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Multiple Electron Resonance Spectroscopy pp 229–259Cite as

Disordered Matrices

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Abstract

Endor in disordered matrices—polycrystalline, glassy, and amorphous media—is a rapidly developing area because it has been recognized that considerable information can be obtained. For many systems of chemical, technological, and biochemical interest, single crystals do not exist or are not readily obtainable. Thus, it is particularly important to develop methods of investigating paramagnetic species in disordered systems. Extraction of geometric and electronic structural information from esr spectra in disordered solids is generally difficult, and double resonance methods like endor and eldor can often be of considerable aid. Indeed, in some cases, the interpretation of the double resonance spectra is much easier. In this chapter, we wish to demonstrate the types of information obtainable by electron magnetic double resonance methods applied to radicals in disordered solids.

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Authors and Affiliations

  1. Department of Chemistry, Wayne State University, Detroit, Michigan, USA

    Larry Kevan & P. A. Narayana

Authors
  1. Larry Kevan
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  2. P. A. Narayana
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Editor information

Editors and Affiliations

  1. Diamond Shamrock Corporation, Painesville, Ohio, USA

    Martin M. Dorio

  2. Cornell University, Ithaca, New York, USA

    Jack H. Freed

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© 1979 Plenum Press, New York

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Kevan, L., Narayana, P.A. (1979). Disordered Matrices. In: Dorio, M.M., Freed, J.H. (eds) Multiple Electron Resonance Spectroscopy. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-3441-5_6

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  • DOI: https://doi.org/10.1007/978-1-4684-3441-5_6

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-3443-9

  • Online ISBN: 978-1-4684-3441-5

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