Chem. 738, 192 (1970).Google Scholar
  89. 83.
    Degani, I., and Fochi, R., Synthesis, 471 (1976).Google Scholar
  90. 84.
    Callaghan, A., Layton, A. J., and Nyholm, R. S., Chem. Commun., 399 (1969).Google Scholar
  91. 85.
    Gray, H. B., and Billig, E., J. Am. Chem. Soc. 85, 2019 (1963).Google Scholar
  92. 86.
    Williams, R., Billig, E., and Gray, H. B., J. Am. Chem. Soc. 88, 43 (1966).Google Scholar
  93. 87.
    Jenkins II. J. J., Diss. Abstr. Int. B 38, 5364 (1978).Google Scholar
  94. 88.
    Calas, P., Fabre, J. M., Khalife-el-Saleh, M., Mas, A., Torreilles, E., and Giral, L., Tetrahedron Lett., 4475 (1975).Google Scholar
  95. 89.
    Calas, P., Fabre, J. M., Mas, A., Khalife-el-Saleh, M., Torreilles, E., Cot, L., and Giral, L., Mol. Cryst. Liq. Cryst. 32, 151 (1976).Google Scholar
  96. 90.
    Schrauzer, G. N., and Rabinowitz, H. N., J. Am. Chem. Soc. 90, 4297 (1968).Google Scholar
  97. 91.
    Schläpfer, C. W., and Nakamoto, K., Inorg. Chem. 14, 1338 (1975).Google Scholar
  98. 92.
    Shupack, S. I., Billig, E., Clark, R. J. H., Williams, R., and Gray, H. B., J. Am. Chem. Soc. 86, 4594 (1964).Google Scholar
  99. 93.
    Maki, A. H., Edelstein, N., Davison, A., and Holm, R. H., J. Am. Chem. Soc. 86, 4580 (1964).Google Scholar
  100. 94.
    Schmitt, R. D., and Maki, A. H., J. Am. Chem. Soc. 90, 2288 (1968).Google Scholar
  101. 95.
    Clark, R. J. H., and Turtle, P. C., J. Chem. Soc. Dalton, 2142 (1977).Google Scholar
  102. 96.
    Grim, S. O., Matienzo, L. J., and Swartz, Jr., W. E., Inorg. Chem. 13, 447 (1974).Google Scholar
  103. 97.
    Geiger, Jr., W. E., Allen, C. S., Mines, T. E., and Senftleber, F. C., Inorg. Chem. 16, 2003 (1977).Google Scholar
  104. 98.
    Rosa, E. J., and Schrauzer, G. N., J. Phys. Chem. 73, 3132 (1969).Google Scholar
  105. 99.
    Alcácer, L. J., Novais, H. M., Pedroso, F. P., Flandrois, S., Coulon, C., Chasseau, D., and Gaultier, J., Solid State Commun. 35, 945 (1980).Google Scholar
  106. 100.
    Plumlee, K. W., Hoffman, B. M., Ibers, J. A., and Soos, Z. G., J. Chem. Phys. 63, 1926 (1975).Google Scholar
  107. 101.
    Kobayashi, A., and Sasaki, Y., Bull. Chem. Soc. Jap. 50, 2650 (1977).Google Scholar
  108. 102.
    Plumlee, K. W., Hoffman, B. M., Ratajack, M. T., and Kannewurf, C. R., Solid State Commun. 15, 1651 (1974).Google Scholar
  109. 103.
    Plumlee, K. W., Diss. Abstr. Int. B 36, 6196 (1976).Google Scholar
  110. 104.
    Fritchie, C. J., Acta Crystallogr. 20, 107 (1966).Google Scholar
  111. 105.
    Forrester, J. D., Zalkin, A., and Templeton, D. H., Inorg. Chem. 3, 1500 (1964).Google Scholar
  112. 106.
    Jacobs, L S., Hart, Jr., H. R., Interrante, L. V., Bray, J. W., Kasper, J. S., Watkins, G. D., Prober, D. E., Wolf, W. P., and Bonner, J. C., Physica B 86-88, 655 (1977).Google Scholar
  113. 107.
    Bray, J. W., Hart, Jr., H. R., Interrante, L. V., Jacobs, I. S., Kasper, J. S., Watkins, G. D., Wee, S. H., and Bonner, J. C., AIP Conf. Proc. 29, 504 (1976).Google Scholar
  114. 108.
    Bloch, D., Voiron, J., Bonner, J. C., Bray, J. W., Jacobs, I. S., and Interrante, L. V., Phys. Rev. Lett. 44, 294 (1980).Google Scholar
  115. 109.
    Jacobs, I. S., Interrante, L. V., and Hart, Jr., H. R., AIP Conf. Proc. 24, 355 (1974).Google Scholar
  116. 110.
    Bonner, J. C., Wei, T. S., Hart, Jr., H. R., Interrante, L. V., Jacobs, I. S., Kasper, J. S., Watkins, G. D., and Blöte, H. W. J., J. Appl. Phys. 49, 1321 (1978).Google Scholar
  117. 111.
    Smith, L. S., Ehrenfreund, E., Heeger, A. T., Interrante, L. V., Bray, J. W., Hart, Jr., H. R., and Jacobs, I. S., Solid State Commun. 19, 377 (1976).Google Scholar
  118. 112.
    Moncton, D. E., Birgeneau, R. J., Interrante, L. V., and Wudl, F., Phys. Rev. Lett. 39, 507 (1977).Google Scholar
  119. 113.
    Interrante, L. V., Bray, J. W., Hart, Jr., H. R., Kasper, J. S., Piacente, P. A., and Watkins, G. D., Ann. N. Y. Acad. Sci. 313, 407 (1978).Google Scholar
  120. 114.
    Isett, L. C., Rosso, D. M., and Bottger, G. L., Phys. Rev. B 22, 4739 (1980).Google Scholar
  121. 115.
    Andersen, J. R., Patel, V. V., and Engler, E. M., Tetrahedron Lett., 239 (1978).Google Scholar
  122. 116.
    Rivera, N. M., Engler, E. M., and Schumaker, R. R., Chem. Commun., 184 (1979).Google Scholar
  123. 117.
    Wharton, E. J., and McCleverty, J. A., J. Chem. Soc. A, 2258 (1969).Google Scholar
  124. 118.
    Kasper, J. S., and Moncton, D. E., Phys. Rev. B 20, 2341 (1979).Google Scholar
  125. 119.
    Enemark, J. H., and Lipscomb, W. N., Inorg. Chem. 4, 1729 (1965).Google Scholar
  126. 120.
    Hamilton, W. C., and Bernai, L., Inorg. Chem. 6, 2003 (1967).Google Scholar
  127. 121.
    Browall, K. W., Interrante, L. V., and Kasper, J. S., J. Am. Chem. Soc. 93, 6289 (1971).Google Scholar
  128. 122.
    Browall, K. W., Bursh, T., Interrante, L. V., and Kasper, J. S., Inorg. Chem. 11, 1800 (1972).Google Scholar
  129. 123.
    Schlupp, R. L., and Maki, A. H., Inorg. Chem. 13, 44 (1974).Google Scholar
  130. 124.
    Interrante, L. V., Adv. Chem. Ser. 150, 1 (1976).Google Scholar
  131. 125.
    Interrante, L. V., and Kasper, J. S., AIP Conf. Proc. 53, 205 (1979).Google Scholar

Copyright information

© Plenum Press, New York 1983

Authors and Affiliations

  • L. Alcácer
    • 1
  • H. Novais
    • 1
  1. 1.Serviço de Química-Física Estado SólidoLNETISacavémPortugal

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