Abstract
Surface enhanced Raman scattering from molecular monolayers adsorbed in tunnel junctions and at single crystal surfaces in ultra high vacuum has been studied as a function of surface topography, the adsorbate and the energy of the vibrational mode. Surface enhanced Raman scattering is shown to involve both the enhancement of the local electric fields at the rough noble metal surface due to the optical excitation of surface plasmon polaritons and the modulation of the optically induced surface charge density by the molecular vibrations.
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References
M. Fleischmann,P.J. Hendra and A.J. McQuilla, Chem. Phys. Lett. 26, 163 (1974).
D.L. Jeanmaire and R.P. van Duyne, J. Electroanal. Chem. 84, 1 (1977).
M.G. Albrecht, J.A. Creighton, R.E. Hester and J.A.D. Matthew, Chem. Phys. Lett. 55, 55 (1978).
R.R. Smardzewski, R.J. Colton and J.S. Murdey, Chem. Phys. Lett. 68, 53 (1979).
G.R. Easley (private communication).
T.A. Wood and M.V. Klein, J. Vac. Sci. Technol. 16, 459 (1979); I. Pockrand and A. Otto (private communication).
M. Moskovits (private communications).
J.M. Rowe, C.V. Shank, D.A. Zwemer and C.A. Murray, Phys. Rev. Lett. 44, 1770 (1980).
E. Burstein, C.Y. Chen and S. Lundqvist. US-USSR Symposium of Light Scattering, ed. J.L. Birman, H.Z. Cummins and K.K. Rebane ( Plenum, New York 1980 ). p. 479.
H. Seki and M. Philpott, (private communication).
J.C. Tsang and J.R. Kirtley, Solid State Commun. 30, 617 (1980).
J.C. Tsang, J.R. Kirtley and J.A. Bradley, Phys. Rev. Lett. 43, 772 (1979).
P.N. Sanda, J.M. Warlaumont, J.E. Demuth, J.C. Tsang, K. Christmann and J.A. Bradley, (submitted for publication).
Y.J. Chen, W.P. Chen and E. Burstein, Phys. Rev. Lett. 36, 1207 (1976).
M. Moskovits, J. Chem. Phys. 69, 4159 (1978)
D.S. Wang, M. Kerker and H. Chew, Appl. Optics 19, 2315 (1980).
M. Philpott, J. Chem. Phys. 62, 1812 (1975)
S. Efrima and H. Metiu, Chem. Phys. Lett. 60, 59 (1978)
F.W. King, R.P. van Duyne and G.C. Schatz, J. Chem. Phys. 69, 4472 (1978).
J.R. Kirtley, S.S. Jha and J.C. Tsang, Solid State Commun. 35, n° 7 (1980).
D. Heitmann, Optics Commun. 20, 292 (1977).
John Kirtley and P.K. Hansma, Phys. Rev. B13, 2910 (1976).
R.V. Coleman (private communication).
C.S. Korman, J.C. Lau, A.M. Johnson and R.V. Coleman, Phys. Rev. B19, 994 (1979).
J.R. Kirtley, T.N. Theis and J.C. Tsang, Appl. Phys. Lett. 37, 435 (1980).
S.S.Jha, J.R. Kirtley and J.C. Tsang, Phys. Rev. B22, n° 8 (1980).
S.L. McCarthy and J. Lambe, Appl. Phys. Lett. 30, 427 (1977).
M. Dujardin and M. Theye, J. Phys. Chem. Solids 32, 2033 (1971).
J.D. Langan and P. Hansma, Surf. Sci. 52, 211 (1975).
A.E.T. Kuiper, J. Madema and J.J.G.M. van Bokhoven, J. Catal. 29, 40 (1973).
J.E. Demuth (this conference).
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© 1982 Plenum Press, New York
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Tsang, J.C., Kirtley, J.R., Jha, S.S. (1982). Surface Enhanced Raman Scattering from Characterized Metal Surfaces. In: Caudano, R., Gilles, JM., Lucas, A.A. (eds) Vibrations at Surfaces. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-4058-4_34
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DOI: https://doi.org/10.1007/978-1-4684-4058-4_34
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