Abstract
The surface tensions of aqueous solutions of variously substituted cellulose ether surfactants were measured over the complete concentration range and at varying temperatures. The surface excess thermodynamic expressions for these surfactant systems are derived and used to calculate the characteristic interracial thickness parameter, the surface excess interracial adsorption of the surfactants and the surface excess entropy, enthalpy, and free energy of the respective solutions. The relationship of these properties to the molecular structure of the cellulose ether surfactant molecules is discussed. From this analysis, several conclusions regarding physical properties such as protective colloid behavior can be made.
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Bibliography
E. D. Klug, D. P. Winquist, and C. A. Lewis, in “Water Soluble Polymers, Polymer Science and Technology,” Volume 2, Plenum Press, New York, pp. 401–416, 1973.
I. M. Timokhin, N. I. Lyzhina, Maslo-Zhir. Prom., 37 (6), 18 (1971).
A. J. Desmarais and H. o. Esser, Soc. Chem. Ind. (London, Monogr. No. 24), 57 (1966).
J. L. Cayais, R. S. Schechter and W. H. Wade, “Adsorption at Interfaces,” A. C. S. Symposium Series, No. 8, 234 (1975).
R. Defay, I. Prigogine, A. Bellemans, D. H. Everett, “Surface Tension and Adsorption,” Wiley and Sons, New York, 1966, pp. 55–57.
J. W. Gibbs, “The Collected Works of J. W. Gibbs,” Yale University Press, New Haven, 1948, Vol. 1, pp. 219–229.
D. H. Everett, ed., Pure and Appl. Chem. J., J31, 599 (1972).
F. W. Billmeyer, Jr., “Textbook of Polymer Science,” 2nd Ed., Wiley-Interscience, New York, 1971, pp. 39–41.
S. A. Chang and D. G. Gray, J. Colloid and Interface Science, to be published.
J. Th. G. Overbeek, “Colloid and Surface Chemistry. Part 1, Surface Chemistry,” M.I.T. Center for Advanced Engineering Study, Cambridge, 1971, pp. 6.1–6.13.
A. W. Adamson, “Physical Chemistry of Surfaces,” 2nd Ed., Interscience, New York, 1967, pp. 92–3.
J. T. Davies and E. R. Rideal, “Interfacial Phenomena,” 2nd Ed., Academic Press, 1963, pp. 200–201.
J. M. G. Lankveld, Meded. Landbouwhogesch. Wageningen, No. 70-21, 1–114 (1970).
“Encyclopaedia of Polymer Science and Technology,” Volume 3, Interscience, New York, 1965, p. 504.
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© 1980 Plenum Press, New York
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Wingrave, J.A. (1980). Interfacial Behavior of Polymer Colloids. In: Fitch, R.M. (eds) Polymer Colloids II. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-3635-8_20
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DOI: https://doi.org/10.1007/978-1-4684-3635-8_20
Publisher Name: Springer, Boston, MA
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