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Charge and Spin Delocalization to the Trifluoromethyl Group

  • Leon M. Stock
  • Michael R. Wasielewski

Abstract

Herbert Brown has a long-standing interest in the concepts of hyperconjugation and non-classical behavior as influences in carbonium ion chemistry. It seems appropriate to consider at this symposium the analogous problem of delocalization to saturated substituents such as the trifluoromethyl group in negatively charged ions and in radicals.

Keywords

Fluorine Atom Trifluoromethyl Group Group Orbital Ortho Hydrogen Fluorine Substitution 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1978

Authors and Affiliations

  • Leon M. Stock
    • 1
  • Michael R. Wasielewski
    • 1
  1. 1.Department of ChemistryThe University of ChicagoChicagoUSA

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