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Quasi-Crystals Produced by Colloidal Photochromic Dyes in an Applied Electric Field

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Abstract

Colloidal solutions are formed during the photochemical transformation of solutions of photochromic spiropyrans in non-polar solvents. The systems are composed of globules ~ 0.1–0.4 µm in diameter. The globules consist of highly dipolar crystalline nuclei enclosed in amorphous envelopes. In a constant external electric field linear quasi-crystalline material is formed composed of globules joined together like straight strings of beads aligned along the electric lines of force. The distinctive features of quasi-crystal formation were studied in the electron microscope.

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References

  1. Mees C E and James T H, Theory of the Photographic Process, Ch. 11 and 12, Macmillan, N.Y. (1966).

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© 1979 Plenum Press, New York

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Krongauz, V.A. (1979). Quasi-Crystals Produced by Colloidal Photochromic Dyes in an Applied Electric Field. In: Jennings, B.R. (eds) Electro-Optics and Dielectrics of Macromolecules and Colloids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-3497-2_35

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  • DOI: https://doi.org/10.1007/978-1-4684-3497-2_35

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-3499-6

  • Online ISBN: 978-1-4684-3497-2

  • eBook Packages: Springer Book Archive

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