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Kinetic and Morphological Aspects of Lithium Electrodes at Ambient Temperature in Propylene Carbonate

  • Israël Epelboin
  • Michel Froment
  • Michel Garreau
  • Jacques Thevenin
  • Dominique Warin
Part of the NATO Conference Series book series (NATOCS, volume 2)

Abstract

Advance in the realization of high energy secondary batteries using lithium as negative electrode is hindered by the impossibility of obtaining a great number of cycles with lithium electrodeposits strippable with high coulombic efficiencies. The difficulties encountered are linked to the reactivity of Lithium which, with all the electrolytes known, leads to the formation of passivating layers whose influence on the lithium electrochemical behavior has not been elucidated yet.

Keywords

Scanning Electron Microscope Observation Propylene Carbonate Rotate Disc Electrode Exchange Current Density Lithium Perchlorate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    A.N. Dey “Electrochemical alloying of lithium in organic electrolytes”, J. of Electrochem. Soc. 118: 1547 (1971).CrossRefGoogle Scholar
  2. 2.
    J.R. Van Beck and P.J. Rommers “Behavior of the secondary electrode on alloying substrates in propylene carbonate based electrolytes” 11th International Power Sources Symposium Brighton (1978) paper 37.Google Scholar
  3. 3.
    M. Froment, M. Garreau, J. Thevenin and D. Warin “Sur la nature des couches passivantes formées sur l’électrode de lithium en présence de carbonate de propylène et de perchlorate de lithiun J. Microsc. Spectrosc. Electron. 4: 111 (1979).Google Scholar
  4. 4.
    M. Garreau, J. Thevenin and D. Warin “Cycling behavior of lithium in propylene carbonate-LiClO4 electrolyte” Progress in Batteries and Solar cells 2: 54 (1979).Google Scholar

Copyright information

© Plenum Press, New York 1980

Authors and Affiliations

  • Israël Epelboin
    • 1
  • Michel Froment
    • 1
  • Michel Garreau
    • 1
  • Jacques Thevenin
    • 1
  • Dominique Warin
    • 1
  1. 1.“Physique des Liquides et Electrochimie”, Groupe de Recherche n°4 du C.N.R.S. associé àl’Université Pierre et Marie CurieParis Cedex 05France

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