Advertisement

Solid Electrolytes

  • Robert A. Huggins
Part of the NATO Conference Series book series (NATOCS, volume 2)

Abstract

This paper will discuss a number of aspects of solid electrolytes that are relevant to their potential use in practical advanced batteries. It is intended to serve as a starting point for the considerations of the solid electrolyte study group, rather than as an exposition of the current state of knowledge in this area.

Keywords

Solid Electrolyte Minimum Energy Path Lithium Iodide Alkali Silicate Solid Electro 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    R. A. Huggins and A. Rabenau, Mat. Res. Bull. 13, 1315 (1978).CrossRefGoogle Scholar
  2. 2.
    W. F. Flygare and R. A. Huggins, J. Phys. Chem. Solids 34, 1199 (1973).CrossRefGoogle Scholar
  3. 3.
    O. B. Ajayi, Ph.D. Dissertation, Stanford University (1975).Google Scholar
  4. 4.
    O. B. Ajayi, L. E. Nagel, I. D. Raistrick and R. A. Huggins, J. Phys. Chem. Solids 37, 167 (1976).CrossRefGoogle Scholar
  5. 5.
    R. A. Huggins, “Crystal Structures and Fast Ionic Conduction,” in Solid Electrolytes, ed. by P. Hagenmuller and W. van Gool, Academic Press (1978), p. 27.Google Scholar
  6. 6.
    R. A. Huggins, “Evaluation of Properties Related to the Application of Fast Ionic Transport in Solid Electrolytes and Mixed Conductors,” Proceedings of International Conference on EAst Ion Transport in Solids, Elsevier North-Holland (1979).Google Scholar
  7. 7.
    A. Potier and D. Rousselet, J. Chim. Phys. 70, 873 (1973).Google Scholar
  8. 8.
    P. H. Bottelberghs, “Anomalous Electrical Conductivity in Na2WO4,” in Fast Ion Transport in Solids, ed. by W. van Gool, North-Holland (1973), p. 637.Google Scholar
  9. 9.
    P. H. Bottelberghs and E. Everts, J. Solid State Chem. 14, 342 (1975).CrossRefGoogle Scholar
  10. 10.
    P. H. Bottelberghs and F. R. van Buren, J. Solid State Chem. 13, 182 (1975).CrossRefGoogle Scholar
  11. 11.
    W. Weppner and R. A. Huggins, “Thermodynamic Properties of the Solid Electrolyte LiAℓCℓ4,” Proceedings of International Conference on East Ion Transport in Solids, Elsevier North-Holland (1979).Google Scholar
  12. 12.
    I. Barin and O. Knacke, Thermochemical Properties of Inorganic Substances, Springer, Berlin (1973).Google Scholar
  13. 13.
    R. M. Yonco, E. Valeckis and V. A. Maroni, J. Nucl. Mat. 57, 317 (1977).CrossRefGoogle Scholar
  14. 14.
    A. Bonomi, M. Hadate and C. Gentaz, J. Electrochem. Soc. 124, 982 (1977).CrossRefGoogle Scholar
  15. 15.
    P. Hartwig, W. Weppner and W. Wichelhaus, Mat. Res. Bull. 14, 493 (1979).CrossRefGoogle Scholar
  16. 16.
    P. Hartwig, W. Weppner and W. Wichelhaus, “Fast Ionic Conduction in Solid Lithium Nitride Halides,” Proceedings of International Conference on Fast Ion Transport in Solids, Elsevier North Holland (1979).Google Scholar
  17. 17.
    P. Hartwig, W. Weppner, W. Wichelhaus and A. Rabenau, Solid State Communications, in press.Google Scholar
  18. 18.
    J. B. Goodenough, H. Y-P Hong and J. A. Kafalas, Mat. Res. Bull. 11, 203 (1976).CrossRefGoogle Scholar
  19. 19.
    J. A. Kafalas and R. J. Cava, “Effect of Pressure and Composition on Fast Na+-Ion Transport in the System Na1+X zr2SixP3-xO12,” Proceedings of International Conference on Fast Ion Transport in Solids, Elsevier North-Holland (1979).Google Scholar
  20. 20.
    J. Bruinink, J. Appl. Electrochem 2, 239 (1972).CrossRefGoogle Scholar
  21. 21.
    L. Glasser, Chem. Rev. 75, 21 (1975).CrossRefGoogle Scholar
  22. 22.
    M. G. Shilton and A. T. Howe, Mat. Res. Bull 12, 701 (1977).CrossRefGoogle Scholar
  23. 23.
    P. E. Childs, A. T. Howe and M. G. Shilton, J. Power Sources 3, 105 (1978).CrossRefGoogle Scholar
  24. 24.
    A. T. Howe, M. G. Shilton and P. E. Childs, “Fast Proton Conduction in Hydrogen Uranyl Phosphate and Arsenate,” presented at Second International Meeting on Solid Electrolytes, St. Andrews, Scotland, September 1978.Google Scholar
  25. 25.
    T. K. Halstead, T. C. Jones, R. C. T. Slade and P. E. Childs, “Hydrogen Mobility Studies in Solid Electrolyte and Electrode Materials Using NMR,” presented at Second International Meeting on Solid Electrolytes, St. Andrews, Scotland, September 1978.Google Scholar
  26. 26.
    M. G. Shilton and A. T. Howe, “Evidence for Proton Conductivity in Compounds in the Hydrogen-Uranyl-Periodate-Water System,” Proceedings of International conference on Fast Ion Transport in Solids, Elsevier North-Holland (1979).Google Scholar
  27. 27.
    A. T. Howe and M. G. Shilton, J. Solid State Chem. 28 (1979).Google Scholar
  28. 28.
    G. C. Farrington and J. L. Briant, presented at Electrochemical Society Meeting, Atlanta, October, 1977.Google Scholar
  29. 29.
    G. C. Farrington, J. L. Briant and H. S. Story, “Conductance and Spectroscopy of Protonic Beta and Beta” Aluminas,” presented at Second International Meeting on Solid Electrolytes, St. Andrews, Scotland (1978).Google Scholar
  30. 30.
    Ph. Colomban, A. Kahn and J. P. Boilot, “Protonic Conductors with the β and β″ Aℓ2O3 Structure,” presented at Second International Meeting on solid Electrolytes, St. Andrews, Scotland (1978).Google Scholar
  31. 31.
    G. C. Farrington and J. L. Briant, Mat. Res. Bull. 13, 763 (1978).CrossRefGoogle Scholar
  32. 32.
    G. C. Farrington and J. L. Briant, “Chemistry and Conductivity of Protonic Beta Aluminas,” Proceedings of International Conference on Fast Ionic Transport in Solids, Elsevier North-Holland (1979).Google Scholar
  33. 33.
    S. H. Sheffield and A. T. Howe, Mat. Res. Bull 14, 929 (1979).CrossRefGoogle Scholar
  34. 34.
    R. Calvet and J. Mamy, C. R. Acad. Sci. Paris 2720, 1251 (1971).Google Scholar
  35. 35.
    O. Nakamura, T. Kodama, I. Ogino and Y. Miyake, Japan Kokai Patent 76106683 (1976).Google Scholar
  36. 36.
    O. Nakamura et al., U. S. Patent 4025036 (1977).Google Scholar
  37. 37.
    O. Nakamura et al., Japan Patent 899328 (1978).Google Scholar
  38. 38.
    O. Nakamura et al., Chemistry Letters 17 (1979).Google Scholar
  39. 39.
    W. A. England, M. G. Cross, A. Hamnett, P. J. Wiseman and J. B. Goodenough, presented at Faraday Division Electrochemistry Group Meeting, Oxford, March, 1979.Google Scholar
  40. 40.
    T. Takahashi, S. Tanase, O. Yamamoto and S. Yamauchi, J. Solid State Chem 17, 353 (1976).CrossRefGoogle Scholar
  41. 41.
    B. S. Dunn and J. D. Mackenzie, “Structure and Ionic Properties of Glasses,” in International Review of Science, Physical Chemistry Series Two, Vol. 6, ed. by J. O’M. Bockris, Butter-worths (1976), p. 231.Google Scholar
  42. 42.
    J. L. Souquet and D. Ravaine, Proceedings of 24th Meeting of the ISE, Eindhoven (1973).Google Scholar
  43. 43.
    D. Ravaine, These, Inst. Nat. Polytechnique, Grenoble (1976).Google Scholar
  44. 44.
    D. Ravaine and J. L. Souquet, Phys. Chenu Glasses 18, 27 (1977).Google Scholar
  45. 45.
    D. Ravaine and J. L. Souquet, “Ionic Conductive Glasses,” in Solid Electrolytes ed. by P. Hagenmuller and W. van Gool, Academic Press (1978), p. 277.Google Scholar
  46. 46.
    A. Kone, B. Barrau, J. L. Souquet and M. Ribes, Mat. Res. Bull. 14, 393 (1979).CrossRefGoogle Scholar
  47. 47.
    A. Levasseur, B. Calee, J.-M. Reau and P. Hagenmuller, Mat. Res. Bull 13, 205 (1978).CrossRefGoogle Scholar
  48. 48.
    A. Levasseur, J.-C. Brethous, J.-M. Reau and P. Hagenmuller, Mat. Res. Bull. 14, 921 (1979).CrossRefGoogle Scholar
  49. 49.
    W. Jeitschko, Acta Cryst. B28, 60 (1972).Google Scholar
  50. 50.
    W. Jeitschko and T. A. Bither, Z. Naturforsch. 27b, 1423 (1972).Google Scholar
  51. 51.
    W. Jeitschko, T. A. Bither and P. E. Bierstedt, Act. Cryst. B33, 2767 (1977).Google Scholar
  52. 52.
    J. P. Malugani, A. Wasniewski, M. Doreau and G. Robert, C. R. Acad. Sci. Paris 284C, 99 (1977).Google Scholar
  53. 53.
    J.-C. Reggiani, J.-P. Malugani and J. Bernard, J. Chim. Phys. 75, 849 (1978).Google Scholar
  54. 54.
    J.-P. Malugani and G. Robert, Mat. Res. Bul. 14, 1075 (1979).CrossRefGoogle Scholar
  55. 55.
    J. Kuwamo, T. Isoda and M. Kato, Denki Kagaku 45, 104 (1977).Google Scholar
  56. 56.
    M. Lazzari, B. Scrosati and C. A. Vicent, Electrochim. Acta 22, 51 (1977).CrossRefGoogle Scholar
  57. 57.
    M. Lazzari, B. Scrosati and C. A. Vicent, “Vitreous Solid Electrolytes,” Proceedings of International Conference on Fast Ion Transport in Solids, Elsevier North-Holland (1979).Google Scholar
  58. 58.
    S. I. Smedley and C. A. Angell, Solid State Comm. 27, 21 (1978).CrossRefGoogle Scholar
  59. 59.
    C. A. Angell and L. Boehm, “Ionic Conductivity in Lithium Oxide-Fluoride Glasses,” Proceedings of Intenational Conference on Fast Ion Transport in Solids, Elsevier North-Holland (1979).Google Scholar
  60. 60.
    A. M. Glass and K. Nassau, “High Alkali Ion Conductivity in Rapidly Quenched Oxides Containing No Network Formers,” Pro-deedings of International Conference on Fast Ion Transport in Solids, Elsevier North-Holland (1979).Google Scholar
  61. 61.
    P. V. Wright, British Polymer Jour. 7, 319 (1975).CrossRefGoogle Scholar
  62. 62.
    M. Armand, J. M. Chabagno and M. Duclot, “Polymeric Solid Electrolytes,” presented at Second International Meeting on Solid Electrolytes, St. Andrews (1978).Google Scholar
  63. 63.
    M. B. Armand, J. M. Chabagno and M. Duclot, “Poly-Ethers as Solid Electrolytes,” Proceedings of International Conference on Fast Ion Transport in Solids, Elsevier North-Holland (1979).Google Scholar
  64. 65.
    D. Chapin, H. Cheradame, J. M. Latour and J. L. Souquet, Proceedings of European Symposium on Electric Phenomena in Polymer Science, Pisa (1978).Google Scholar
  65. 66.
    Y-W. Hu, I. Raistrick and R. A. Huggins, Mat. Res. Bull. 11, 1227 (1976).CrossRefGoogle Scholar
  66. 67.
    R. A. Huggins, Electrochimica Acta 22, 773 (1977).CrossRefGoogle Scholar
  67. 68.
    Y-W. Hu, I. D. Raistrick and R. A. Huggins, J. Electrochem. Soc. 124, 1240 (1977).CrossRefGoogle Scholar
  68. 69.
    Y-W. Hu, Ph.D. Dissertation, Stanford University (1979).Google Scholar
  69. 70.
    R. F. Aspandiar, unpublished results, Stanford University.Google Scholar

Copyright information

© Plenum Press, New York 1980

Authors and Affiliations

  • Robert A. Huggins
    • 1
  1. 1.Department of Materials Science & EngineeringStanford UniversityStanfordUSA

Personalised recommendations