Skip to main content

The Infinite Linear Chain Compounds Hg3—δAsF6 and Hg3—δSbF6

  • Chapter

Abstract

The compound Hg3-δ AsF6 was first prepared in 1971 by Gillespie and Ummat1 during the course of experiments which had as their aim the preparation of polyatomic cations of mercury having the general formula Hg2+ n . The mercurous cation Hg2+ 2, 1, has been known for a very long time and it was the unique example of a metal cation containing two covalently bonded metal atoms.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Gillespie, R. J., and Ummat, P. K., J. Chem. Soc. Chem. Commun. 1168 (1971).

    Google Scholar 

  2. Gillespie, R. J., and Passmore, J., Acct. Chem. Res., 4, 413 (1971).

    Article  Google Scholar 

  3. Davies, C. G., Dean, P. A. W., Gillespie, R. J., and Ummat, P. K., J. Chem. Soc. Chem. Commun., 782 (1971).

    Google Scholar 

  4. Cutforth, B. D., Davies, C. G., Dean, P. A. W., Gillespie, R. J., Ireland, P. R., and Ummat, P. K., Inorg. Chem. 12, 1343 (1973).

    Article  Google Scholar 

  5. Torsi, G., Fung, K. W., Begun, G. H., and Mamantov, G., Inorg. Chem. 10, 2285 (1975).

    Article  Google Scholar 

  6. Ellison, R. D., Levy, H. A., and Fung, K. W., Inorg. Chem. 11, 833 (1972).

    Article  Google Scholar 

  7. Cutforth, B. D., Gillespie, R. J., and Ireland, P. R., J. Chem. Soc. Chem. Commun., 723 (1973). Cutforth, B. D., Gillespie, R J., Ireland, P. R., Sawyer, J F., and Ummat, P. K., Inorg. Chem. (in press).

    Google Scholar 

  8. Brown, I. D., Cutforth, B. D., Davies, C. G., Gillespie, R. J., Ireland, P. R., and Vekris, J. E., Can. J. Chem. 52, 791 (1974).

    Article  Google Scholar 

  9. Cutforth, B. D., and Gillespie, R. J., Inorg. Syntheses 19, 22 (1979).

    Article  Google Scholar 

  10. Miro, N. D., MacDiarmid, A. G., Heeger, A. J., Garito, A. F., Chiang, C. K., Schultz, A. J., and Williams, J. M., J. Inorg. Nucl. Chem. 40, 1351 (1978).

    Article  Google Scholar 

  11. Chartier, D., Ph.D. thesis, McMaster University, 1982.

    Google Scholar 

  12. Gillespie, R. J., and Morton, M. J., Q. Rev. Chem. Soc. 25, 53 (1971).

    Article  Google Scholar 

  13. Schultz, A. J., Williams, J. M., Miro, N. D., MacDiarmid, A. G., and Heeger, A. J., Inorg. Chem. 17, 646 (1978).

    Article  Google Scholar 

  14. Pouget, J. P., Shirane, G., Hasting, J. M., Heeger, A. J., Miro, N. D., and MacDiarmid, A. G., Phys. Rev. B 18, 3645 (1978).

    Article  Google Scholar 

  15. Tun, Z., and Brown, I. D., Acta. Crystallogr. B. (in press).

    Google Scholar 

  16. Datars, W. R., Van Schyndel, A., Lass, J. S., Chartier, D., and Gillespie, R. J., Phys. Rev. Lett. 40, 1184 (1978).

    Article  Google Scholar 

  17. Cutforth, B. D., Datars, W. R., Van Schyndel, A., and Gillespie, R. J., Solid State Commun. 21, 377 (1977).

    Article  Google Scholar 

  18. Chiang, C. K., Spal, R., Denenstein, A. M., Heeger, A. J., Miro, N. D., and MacDiarmid, A. G., Solid State Commun 22, 293 (1977).

    Article  Google Scholar 

  19. Peebles, D. L., Chiang, C. K., Cohen, M. J., Heeger, A. J., Miro, N. D., and MacDiarmid, A. G., Phys. Rev. B 15, 4607 (1977).

    Article  Google Scholar 

  20. Batalla, E., M. Sc. thesis, McMaster University, 1976.

    Google Scholar 

  21. Koteles, E. S., Datars, W. R., Cutforth, B. D., and Gillespie, R. J., Solid State Commun. 20, 1129 (1976).

    Article  Google Scholar 

  22. Spal, R., Chiang, C. K., Denenstein, A. M., Heeger, A. J., Miro, N. D., and MacDiarmid, A. G., Phys. Rev. Lett. 39, 650 (1977).

    Article  Google Scholar 

  23. Chakraborty, D. P., Spal, R., Chiang, C. K., Denenstein, A. M., Heeger, A. J., and MacDiarmid, A. G., Solid State Commun. 27, 849 (1978).

    Article  Google Scholar 

  24. Kaveh, M., and Ehrenfreund, E., Solid State Commun. 31, 709 (1979).

    Article  Google Scholar 

  25. Emery, V. J., and Axe, J. D., Phys. Rev. Lett. 40, 1507 (1978).

    Article  Google Scholar 

  26. Janner, A., and Janssen, T., Acta Crystallogr. A 36, 408 (1980).

    Article  MathSciNet  Google Scholar 

  27. Hastings, J. M., Pouget, J. P., Shirane, G., Heeger, A. J., Miro, N. D., and MacDiarmid, A. G., Phys. Rev. Lett. 39, 1484 (1977).

    Article  Google Scholar 

  28. Sacco, J. E., and Sokoloff, J. B., Phys. Rev. B 18, 6549 (1978).

    Article  Google Scholar 

  29. Heilmann, I. U., Axe, J. D., Hastings, J. M., Shirane, G., Heeger, A. J., and MacDiarmid, A. G., Phys. Rev. B 20, 752 (1979).

    Article  Google Scholar 

  30. Heilmann, I. U., Hastings, J. M., Shirane, G., Heeger, A. J., and MacDiarmid, A. G., Solid State Commun. 29, 469 (1979).

    Article  Google Scholar 

  31. Wei, T., Garito, A. F., Chiang, C. K., and Miro, N. D., Phys. Rev. B 16, 3373 (1977).

    Article  Google Scholar 

  32. Moses, D., Denenstein, A., Heeger, A. J., Nigrey, P. J., and MacDiarmid, A. G., Phys. Rev. Lett. 16, 3373 (1979).

    Google Scholar 

  33. Tarasov, V. V., in New Problems in the Physics of Glass, Oldbourne, London (1963).

    Google Scholar 

  34. Spal, R., Chen, C. E., Denenstein, A. M., McGhil, A. A., Heeger, A. J., and MacDiarmid, A. G., Solid State Commun. 32, 641 (1979).

    Article  Google Scholar 

  35. Batalla, E., Datars, W. R., Chartier, D., and Gillespie, R. J., to be published.

    Google Scholar 

  36. Gold, A. V., in Solid State Physics. I. Electrons in Metals, J. F. Cochrane and R. R. Haering, Eds, Gordon and Breach, New York (1967), pp. 39–126.

    Google Scholar 

  37. Razavi, F. S., Datars, W. R., Chartier, D., and Gillespie, R. J., Phys. Rev. Lett. 42, 1182 (1979).

    Article  Google Scholar 

  38. Batalla, E., Razavi, F. S., and Datars, W. R., Phys. Rev. B 25, 2109 (1982).

    Article  Google Scholar 

  39. Ehrenfreund, E., Newman, P. R., Heeger, A. J., Miro, N. D., and MacDiarmid, A. G., Phys. Rev. B 16, 1781 (1977).

    Article  Google Scholar 

  40. Berlinsky, J., private communication.

    Google Scholar 

  41. Azbel, M. Ya., Phys. Rev. Lett. 43, 1954 (1979).

    Article  Google Scholar 

  42. Batalla, E., Datars, W. R., Chartier, D., and Gillespie, R. J., Solid State Commun., 40, 465 (1982).

    Google Scholar 

  43. Cook, J. R., and Datars, W. R., Phys. Rev. B 1, 1415 (1970).

    Article  Google Scholar 

  44. Visscher, P. B., and Falicov, L. M., Phys. Rev. B 2, 1518 (1970).

    Article  Google Scholar 

  45. Dinser, R. J., Datars, W. R., Chartier, D., and Gillespie, R. J., Solid State Commun. 32, 1041 (1979).

    Article  Google Scholar 

  46. Chakraborty, D. P., Spal, R., Denenstein, A. M., Lee, K-B., Heeger, A. J., and Azbel, M. Ya., Phys. Rev. Lett. 43, 1832 (1979).

    Article  Google Scholar 

  47. Rosenthal, M. D., and Maxfield, B. W., Rev. Sci. Instrum. 46, 398 (1975).

    Article  Google Scholar 

  48. Chiang, C. K., Spal, R., Denenstein, A., Heeger, A. J., Miro, N. D., and MacDiarmid, A. G., in Thermoelectricity of Metallic Conductors, F. J. Blatt and P. A. Schroder, Eds., Plenum Press, New York (1978), p. 393.

    Google Scholar 

  49. Scholz, G. A., Datars, W. R., Chartier, D., and Gillespie, R. J., Phys. Rev. B 16, 4209 (1977).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1983 Plenum Press, New York

About this chapter

Cite this chapter

Brown, I.D., Datars, W.R., Gillespie, R.J. (1983). The Infinite Linear Chain Compounds Hg3—δAsF6 and Hg3—δSbF6 . In: Miller, J.S. (eds) Extended Linear Chain Compounds. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-4175-8_1

Download citation

  • DOI: https://doi.org/10.1007/978-1-4684-4175-8_1

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-4177-2

  • Online ISBN: 978-1-4684-4175-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics