Skip to main content

Structure and Phase Transitions in Physisorbed Monolayers

  • Chapter

Part of the book series: NATO Advanced Study Institutes Series ((NSSB,volume 50))

Abstract

We present here an overview of the experimental phase behavior of simple atomic and molecular adsorbates on homogeneous substrates, emphasizing recent investigations using the (001) surface of graphite where in many cases there is close correspondence between the measurements and expected 2-D behavior. Because of space limitations only a partial view of the subject is presented; in particular, the beautiful thermodynamic studies of adsorbed He done by Dash, Bretz, Vilches and others are not covered. Illustrative examples have been chosen to a large extent from the authors’ own work, not because of any exaggerated sense of their relative importance and/or interest, but merely because the necessary figures were already in hand !

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. F. Paneth and A. Radu, Chem. Ber. 57:1221 (1924).

    Google Scholar 

  2. S. Brunauer, P. H. Emmett and E. Teller, J. Am. Chem. Soc. 60:310 (1938).

    Article  ADS  Google Scholar 

  3. G. D. Halsey, Jr., J. Chem. Phy. 16:931 (1948).

    Article  ADS  Google Scholar 

  4. W. J. C. Orr, Proc. Roy. Soc. (London) A175:349 (1939).

    ADS  Google Scholar 

  5. E. A. Gulbrandsen and K. F. Andrew, Ind. Eng. Chem. 44:1039 (1952).

    Article  Google Scholar 

  6. M. H. Polley, W. D. Schaeffer and W. R. Smith, J. Phys. Chem. 57:469 (1953).

    Article  Google Scholar 

  7. W. D. Schaeffer, W. R. Smith and M. H. Polley, Ind. Eny. Chem. 45:1721 (1953).

    Article  Google Scholar 

  8. B. B. Fischer and W. G. McMillan, J. Chem. Phys. 28:549 (1958) and earlier work cited therein. 9. W. A. Steele, “The Interactions of Gases with Solid Surfaces,” Pergamon Press (1974).

    Article  ADS  Google Scholar 

  9. F. E. Hanson, M. J. Handell and J. P. McTague, J Phys. (PARIS) 38:C4–76 (1977).

    Article  Google Scholar 

  10. J. G. Dash, “Films on Solid Surfaces,” Academic Press (1975).

    Google Scholar 

  11. A. Thorny and X. Duval, J. Chim. Phys. 67:1101 (1970).

    Google Scholar 

  12. D. M. Butler, J. A. Litzinger and G. A. Stewart, Phys. Rev. Letters 42:1289, (1979).

    Article  ADS  Google Scholar 

  13. T. T. Chung, unpublished. Quoted in ref. 18.

    Google Scholar 

  14. J. J. Lander and J. Morrison, Surface Sci. 6:1 (1967).

    Article  ADS  Google Scholar 

  15. J. A. Venables and P. S. Schabes-Retchkiman, J. Phys. (PARIS) 38:C4–105 (1977).

    Article  Google Scholar 

  16. J. P. McTague, M. Nielsen, and L. Passell, CRC Crit. Rev. Solid State Mat. Sci. 8:135 (19).

    Google Scholar 

  17. M. Nielsen, W. D. Ellenson and J. P. McTague, in “Neutron Inelastic Scattering” 1977, (IAEA Vienna), Vol. II., p. 433 (1978).

    Google Scholar 

  18. J. K. Kjems, L. Passell, H. Taub and J. G. Dash, Phys. Rev. Letters 32:724 (1974).

    Article  ADS  Google Scholar 

  19. J. K. Kjems, L. Passell, H. Taub, J. G. Dash and A. D. Novaco, Phys. Rev. B 13:1446 (1976).

    Article  ADS  Google Scholar 

  20. H. Taub, K. Carneiro, J. K. Kjems, L. Passell and J. P. McTague, Phys. Rev. B 16:4551 (1977).

    Article  ADS  Google Scholar 

  21. D. Frenkel, F. E. Hanson and J. P. McTague, these proceedings.

    Google Scholar 

  22. M. D. Chinn and S. C. Fain, Jr., Phys. Rev. Letters 39:146 (1977).

    Article  ADS  Google Scholar 

  23. S. C. Fain Jr. and M. D. Chinn, J. Phys. (PARIS) 38:C4–99 (1977).

    Article  Google Scholar 

  24. J. A. Venables and P. S. Schabes-Retchkiman, J. Phys. (PARIS) 38:C4–105 (1977).

    Article  Google Scholar 

  25. P. M. Horn, R. J. Birgenau, P. Heiney and E. M. Hammonds, Phys. Rev. Letters 41:961 (1978).

    Article  ADS  Google Scholar 

  26. S. Ostlund and A. N. Berker, Phys. Rev. Letters 42:843 (1979).

    Article  ADS  Google Scholar 

  27. A. D. Novaco and J. P. McTague, Phys. Rev. Letters 38:1286 (1977).

    Article  ADS  Google Scholar 

  28. A. D. Novaco and J. P. McTague, J. Phys. (PARIS) 38:C4–116 (1977).

    Article  Google Scholar 

  29. J. P. McTague and A. D. Novaco, Phys. Rev. B, (1979).

    Google Scholar 

  30. C. G. Shaw, S. C. Fain Jr. and M. D. Chinn, Phys. Rev. Letters 41:955 (1978).

    Article  ADS  Google Scholar 

  31. M. Nielsen, J. P. McTague and W. D. Ellenson, J. Phys. (PARIS) 38:C4–10 (1977).

    Article  Google Scholar 

  32. J. P. McTague and M. Nielsen, Phys. Rev. Letters 37:596 (1976).

    Article  ADS  Google Scholar 

  33. M. Nielsen and J. P. McTague, Phys. Rev. B

    Google Scholar 

  34. J. Stoltenberg and O. Vilches, unpublished.

    Google Scholar 

  35. E. Domany and E. K. Riedel, J. Appl. Phys. 49:1315 (1978).

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1980 Plenum Press, New York

About this chapter

Cite this chapter

McTague, J.P., Nielsen, M., Passell, L. (1980). Structure and Phase Transitions in Physisorbed Monolayers. In: Riste, T. (eds) Ordering in Strongly Fluctuating Condensed Matter Systems. NATO Advanced Study Institutes Series, vol 50. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-3626-6_16

Download citation

  • DOI: https://doi.org/10.1007/978-1-4684-3626-6_16

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-3628-0

  • Online ISBN: 978-1-4684-3626-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics