Solid State Metal-Ceramic Reaction Bonding

  • F. P. Bailey
  • W. E. Borbidge
Part of the Materials Science Research book series (MSR, volume 14)


It has been found that when certain metals and ceramic materials are held in intimate contact and heated, a reaction occurs at the interface. This results in a strong bond being formed which remains durable even after long periods at elevated temperatures.

With base metals the reaction that occurs results in a macroscopic spinel-type bond being formed between metal and ceramic. “Noble” metals also undergo a similar bonding reaction, which has been observed directly in the electron microscope at magnifications of several 100,000, where an intermediate liquid phase can be seen to form at the metal surface and run over the surface of the ceramic. This phase does not recrystallize on cooling, and the nature of the bond mechanism is not understood.

This process, which is known as “Solid State Reaction Bonding”, has important industrial uses, particularly those involving high temperature “in service” conditions. In general, reaction bonding occurs with a wide range of metals and ceramics, but platinum, gold, copper and nickel appear to be the most significant industrially.


Reaction Bonding Beryllium Oxide Aluminium Silicate Lead Platinum Leak Tightness 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


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  1. 1.
    A. Roth, Vacuum Sealing Techniques, Pergamon Press, Oxford, p. 197 (1966).Google Scholar
  2. 2.
    W.H. Kohl, Handbook of Materials and Techniques for Vacuum Devices, Reinhold Publishing Co., New York, Chapter 15 (1967).Google Scholar
  3. 3.
    H.J. de Bruin, Method of Bonding Beryllium Oxide to Graphite, U.S. Patent 3300852, February 1964.Google Scholar
  4. 4.
    A.G. Buyers, Ceramic-Metal Seal, U.S. Patent 3254403, November 1964.Google Scholar
  5. 5.
    N.V. Philips, Procédé permettant d’assembler hermétiquement un objet métallique et des matériaux céramiques, Gloeilampen-fabricken, French Patent 1545493, November 1966.Google Scholar
  6. 6.
    J.T. Klomp, Sci. Ceram. 5, 501 (1970).Google Scholar
  7. 7.
    J.T. Klomp, Bull. Amer. Ceram. Soc. 51, 683–688 (1972).Google Scholar
  8. 8.
    H. Schmidt-Brüchen and W. Schlapp, Keram. Z. 24, 427 (1972).Google Scholar
  9. 9.
    A.F. Moodie and C.E. Warble, paper presented at XXII International Congress of Pure and Applied Chemistry, Sydney, Australia, August 1969.Google Scholar
  10. 10.
    A.F. Moodie and C.E. Warble, Phil. Mag. 35, 201 (1977).CrossRefGoogle Scholar
  11. 11.
    H.J. de Bruin, A.F. Moodie and C.E. Warble, J. Mater. Sci. 7, 909 (1972).CrossRefGoogle Scholar
  12. 12.
    H.J. de Bruin, A.F. Moodie and C.E. Warble, Gold Bull. 5, 62–64 (1972).CrossRefGoogle Scholar
  13. 13.
    CSIRO and The Flinders University, South Australia, Chemical Bonding of Metals to Ceramic Materials, Australian Patent 452651, Italian Patent 920003, British Patent 1352775, U.S. Patent 4050956.Google Scholar
  14. 14.
    F.P. Bailey and K.J.T. Black, J. Mater. Sci. 13, 1045–1052 (1978).CrossRefGoogle Scholar
  15. 15.
    F.P. Bailey and K.J.T. Black, J. Mater. Sci. 13, 1606–1608 (1978).CrossRefGoogle Scholar
  16. 16.
    E.A. Gulbransen and K.F. Andrew, J. Electrochem. Soc. 104, 451–454 (1957).CrossRefGoogle Scholar
  17. 17.
    J.F. Burgess, C.A. Neugebauer and G. Flanagan, J. Electrochem. Soc. 122, 688–690 (1975).CrossRefGoogle Scholar

Copyright information

© Plenum Press, New York 1981

Authors and Affiliations

  • F. P. Bailey
    • 1
  • W. E. Borbidge
    • 1
  1. 1.Division of Chemical PhysicsCSIROAustralia

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