Vegetable Tannins

  • E. Haslam
Part of the Recent Advances in Phytochemistry book series (RAPT, volume 12)


The desire to understand the chemical composition of living matter was undoubtedly the most significant stimulus to the very early development of organic chemistry in the 18th century. Since that time the subject has been transformed in many ways and perhaps the most significant manifestation of these changes has been the remarkable growth of the organic chemical industry and the part which it now plays in the life of man in the twentieth century. Interest nevertheless still continues to focus upon natural products. What has changed in all these years is the realisation by the natural product chemist that isolation, structure and even synthesis of new natural principles are mere prologue. The drama does not unfold until one begins to consider the place and the role which these “children of nature” have in living systems. For many of those engaged in fields of chemical investigation of nucleic acids, proteins, carbohydrates and lipids, their contributions form an integral part of work which unravels at an increasing pace the mysteries of nature; structure and function have an immediate and significant relationship to biological activity. For others, and particularly those concerned with many of the distinctive secondary plant products such as terpenes, alkaloids and polyphenols, such an intellectual satisfaction does not yet exist. There have been diverse speculations concerning the role of many of these metabolites in the life of the plant but with few exceptions the function of the majority has remained obscure. It is a major question in plant biochemistry which remains to be answered.


Condensed Tannin Hydrolysable Tannin Galloyl Group Chebulic Acid Witch Hazel 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


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  1. 1.
    White, T. 1957. J. Sci. Food Agric. 8: 377.CrossRefGoogle Scholar
  2. 2.
    Bate-Smith, E. C. 1973. Phytochemistry12: 907, 1809.CrossRefGoogle Scholar
  3. 3.
    Bate-Smith, E. C. and P. Ribereau-Gayon. 1959. Qual. Plant,5: 189.CrossRefGoogle Scholar
  4. 4.
    Howes, F. N. 1953. Vegetable Tanning Materials, Butterworths, London.Google Scholar
  5. 5.
    Bate-Smith, E. C. 1962. J. Linn. Soc. (Bot.)58: 95.Google Scholar
  6. 6.
    Schmidt, O. T. 1956. Fortschritt. Chem. Org. Naturstoffe14: 71.Google Scholar
  7. 7.
    Haslam, E. 1966. Chemistry of Vegetable Tannins, Academic Press, London and New York.Google Scholar
  8. 8.
    White, T. 1956. In The Chemistry of Vegetable Tannins, Society of Leather Traders’ Chemists, Croydon, p. 7.Google Scholar
  9. 9.
    Bate-Smith, E. C. and T. Swain. 1962. In: Comparative Biochemistry (editors, H. S. Mason and A. M. Florkin), Vol. III Academic Press, New York.Google Scholar
  10. 10.
    Bate-Smith, E. C. 1954. Food,23: 124.Google Scholar
  11. 11.
    Benoit, R. E., J. Basaraba and R. L. Starkey. 1968. Soil Science,105: 153.CrossRefGoogle Scholar
  12. 12.
    Benoit, R. E. and R. L. Starkey. 1968. Soil Science105: 291.CrossRefGoogle Scholar
  13. 13.
    Handley, W. R. C. 1961. Plant and Soil,15: 37. 15.Google Scholar
  14. 14.
    Grant, W. D. 1976. Science,193: 1137.PubMedCrossRefGoogle Scholar
  15. 15.
    Roux, D. G. 1972. Phytochemistry,11: 1219.CrossRefGoogle Scholar
  16. 16.
    Mayer, W. 1973. (1759) on Otto Theodor Schmidt, Liebig’s Annalen.Google Scholar
  17. 17.
    Freudenberg, K. 1920. Die Chemie der Naturlichen Gerbstoffe, Springer-Verlag, Berlin.Google Scholar
  18. 18.
    Schmidt, O. T. and W. Mayer. 1956. Angew. Chem.68: 103.CrossRefGoogle Scholar
  19. 19.
    Roberts, E. A. H. and M. Myers. 1960. J. Sci. Food Agric.11: 153CrossRefGoogle Scholar
  20. 20.
    Bradfield, A. E. and M. Penney. 1948. J. Chem. Soc. 2249.Google Scholar
  21. 21.
    Britton, G. and E. Haslam. 1965. J. Chem. Soc., 7312.Google Scholar
  22. 22.
    Freudenberg, K. 1919. Ber.52:177Google Scholar
  23. 23.
    W. Mayer, W. Kunz and F. Loebich 1965.688:232.Google Scholar
  24. 24.
    Perkin, A. G. and Y. Uyeda. 1922. J. Chem. Soc., 121Google Scholar
  25. 25.
    N. Kutani. 1960. Chem. Pharm. Bull.8: 72.CrossRefGoogle Scholar
  26. 26.
    Haslam E. and R. D. Haworth 1964. Progr. Org.Google Scholar
  27. 27.
    Grimshaw, J.In: Rodds Chemistry of Organic Compounds Second Edition (Editor, S. Coffey), Elsevier, Amsterdam and New York.Google Scholar
  28. 28.
    Armitage, R. G. S. Bayliss, J. W. Gramshaw, E. Haslam, R. D. Haworth, K. Jones, H. J. Rogers and T. Searle. 1961. J. Chem. Soc., 1842.Google Scholar
  29. 29.
    Armitage, R., E. Haslam, R. D. Haworth and T. Searle. 1962. J. Chem. Soc., 3808.Google Scholar
  30. 30.
    Haslam, E. 196?. J. Chem. Soc., (C) 1734.Google Scholar
  31. 31.
    Britton, G., P. W. Crabtree, E. Haslam and J. E. Stangroom. 1966. J. Chem. Soc., (C) 783.Google Scholar
  32. 32.
    Mathieson, A. McL. 1965. Tetrahedron Letters, 4137; Gulvenor, C. J. 1966. Tetrahedron Letters, 1091.Google Scholar
  33. 33.
    Reddy, K. K., S. Rajadurai, K. N. S. Sastry and Y. Nayudamma. 1964. Austral. J. Chem.,17: 238.Google Scholar
  34. 34.
    Fischer, E. and K. Freudenberg. 1914. Ber.,47: 2485.Google Scholar
  35. 35.
    Haslam, E., R. D. Haworth and P. C. Keen. 1962. J. Chem. Soc., 3815.Google Scholar
  36. 36.
    Schmidt, O. T. and D. M. Schmidt. 1952. Liebig’s Annalen,25:,31.CrossRefGoogle Scholar
  37. 37.
    Schmidt, O. T. and R. Lademann 1950. Liebig’s Annalen,569:149.CrossRefGoogle Scholar
  38. 38.
    Jochims, J. C., G. Taigel and O. T. Schmidt. 1968. Liebig’s Annalen,717: 169.CrossRefGoogle Scholar
  39. 39.
    Schmidt, O. T., L. Wurtell and A. Harrens. 1965. LiebAnnalen,690: 150.Google Scholar
  40. 40.
    Mayer, W., A. Einwiller and J. C. Jochims. 1967. Liebig’s Annalen,707: 182.CrossRefGoogle Scholar
  41. 41.
    Mayer, W. H. Seitz and J. C. Jochims. 1969. Liegbig’s Annalen,721: 186.Google Scholar
  42. 42.
    Mayer, W. F. Kuhlmann and G. Schilling. 1971. Liebig’s Annalen,747: 51.CrossRefGoogle Scholar
  43. 43.
    Mayer, W. H. Seitz, J. C. Jochims, K. Schauerte and Schilling. 1971. Liebig’s Annalen,751: 60.CrossRefGoogle Scholar
  44. 44.
    Mayer, W. W. Bilzer and K. Schauerte. 1971. Liebig’sAnnalen,754: 149Google Scholar
  45. 45.
    Mayer, W., H. Busath and Schick. 1976. Liebig’s Annalen, 2169; Mayer, W. H. Schick and G. Schilling. 1976. Liebig’s Annalen, 2178.Google Scholar
  46. 46.
    Schmidt, O. T. and W. Mayer. 1951. Liebig’s Annalen,571: 1,15.Google Scholar
  47. 47.
    Haworth, R. D. and L. B. de Silva. 1951. J. Chem. Sog., 3511; 1954. 3611.Google Scholar
  48. 48.
    Haslam, E. and M. Uddin. 1967. J. Chem. Soc., C. 2381.Google Scholar
  49. 49.
    Schmidt, O. T. and W. Nieswandt. 1950. Liebig’s Annallen,568:165.Google Scholar
  50. 50.
    Schmidt, O. T., R. H. Hensler and P. Stephen.1957. Liebig’s Annalen,609: 186.CrossRefGoogle Scholar
  51. 51.
    Schmidt, O. T., J Schulz and R. Wurmb. 1967. Lie-big’s Annalen,706:169.CrossRefGoogle Scholar
  52. 52.
    Schmidt, O. T., R. Schanz, W. Groebke and R. Wurmb. Liebig’s Annalen,706: 154.Google Scholar
  53. 53.
    Schmidt, O. T., R. Schanz, R. Wurmb and R. Eckert. 1967. Liebig’s Annalen,706: 131.CrossRefGoogle Scholar
  54. 54.
    Schmidt, O. T., R. Eckert, E. Gunther and H. Filsser. 1967. Liebig’s Annalen,706: 24.Google Scholar
  55. 55.
    Schmidt, O. T., K. Demmler, H. Bilterman and P. Stephan. 1957. Liebig’s Annalen,609: 192.CrossRefGoogle Scholar
  56. 56.
    Schmidt, O. T., D. M. Schmidt and J. Herok. 1954. Liebig’s Annalen,587:67.CrossRefGoogle Scholar
  57. 57.
    Mayer, W., W. Gabler, A. Riester and H. Korger. 1967. Liebig’s Annalen,707: 177.CrossRefGoogle Scholar
  58. 58.
    Reeves, R. E. 1951. Adv. Carbohydrate Chem.,6: 107.CrossRefGoogle Scholar
  59. 59.
    Freudenberg, K. and P. Maitland. 1934. Liebig’s Annalen,570: 193.CrossRefGoogle Scholar
  60. 60.
    Freudenberg, K. and K. Weinges. 1958. Fortschritt. Chem. Org. Naturstoffe,16: 1.Google Scholar
  61. 61.
    Freudenberg, K. and K. Weinges. 1954. Liebig’s Annalen,590: 140.CrossRefGoogle Scholar
  62. 62.
    Roux, D. G. 1958. Nature,181: 1454.CrossRefGoogle Scholar
  63. 63.
    Roux, D. G. and E. Paulus. 1961. Biochem. J.,78: 476, 785; 1962.82: 320.Google Scholar
  64. 64.
    Roux, D. G. and E. A. Maihs. 1961. Biochem. J.,78: 123.Google Scholar
  65. 65.
    Brown, B. R. and W. Cummings. 1958. J. Chem. Soc., 4302.Google Scholar
  66. 66.
    Brown, B. R., W. Cummings and J. Newbould. 1961. J. Chem. Soc., 3677.Google Scholar
  67. 67.
    Brown, B. R., M. M. Bokadia and W. Cummings. 1960. J. Chem. Soc., 3308.Google Scholar
  68. 68.
    Creasey, L. L. and T. Swain. 1965. Nature,208: 151.CrossRefGoogle Scholar
  69. 69.
    Geissman, T. A. and H. F. Dittmar. 1965. Phytochemistry,4: 359.CrossRefGoogle Scholar
  70. 70.
    Hathway, D. E. and J. W. T. Seakins. 1957. J. Chem. Soc., 1562; 1957. Biochem. J.,67: 239.Google Scholar
  71. 71.
    Brown, B. R. and R. J. Whiteoak. 1964. J. Chem. Soc., 3804.Google Scholar
  72. 72.
    Drewes, S. E., D. G. Roux, S. H. Eggers and J. Feeney. 1966. Chem. Comm., 368; 1967. J. Chem. Soc., (C), 1217.Google Scholar
  73. 73.
    Roux, D. G.,S. E. Drewes, H. M. Saayman, J. Feeney and S. H. Eggers. 1965. Chem. Comm., 370; 1967. J. Chem. Soc., (C) 1302.Google Scholar
  74. 74.
    dePreez, I. C., A. C. Rowan and D. G. Roux. 1971. Chem. Comm., 315.Google Scholar
  75. 75.
    Ferreria, D., H. K. L. Hundt and D. G. Roux. 1971. Chem. Comm., 1257.Google Scholar
  76. 76.
    Rosenheim, O. 1920. Biochem.,14:278.Google Scholar
  77. 77.
    Robinson, R. and G. M. Robinson. 1933. Biochem. J.,27:206.PubMedGoogle Scholar
  78. 78.
    Bate-Smith, E. C. 1953. J. Exp. Bot.,4:1CrossRefGoogle Scholar
  79. 79.
    Bate-Smith, E. C. 1954. Biochem. J.,58:122PubMedGoogle Scholar
  80. 80.
    Bate-Smith, E. C. and N. H. Lerner. 1954. Biochem. J.,58:126.PubMedGoogle Scholar
  81. 81.
    Bate-Smith, E. C. and T. Swain. 1954. Chem. and Ind., 433.Google Scholar
  82. 82.
    King, F. E. and W. Bottomley. 1954. J. Chem. Soc., 1399.Google Scholar
  83. 83.
    Forsyth, W. G. C. and J. B. Roberts. 1960. Biochem. J.,74: 374.PubMedGoogle Scholar
  84. 84.
    Freudenberg, K. and K. Weinges. 1960. Tetrahedron,8: 336.CrossRefGoogle Scholar
  85. 85.
    Weinges, K., W. Bahr, W. Ebert, K. Göritz and H.-D. Marx. 1969. Fortschritte Chem. Org. Naturstoffe,27:158.Google Scholar
  86. 86.
    Marini-Bettolo, G. B., F. Ferrari, F. D. Monache and A. Poce-Tucci. 1972. Phytochemistry, 2333Google Scholar
  87. 87.
    Marini-Bettolo, G. B., F. Ferrari and F. D. Monache. 1971. Gazz. chim. ital.101: 387.Google Scholar
  88. 88.
    Weinges, K.,W. Kaltenhauser, H.-D. Marx, E. Nader, F. Nader, J. Perner and D. Seiler. 1968. Leibig’s Annalen,711: 184.Google Scholar
  89. 89.
    Thompson, R. S., D. Jacques, E. Haslam and R. J. N. Tanner. 1972. J. Chem. Soc., (Paerkin 1) 1387.CrossRefGoogle Scholar
  90. 90.
    Clark-Lewis, J. W. 1968. Austral. J. Chem.,21: 2059.Google Scholar
  91. 91.
    Eliel, E. L., W. F. Bailey, L. D. Kopp, R. L. Wilier, D. M. Grant, R. Bertrand, K. A. Christensen, D. K. Bailing, M. W. Duch, E. Wenkert, F. M. Schell and D. W. Cochran. 1975. J. Amer. Chem. Soc.97: 322.CrossRefGoogle Scholar
  92. 92.
    Fletcher, A. C., L. J. Porter, E. Haslam and R. K. Gupta. 1977. J. Chem. Soc., (Perkin I) in press.Google Scholar
  93. 93.
    Whiting, D. A., E. Haslam, C. T. Opie and M. J. Begley, unpublished observations.Google Scholar
  94. 94.
    Weinges, K., H. -D. Marx and K. Göritz. 1970. Chem. Ber.,103:2336.CrossRefGoogle Scholar
  95. 95.
    Jurd, L. and R. Lundin. 1968. Tetrahedron,24: 2653.CrossRefGoogle Scholar
  96. 96.
    duPreez, I. C., A. C. Rowan, D. G. Roux and J. Feeney. 1971. J. C. S. Chem. Comm., 315.Google Scholar
  97. 97.
    Haslam, E. 1969. J. Chem. Soc., (C). 1824.Google Scholar
  98. 98.
    Weinges, K., K. Göritz and F. Nailer, 1968. Liebig’s Annalen,715: 164.CrossRefGoogle Scholar
  99. 99.
    Geissman, T. A. and N. N. Yoshimura. 1966. Tetrahedron Letters, 2669.Google Scholar
  100. 100.
    Grisebach, H. 1968. In Recent Advances in Phyto-chemistry. Volume 1, (edited by T. J. Mabry, V. C. Runeckles and R. E. Alson), Appleton- Century-Crofts, New York. p. 379.Google Scholar
  101. 101.
    Daly, J. W., D. M. Jerina and B. Witkop. 1972.Experentia,28: 1129.CrossRefGoogle Scholar
  102. 102.
    Hahlbrock, K. and H. Grisebach. 1975. The Flavonoids, editors, J. B. Harborne, T. J. Mabry and H. Mabry, 1975. Chapman and Hall, London, p. 866.Google Scholar
  103. 103.
    Birch, A. J. 1963. In Chemical Plant Taxonomy,editor, T. Swain, Academic Press, London and New York, p. 148.Google Scholar
  104. 104.
    Roux, D. G. and D. Ferreira 1974. Phytochemistry,13: 2039.CrossRefGoogle Scholar
  105. 105.
    Clark-Lewis, J. W. and D. C. Skingle. 1967.Austral. J. Chem.20:2169.Google Scholar
  106. 106.
    Jacques, D. and E. Haslam. 1974. J. C. S. Chem. Com. 231.Google Scholar
  107. 107.
    Jacques, D., C. T. Opie, L. J. Porter and E. Haslam. 1977. Phytochemistry,16: 99.CrossRefGoogle Scholar
  108. 108.
    Jacques, D., C. T. Opie, L. J. Porter and E. Haslam. 1977. J. Chem. Soc., (Perkin I), in press.Google Scholar
  109. 109.
    Haslam, E. 1974. J. C. S. Chem. Comm., 594.Google Scholar
  110. 110.
    Swain, T. In Plant Biochemistry, (editors, J. Loomis, W. D. and J. Bataill. 1966. Phytochemistry,5: 423.Google Scholar
  111. 111.
    Haslam, E. 1974. Biochem. J.,39: 285.Google Scholar
  112. 112.
    Helferich, B. and T. Kleinschmidt. 1968. Hoppe-Seyler’s Z. Physiol. Chem.,349:25–28.CrossRefGoogle Scholar
  113. 113.
    Gustavson, K. H. and B. Holm. 1952. J. Amer. Leather Chem. Assn.,47: 700.Google Scholar
  114. 114.
    Ellis, S. C. and K. G. A. Pankhurst. 1954. Discuss. Faraday Soc.,16: 170.CrossRefGoogle Scholar
  115. 115.
    Geissman, T. A. 1972. In Recent Advances in Phytochemistry, Volume 4, (editors V. C. Runeckles and J. E. Watkin, Appleton Century-Crofts. p. 303.Google Scholar

Copyright information

© Plenum Press, New York 1979

Authors and Affiliations

  • E. Haslam
    • 1
  1. 1.Department of ChemistryUniversity of SheffieldSheffieldUK

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