Prediction of Volatilization Rates of Chemicals in Water

  • James H. Smith
  • David C. Bomberger
Part of the Environmental Science Research book series (ESRH, volume 16)


Transport of chemicals from water bodies and wastewater treatment facilities to the atmosphere by volatilization (evaporation) can be an important environmental pathway for certain chemicals. Liss and Slater (1974) and Mackay and Leinonen (1975) assumed a two-film model in which the rates of diffusion in air and in water control the rate of transfer of a chemical across the interface between air and water.


Mass Transfer Coefficient Methyl Parathion Wastewater Treatment Facility Film Theory Film Mass Transfer Coefficient 


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  1. Danckwerts, P.V., (1951), Ind. Eng. Chem. 43, 1460.CrossRefGoogle Scholar
  2. Danckwerts, P.V., (1955), J. AIChE, 1, 456.CrossRefGoogle Scholar
  3. Hill IV J., et al (1976), “Dynamic Behavior of Vinyl Chloride in Aquatic Ecosystems”, U.S. Environmental Protection Agency, EPA-600/13–76–001.Google Scholar
  4. Higbie, R., (1935), Trans. AIChE, 31, 365.Google Scholar
  5. Liss, P.S. and P.G. Slater, (1974), Nature, 247, 181–184.ADSCrossRefGoogle Scholar
  6. Present, R.D., (1958), Kinetic Theory of Gases (McGraw-Hill, New York).Google Scholar
  7. Mackay, D., and P.J. Leinonen, (1975), Environ. Sci. Tech., 9, 1178–1180.CrossRefGoogle Scholar
  8. Mackay, D., and A.W. Wolkoff, (1973), Environ. Sci. Tech., 7, 611–614.CrossRefGoogle Scholar
  9. Reid, R.C., and T.K. Sherwood, (1966), The Properties of Gases and Liquids, 2nd ed. (McGraw-Hill, New York).Google Scholar
  10. Smith, J.H., and D.C. Bomberger, (1978), “Prediction of Volatilization Rates of Chemicals in Water”, paper presented at the AIChE 85th National Meeting, June 4–8, 1978.Google Scholar
  11. Smith, J.H. et al, (1977), “Environmental Pathways of Selected Chemicals in Freshwater Systems. Part 1: Background and Experimental Procedures”, EPA report No. EPA-600/7–77–113; (1978) “Part 2: Laboratory Results”, EPA report No.EPA-600/7–78–074.Google Scholar
  12. Tsivoglou, E.C., (1965), J. Water Poll. Control Fed., 37, 1343–1362; (1967), “Measurement of Stream Reaeration”, U.S. Department of the Interior, Washington, D.C, June 1967.Google Scholar

Copyright information

© Plenum Press, New York 1980

Authors and Affiliations

  • James H. Smith
    • 1
  • David C. Bomberger
    • 1
  1. 1.SRI InternationalMenlo ParkUSA

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