Abstract
Most ceramics while being processed begin as an aggregation of particles and of pores. During processing the size and distribution of pores change. Some factors affecting pore size distribution (PSD) during processing are the particle size distribution, forming pressure, the volatilization of temporary binders and plasticizers, decomposition, and sintering. After processing many ceramics are porous and their PSDs can affect the properties in use. Mercury intrusion has been found to be the most useful method of characterizing PSD of porous ceramics. The method was first proposed by Washburn in 1921,1 but not until 1945 did Ritter and Drake report applications. 2 Since then many investigators have used the method to characterize porous materials. 4,5 This paper will describe several applications of mercury porosimetry for the characterization of ceramics at various stages of processing.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
E. W. Washburn, Proc. Nat. Acad. Sci., 7, 115–16 (1921).
H. L. Ritter and L. C. Drake, Ind. Eng. Chem. Anal. Ed., 17, 12, 782–786 (1945).
L. G. Joyner, E. P. Barrett, and R. Skold, J. Am. Chem. Soc., 71, 3155–8 (1951).
H. M. Rootare, Aminco Lab. News, 24, 4A-4H (1968).
C. Orr, Jr., Powder Technol., 3, 117–23 (1969/70).
O. J. Whittemore, Jr., and J. H. C. Castro, Proceedings, Mat. & Equip. & Whitewares Div., Am. Ceram. Soc., 48–51 (1976).
D. B. Calkins, Ph.D. Thesis, Univ. of Washington, Seattle (1970).
D. S. Adcock and I. C. McDowall, J. Am. Ceram. Soc., 40, 10, 355–62 (1957).
C. M. Lambe, in Ceramic Fabrication Processes, ed. W. D. Kingery, 31–40 (1958).
A. Watson, J. O. May, and B. Butterworth, Trans. Brit. Ceram. Soc. 56, 37 (1957).
O. J. Whittemore, Jr., and J. J. Sipe, Powder Technol., 9, 155–64 (1974).
P. Jeschke, J. Am. Ceram. Soc., 49, 7, 360–3 (1966).
O. J. Whittemore, Jr., unpublished report to the Foundation in Refractories Education, 1974.
H. D. Joss, M.S. Thesis, Univ. of Washington, Seattle (1975).
J. J. Sipe, Ph.D. Thesis, Univ. of Washington, Seattle (1971).
R. L. Coble, J. Am. Ceram. Soc., 41, 2, 55–62 (1958).
J. J. Sipe and O. J. Whittemore, Jr., J. Am. Ceram. Soc., 53, 9, 525 (1970).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1978 Plenum Press, New York
About this chapter
Cite this chapter
Whittemore, O.J. (1978). Pore Morphography in Ceramic Processing. In: Palmour, H., Davis, R.F., Hare, T.M. (eds) Processing of Crystalline Ceramics. Materials Science Research, vol 11. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-3378-4_12
Download citation
DOI: https://doi.org/10.1007/978-1-4684-3378-4_12
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-3380-7
Online ISBN: 978-1-4684-3378-4
eBook Packages: Springer Book Archive