Rheology pp 487-492 | Cite as

Capillary Rheometry of Polypropylene: Influence of Molecular Weight on die Swelling

  • D. Romanini
  • G. Pezzin


Although there is a relatively large number of papers in the literature concerning the phenomenon of “die swell”, the knowledge of the molecular parameters that influence the expansion of a polymer at the die exit is still scarce, and most of the data collected up to now relate to polystyrene and polyethylene (1–7). To the best of the authors’ knowledge, only Coen and Petraglia (8), Han and coworkers (9), and Fujiyama and Awaya (10) have investigated polypropylene. This polymer is essentially linear and it is well suited for investigations in which a better understanding of the relationship between average molecular weight and rheological properties is required.


Shear Stress Average Molecular Weight High Density Polyethylene Master Curve Extrusion Temperature 
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  1. 1).
    C.D. Han, Rheology in Polymer Processing, Academic Press, N.Y, (1976).Google Scholar
  2. 2).
    N. Nakajima and M. Shida, Trans. Soc. Rheol., 10, 299 (1966).CrossRefGoogle Scholar
  3. 3).
    W.W. Graessley, S.D. Glasscock and R.L. Crawley, Trans. Soc. Rheol., 14, 519 (1970).CrossRefGoogle Scholar
  4. 4).
    J. Vlachopoulos, M. Horie and S. Lidorikis, Trans. Soc. Rheol., 16, 669 (1972).CrossRefGoogle Scholar
  5. 5).
    M.G. Rogers, J. Appl. Polym. Sci., 14, 1679 (1970).CrossRefGoogle Scholar
  6. 6).
    G. Locati, Rheol. Acta, 15, 525 (1976).CrossRefGoogle Scholar
  7. 7).
    R. Racin and D.C. Bogue, J. Rheology, 23, 263 (1979).ADSCrossRefGoogle Scholar
  8. 8).
    A. Coen and G. Petraglia, Polym. Eng. Sci., 10, 79 (1970).CrossRefGoogle Scholar
  9. 9).
    C.D. Han, M. Charles and W. Philippoff, Trans. Soc. Rheol., 14, 393 (1970).CrossRefGoogle Scholar
  10. 10).
    M. Fujiyama and Awaya, J. Appl. Polym. Sci., 16, 275 (1972).CrossRefGoogle Scholar
  11. 11).
    R.A. Mendelson, F.L. Finger and E.B. Bagley, J. Polym. Sci. C, 35, 177 (1971).CrossRefGoogle Scholar
  12. 12).
    F. Danusso, G. Moraglio, W. Ghiglia, L. Motta and G. Talamini, La Chimica e l’Industria, 41(8), 748 (1950).Google Scholar
  13. 13).
    R.I. Tanner, J. Polym. Sci., A-2, 8, 2067 (1970).Google Scholar
  14. 14).
    D. Romanini, A. Savadori and G. Gianotti, Rheology of branched LDPE, Polymer, in press.Google Scholar
  15. 15).
    R.A. Mendelson and F.L. Finger, J. Appl. Polym. Sci., 19, 1061 (1975).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1980

Authors and Affiliations

  • D. Romanini
    • 1
  • G. Pezzin
    • 1
    • 2
  1. 1.Research Centre of Plastics DivisionMontedison S. p. A.FerraraItaly
  2. 2.Macromolecular Physics CentreC. N. R.BolognaItaly

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