Abstract
Experimental results are presented for the size separation of polystyrene latexes using a porous packed system of a single large pore size. Parameters such as separation factor, ionic strength, flow rate, axial dispersion, and resolution are considered, and compared to results obtained using nonporous hydrodynamic chromatography (HDC). The porous system shows improved peak separation, however, overall resolution is decreased due to increased axial dispersion. A parallel flow-through bank model is presented to account for the ionic strength behavior of the separation factor in a porous system. Resolution in terms of optimum signal detection is discussed to account for absorption and scattering effects of polystyrene latexes. Overall improvement in HDC signal resolution resulting from optical density measurements in the absorbing region is shown to occur.
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References
H. Small, J. Colloid Interface Sci., 48, 147 (1974).
H. Small, F. L. Saunders, and J. Sole, Adv. Colloid Interface Sci., 6, 237 (1976).
R. F. Stoisits, G. W. Poehlein, and J. W. Vanderhoff, J. Colloid Interface Sci., 57, 337 (1976).
A. J. McHugh, C. A. Silehi, G. W. Poehlein, and J. W. Vanderhoff, paper presented at A.I.Ch.E Meeting, Houston, Texas (March 1977).
C. A. Silebi and A. J. McHugh, A.I.Ch.E. J., 24, 204 (1978).
D. C. Prieve and P. M. Hoysan, J. Colloid Interface Sci., 64, 201 (1978).
C. A. Silebi and A. J. McHugh, J. Appl. Polym. Sci., 23, 1699 (1979).
K. F. Krebs and W. Wunderlich, Angew, Makromol. Chem., 20, 203 (1971).
H. Coll, G. R. Fague, and K. A. Robillard, Exclusion Chromatography of Colloidal Dispersions, unpublished manuscript, Eastman Kodak Co., Rochester, New York (1975).
S. Singh and A. E. Hamielec, J. Appl. Polym. Sci., 22, 577 (1978).
A. J. McHugh, C. A. Silebi, G. W. Poehlein, and J. W. Vanderhoff, Colloid Interface Sci., IV, 549 (1976).
D. J. Nagy, C. A. Silebi, and A. J. McHugh, Hydrodynamic Chromatography of Polymer Latexes Using Porous Packing, to be published.
E. A. DiMarzio and C. M. Guttman, Macromolecules, 3, 131, 681 (1970).
J. Mysels and D. Stigter, J. Phys. Chem., 59, 45 (1955).
D. B. Bly, J. Polym. Sci., 21, 3 (1968).
H. Brenner and L. J. Gaydos, J. Colloid Interface Sci., 58, 312 (1977).
M. Kerker, The Scattering of Light and Other Electromagnetic Radiation, Academic Press, New York, 37 (1969).
J. G. Carter, T. M. Jelinek, R. N. Hamm, and R. D.Birkhoff, J. Chem. Phys., 44, 226 (1966).
R. H. Partridge, J. Chem. Phys., 47, (1967).
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© 1980 Plenum Press, New York
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Nagy, D.J., Silebi, C.A., McHugh, A.J. (1980). Latex Particle Size Analysis by Chromatographic Methods: Porous Packed Systems and Detection of Polystyrene. In: Fitch, R.M. (eds) Polymer Colloids II. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-3635-8_8
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DOI: https://doi.org/10.1007/978-1-4684-3635-8_8
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-3637-2
Online ISBN: 978-1-4684-3635-8
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