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ENDOR of Triplet State Systems in Solids

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Book cover Multiple Electron Resonance Spectroscopy

Abstract

Physical systems possessing one unit of effective electron spin angular momentum have been the subject of extensive study. Such triplet state systems may be excited- and ground-state molecules, pairs of free radical molecules, transition element ions, pairs of ions, and defects in solids. The molecules may range from relatively simple diatomic species to multiatom biological complexes. Detailed magnetic resonance measurements can yield information concerning wave functions, geometry and structure, lifetime of excited states, interactions with the environment, and other properties of these triplet state entities. We will discuss here the particular usefulness of electron nuclear double resonance(1) (endor)—nuclear magnetic resonance transitions detected by means of electron paramagnetic resonance (epr). Emphasis will be placed on triplet species in solids.

NRC/NBS Postdoctoral Research Associate, 1976–1977. An official contribution of the National Bureau of Standards; not subject to copyright.

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  1. Marvin D. Kemple

    Present address: Department of Physics, Indiana University-Purdue University, Indianapolis, Indiana, USA

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  1. National Bureau of Standards, Washington, D.C., USA

    Marvin D. Kemple

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  1. Diamond Shamrock Corporation, Painesville, Ohio, USA

    Martin M. Dorio

  2. Cornell University, Ithaca, New York, USA

    Jack H. Freed

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Kemple, M.D. (1979). ENDOR of Triplet State Systems in Solids. In: Dorio, M.M., Freed, J.H. (eds) Multiple Electron Resonance Spectroscopy. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-3441-5_12

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  • DOI: https://doi.org/10.1007/978-1-4684-3441-5_12

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-3443-9

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